Assessment of the Uncertainties in the NO2 and O3 Measurements by Visible Spectrometers

The column amounts of nitrogen dioxide (NO2) and ozone (O3) were measured using a visible spectrometer based on the twilight zenith-sky technique at two observatories located at similar latitudes in the northern part of Japan separated by a distance of 150 km. The measurements began in April 1991 at the Moshiri Observatory (44.4°N, 142.3°E) and in April 1994 at the Rikubetsu Observatory (43.5°N, 143.8°E). Since weather conditions and the possible influence from tropospheric pollution were not always identical at these two observatories, the overall accuracy of the measurements was studied comparing these data sets. The first year data obtained at a solar zenith angle of 90 degrees indicated that the NO2 slant column values at sunrise and sunset agreed within 0.36 and 0.54 × 1016 cm-2, respectively, corresponding to 5 % (June) and to 12 % (December) of the columns. The O3 values agreed within 0.76 × 1019 cm-2, corresponding to 4 % (March) 6 % (August) of the columns, although a part of the difference was systematic. The O3 column amounts were also compared to those obtained by the Dobson spectrometer at Sapporo (43.5°N, 143.8°E), whose latitude is similar to these observatories. When an air mass factor of 17.5 was used, the two-year Moshiri vertical column values agreed with the Dobson direct sun values to within 15 Dobson Units, or 3 6 % of the column. The difference between the two values was found to be due partly to the change in the air mass factor caused by seasonal and day-to-day changes in the shape of the O3 vertical profiles. These results confirm the reliability of the NO2 and O3 measurements by visible spectrometers at these sites for the Network for the Detection of Stratospheric Change (NDSC).     

成像光谱数据特征选择及小麦品种识别实验研究

针对河北栾城获得的MAIS成像光谱仪数据用于小麦品种识别进行了特征选择和分类研究。利用遗传算法以JM距离为准则并结合实验区小麦的生物物理特性，进行了最佳波段选择；利用Fuzzy—Anmap分类器及选出的最佳波段对成像光谱数据进行了分类，区分出了4种小麦品种，小麦的总体分类精度超过97％。     

利用遥感光谱特征提取岩性信息的基础和技术研究

地物光谱特征的研究是遥感技术的基础研究工作之一．从光谱遥感发展与地质应用的趋势出发。从光谱遥感岩矿识别基础与识别技术方法两方面阐述了光谱遥感的研究进展．在技术方法方面，主要从多光谱与成像光谱以及遥感与航空放射性信息集成3个层次上，分析利用光谱特征进行岩石矿物识别的研究进展及其潜力与可行性，并简单阐述了遥感与航空放射性信息的复合这一遥感岩性信息识别研究的发展趋势．     

曲线拟合在核探测器信号幅度提取中的应用

研究数字化核探测器输出脉冲信号的幅度提取问题。根据闪烁探测器的电路特性，推导了其脉冲信号理想曲线方程。综合利用三和值法、最小二乘法、试探法等方法，设计了该理想曲线拟合算法。由脉冲信号采样点数据，通过曲线拟合，计算出曲线的极大值，该值即为闪烁探测器输出脉冲信号的幅度。正反演数据结果对比表明，采用曲线拟合算法提取闪烁探测器输出脉冲信号幅度，其方案可行，计算结果更准确。相较于数字滤波和数字脉冲成形方法提取核探测器输出脉冲幅度，该算法更简单，对仪器的硬件处理速度要求更低。该方法开辟了核探测器脉冲幅度提取的新途径。     

Thermo 6300型电感耦合等离子体发射光谱仪常见故障及排除方法

详细介绍了美国Thermo仪器公司生产的Thermo 6300型电感耦合等离子体发射光谱仪在使用过程中不能"引燃"、容易"熄火"、数据稳定性差等常见故障及排除方法,以及其辅助设备的维护维修实例。     

原子荧光测定食品中总砷方法的改进与探讨

针对国标《GB 5009.11—2003食品中总砷及无机砷的测定》中的原子荧光-湿法消解测定总砷的方法中存在的难于控制完全消解样品、测定结果不稳定,试剂用量大的问题,对原方法进行了3点改进。一是利用浓硫酸沸点高,能脱水碳化破坏有机物的特性,通过高温浓缩硫酸对样品进行两次脱水碳化消解,使样品消解的更完全,且节省试剂;二是针对样品中砷形态的多样性,加强温度控制,低温消解、降低易挥发砷化合物的损失,高温加速样品消解,缩短操作时间;三是加盖小漏斗制造回流,减少易挥发砷化合物的损失,使方法易操作、节省试剂。用改进的方法测定菠菜粉(GBW10015)、海带粉(GBW08517)和虾粉(CNAS T0442)中的总砷,不少于6个平行样的测定结果均位于参考值范围的中间部分,且RSD值均小于7%,表明改进的方法准确、稳定。结果还表明,200℃的硫酸、高氯酸的混合酸和高温浓硫酸均能有效消解样品中砷甜菜碱和砷糖类化合物。     

基于灰度归一化的HJ-1A星HSI图像条带噪声去除方法

针对HJ -1A星HSI图像上的条带噪声,在分析传统条带噪声去除方法的基础上,提出了一种新的基于灰度归一化去除条带噪声的方法.首先,设计孤立点检测窗口,将随机斑点噪声与条带噪声分离;然后,利用灰度归一化方法建立图像各列像元灰度级与基准列像元灰度级对应的查找表,根据查找表对HSI图像条带噪声进行消除.实验结果表明,该方法在很好地保留图像光谱信息的情况下,能够有效地消除图像条带噪声和随机斑点噪声.     

一次冰雹天气过程的多源资料观测分析

利用地基微波辐射计、风廓线雷达和雨滴谱仪等观测资料,对2015年4月28日发生在南京的一次冰雹天气进行了分析,探讨新型探测资料在冰雹监测预警中的应用。结果表明:(1)华北冷涡后部冷空气南下,与低层暖湿气流交汇,是产生这次冰雹的天气背景;高空冷平流叠加在低层暖湿气流之上,使得对流层中低层形成不稳定层结;地面辐合中心及辐合线是降雹的触发机制。(2)微波辐射计监测显示,降雹期间冰雹云中上升气流将底层空气的感热和潜热向上输送,导致2 km以上大气有明显升温,由于低层水汽聚集及冰雹在近地层融化造成降雹时近地层相对湿度、水汽密度增大。冰雹发生在云液态水含量快速增长的波峰上,对冰雹的发生具有较好指示意义。(3)对比南京3站风廓线雷达资料表明各站上空环境风场存在一定差异,六合地区降雹前6 km高度高空急流有利于六合上空形成有利的辐散形势,降雹时0~6 km存在较深厚的垂直风切变,配合地面中尺度低压,降雹最为强烈;南京站降雹时,对流层中下层有一槽过境,而高淳地区冰雹由近地面垂直风切变激发。(4)六合站、高淳站雨滴谱仪分析表明不同降水相态对应的滴谱特征有差异,两站雨滴谱型分别呈指数型、多峰型分布。高淳站雨滴谱仪监测到直径达到15 mm的冰雹粒子,六合站冰雹直径最大为5 mm。两站速度谱大致为单峰型,在较强降水时刻,粒子下落峰值速度在3~4 m·~(-1)。(5)影响六合的超级单体存在钩状回波、回波悬垂、三体散射等雷达回波中尺度特征,地面中尺度低压系统、中低层的中气旋及高层的辐散环流配置造成了雹云中维持较强的旋转上升气流,有利于出现大冰雹。     

深空探测科学仪器研究进展

深空探测是对宇宙中地球以外的行星、卫星、小行星和彗星等星体或空间环境的探测活动.合理选择深空探测科学仪器,了解被测星体的物理及化学性质、地表地貌、动态特性以及有机物和水的存在,对人类了解地外水和生命信息、认识太阳系的起源和演化有着重要意义,是深空探测的重要任务.本文总结了深空探测的科学目标,介绍了近50年来典型深空探测任务中探测器所搭载的科学仪器及其特点,包括质谱仪、光谱仪、探地雷达和磁力计等,整理了其性能参数及面向的探测功能任务,最后讨论了深空探测科学仪器目前呈现出的小型化、低功耗、更强的环境适应能力和多仪器联合使用的发展趋势.     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.