吡啶偶氮类试剂在光度分析中的应用进展

吡啶偶氮类试剂是一类性能优良的络合滴定指示剂和光度显色剂,迄今已合成了200余种,在分光光度分析测定各种金属离子方面得到了广泛的应用。为了进一步改善这类试剂的灵敏度和选择性等分析性能,近年深入研究了吡啶偶氮类试剂的结构与性能的关系,进而相继开发出一系列性能优异的吡啶偶氮类试剂。文章综述了1990—2010年以来常见的吡啶偶氮类试剂及其在分光光度分析测定金属离子方面的进展。从反应体系、最大吸收波长、灵敏度、线性范围等方面归纳了吡啶偶氮类试剂在实际样品中的应用情况,为此类试剂的开发和应用提供一些理论依据。     

广东连州长兴期含煤地层

九陂组(亚田煤组)是粤北和湘南晚二叠世重要的含煤地层,其下伏"梅田灰岩"的涵义和(虫筵)化石Gallowayinella meitienensis的层位问题曾长期未得澄清.通过对梅田组剖面的详细工作,建立了下部的Gallowayinella组合和上部的Nanlingella jiaozishanica-Sphaerul...     

华北古陆南缘豫西新元古代大型疑源类及古地理环境分析

华北古陆南缘豫西元古宙地层中白草坪组出现大量大型具刺疑源类,通常大型疑源类首现于新元古代地层,而华北古陆这类的疑源类却首现于中元古地层,因此,其起源和演化谱系就成为许多学者仍需深入探讨的未解之谜。近年来,蓟县中、新元古代地层一直是视为标准剖面,但是,下马岭组新的锆石SHRIMP U-Pb年龄打破了该组原有的中、新元古代地层的位置,同时也打破了生物演化序列的完整性。新的年龄意味着蓟县剖面中、新元古代地层有可能缺失1200～900 Ma地质记录。从生物地层上分析,豫西的汝阳群和洛峪群中出现大量大型疑源类有可能填补蓟县剖面中生物的空缺。本文通过生物地层学、化学地层学研究和岩相分析,探讨其发生可能和地层及构造意义。     

Stratigraphy of the Triassic?Jurassic Boundary Successions of the Southern Margin of the Junggar Basin, Northwestern China

The Triassic?Jurassic (Tr?J) boundary marks a major extinction event, which (~200 Ma) resulted in global extinctions of fauna and flora both in the marine and terrestrial realms. There prevail great challenges in determining the exact location of the terrestrial Tr?J boundary, because of endemism of taxa and the scarcity of fossils in terrestrial settings leading to difficulties in linking marine and terrestrial sedimentary successions. Investigation based on palynology and bivalves has been carried out over a 1113 m thick section, which is subdivided into 132 beds, along the Haojiagou valley on the southern margin of the Junggar Basin of the northern Xinjiang, northwestern China. The terrestrial Lower Jurassic is conformably resting on the Upper Triassic strata. The Upper Triassic covers the Huangshanjie Formation overlaid by the Haojiagou Formation, while the Lower Jurassic comprises the Badaowan Formation followed by the Sangonghe Formation. Fifty six pollen and spore taxa and one algal taxon were identified from the sediments. Based on the key-species and abundance of spores and pollen, three zones were erected: the Late Triassic (Rhaetian) Aratrisporites?Alisporites Assemblage, the Early Jurassic (Hettangian) Perinopollenites?Pinuspollenites Assemblage, and the Sinemurian Perinopollenites?Cycadopites Assemblage. The Tr?J boundary is placed between bed 44 and 45 coincident with the boundary between the Haojiagou and Badaowan formations. Beds with Ferganoconcha (?), Unio?Ferganoconcha and Waagenoperna?Yananoconcha bivalve assemblages are recognized. The Ferganoconcha (?) bed is limited to the upper Haojiagou Formation, Unio?Ferganoconcha and Waagenoperna?Yananoconcha assemblages are present in the middle and upper members of the Badaowan Formation. The sedimentary succession is interpreted as terrestrial with two mainly lake deposit intervals within Haojiagou and Badaowan formations, yielding fresh water algae and bivalves. However, the presence of brackish water algae Tasmanites and the marine?littoral facies bivalve Waagenoperna from the Badaowan Formation indicate that the Junggar Basin was influenced by sea water caused by transgressions from the northern Tethys, during the Sinemurian.     

显微-次显微态自然金中Fe存在形式的初步认识

金是人类使用历史最长的贵金属,具有众所周知的货币保值作用,而近年来,随着科学技术的发展,金的工业应用逐渐成为黄金需求的重要领域。另一方面,矿产金资源的相对不足以及人类对黄金的需求居高不下,使得黄金价格不断高涨,导致了对矿产金资源勘探开发的热潮。对黄金资源的成矿规律、成矿预测研究和对黄金选冶技术的研发已成为重要的研究领域,吸引了众多     

省级古生物化石保护规划“模板”成型

近日,南辽宁省化石资源保护管理局编制完成的《省级古生物化石保护规划编制指南》（送审稿）在北京通过国家古生物化石专家委员会办公室组织的专家评审,至此,明年将在全国全面推行的《省级古生物化石保护规划（2012—2020）》编制工作有了标准框架。     

青海玉树东莫扎抓铅锌矿床围岩蚀变和黄铁矿-闪锌矿矿物学特征及意义

青海玉树地区的东莫扎抓铅锌矿床是"三江"沉积岩容矿贱金属成矿带中的重要矿床之一.矿区过去研究鉴定出多种蚀变类型和矿物种类,但不同蚀变在矿区的空间分布特征、不同矿物中元素含量特点、矿物相互之间的时间和空间关系均不清楚,从而导致所指示的找矿意义也不明确.为此,作者进行了系统岩矿石光薄片的显微镜下鉴定、矿区主要硫化物--黄铁...     

新疆蒙库地区那林卡拉组地质特征简述

下石炭统那林卡拉组中化石含量相当丰富,地层中沉积岩韵律也较为清晰,那林卡拉组位于新疆蒙库地区,通过对该地层的工作及资料收集以及对该组的地质特征的一些简单的认识来简述该地层的地质特征.     

“井水不犯河水”水文地质学含义初步探讨

利用水化学及同位素水文地质学的方法,对密云水库、潮白河及位于潮白河边的2个地下水分层专门监测井进行取样测试,并结合收集相关资料,从水位、水质及氚、氘、氧-18等同位素方面进行分析研究,对中国古语“井水不犯河水”的水文地质学方面的含义进行了一定的微观层次的分析探讨.得出研究点处潮白河水对50 m外的25 m深的浅井井水有...     

鄂尔多斯盆地旦八油田延长组长3储层研究

三叠系延长组长3储集层灰色细粒长石砂岩储层物性差,属低孔、低渗储层.空隙以粒间孔、溶孔为主,且成岩作用控制孔隙结构.根据岩性、物性特征,把研究区储层分为四类:Ⅰ类好储集层,Ⅱ类较好储集层,Ⅲ类较差储集层,Ⅳ类非储层.