东波超镁铁岩体:西藏雅鲁藏布江缝合带西段一个甚具铬铁矿前景的地幔橄榄岩体

东波超镁铁岩体产在雅鲁藏布江缝合带的西段,与周边白垩纪沉积岩地层和火山岩以断层接触.航磁资料显示该岩体约400km2规模,地表出露连续,地下有一定延深.超镁铁岩体由亏损的地幔橄榄岩组成,主要有高镁的方辉橄榄岩、纯橄岩和少量二辉橄榄岩.方辉橄榄岩和二辉橄榄岩中橄榄石和斜方辉石属高镁型,分别为Fo=89.5～91.5和Mg#=90～91.5.但二辉橄榄岩中的Al2O3和CaO含量明显高于方辉橄榄岩.方辉橄榄岩中单斜辉石Mg#=92～95,二辉橄榄岩的Mg#=92～93,两者的值也重叠.二辉橄榄岩中的Al2O3和CaO含量要明显高于方辉橄榄岩.这些均为阿尔卑斯型地幔橄榄岩的典型特征.纯橄岩中的橄榄石Fo=92～93.2,其斜方辉石和单斜辉石的Mg#=～93,但Al2O3和CaO的含量比方辉橄榄岩和二辉橄榄岩的低.三种岩石的成分变化规律,反映了地幔部分熔融程度的差异.二辉橄榄岩铬尖晶石的Cr#值20～30,反映为典型深海橄榄岩特征,指示MOR环境.与其不同的是,方辉橄榄岩的铬尖晶石的Cr#=20～75,指示MOR和SSZ两者兼有环境.岩石的原始地幔标准化的REE和微量元素蛛网图模式支持了上述的认识.东波地幔橄榄岩中的岩石学特征与产有大型铬铁矿床的罗布莎地幔橄榄岩可对比,岩体中已多处发现块状铬铁矿石,其铬铁矿的Cr2O3含量56％～59％,表明东波是寻找铬铁矿大矿和富矿甚具前景的一个超镁铁岩体.     

大别山地区石榴石橄榄岩的岩石学和地球化学

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。     

东海地区高压-超高压变质带中变质橄榄岩及其原岩和成因类型的判别——以PP1孔和PP3孔为例

本文在总结全球地幔橄榄岩岩石学和地球化学特征的基础上,首次提出了一个用于判别HPUHP变质带中变质橄榄岩原岩及其成因类型的判别图解。该图主要由镁铁总量MgO+（%）和一个参数m+f/si比值构成。另用Al2O3和CaO分别与MgO+（%）制成两个辅助图解,以示方辉橄榄岩和二辉橄榄岩之间在Al2O3和CaO含量上的分界。通过原岩判别结果和研究表明,PP3孔和PP1孔两者在变质组合、原岩成因类型、地球化学和变质条件方面存在一系列的重大差异。分别代表来自两种极端的地球化学类型和两种不同大地构造环境的UHP变质体。PP3钻孔以Ol+Gt+Cpx+Opx+Sp为变质矿物共生组合的含石榴石纯橄岩,其原岩系来自地幔残余成因的方辉橄榄岩遭受UHP变质作用的产物,它以成分高度均一,富Mg（Mg’=92）,极端亏损不相容元素REE（∑REE<1×10-6可称为超亏损型）为特征。在变质相中仍保留原岩的残余矿物铬尖晶石（Sp）,其成分显示蛇绿岩地幔橄榄岩的成分趋势。并出现以Gt和Sp共存相为特征的变质相。据实验结果（klemme,2004）表明该共存相的稳定域的PT条件CrSp可达7Gpa,T1400℃,即形成于200km的地幔深度。综合研究显示该孔变质橄榄岩原岩（方辉橄榄岩）具有大洋岩石圈地幔残余成因的某些印记,而不是同深度原生地幔岩相转变的产物。PP1孔变质橄榄岩是由无水矿物相（Ol+Opx+Cpx+Gt）+含水矿物相（Phl±Chu）组成的石榴石橄榄岩杂岩,其原岩来自两种不同成因的超镁铁岩系列：一为具地幔成因的方辉橄榄岩二辉橄榄岩系列（可能相当于地幔楔中的Al型橄榄岩）,另一部分（少数）来自具岩浆成因的超镁铁岩系列（纯橄岩—异剥橄榄岩—辉石岩组合,可能相当于A2型橄榄岩）。该套变质橄榄岩,以成分高度不均一,极端富集REE（∑REE平均>20×10-6可称为超富集型）和大离子亲石元素（K、Ba、Rb）为特征。这种异常现象并不反映其原岩原有的地球化学特征,它可能是由于在俯冲过程中受到陆壳物质的污染,或壳幔相互作用所致。据该孔变质相中缺乏Sp相,而以Gt为标志的变质相的事实,推断其形成的压力条件应>7Gpa, 即形成的深度应大于200km。上述研究表明在苏鲁UHP变质带中,不仅有来自大陆地幔楔中的地幔残余的UHP变质体,而且首次提出有可能来自大陆俯冲前锋具大洋岩石圈地幔性质的（蛇绿岩型地幔残片）变质体存在,这对揭示该区UHP变质带的形成和演化过程提供了新的信息。     

Determination of Zirconium, Niobium, Hafnium and Tantalum at ng g-1 Levels in Geological Materials by Direct Nebulisation of Sample HF Solution into FI-ICP-MS

We have developed a rapid and accurate method to determine Zr, Nb, Hf and Ta (denoted as HFSE) in geological samples by inductively coupled plasma-mass spectrometry fitted with a flow injection system (FI-ICP-MS). The method involves sample decomposition by HF followed by HF dissolution of HFSE coprecipitated with insoluble M and Ca fluoride residues formed during the initial HF attack. This HF solution was directly nebulized into an ICP mass spectrometer. An external calibration curve method and an isotope dilution method (ID) were applied for the determination of Nb and Ta, and of Zr and Hf, respectively. Recovery yields of HFSE were > 96% for peridotite, basalt and andesite compositions, apart from Zr and Hf for peridotite (> 85%). No matrix effects for either signal intensities of HFSE or isotope ratios of Zr and Hf were observed in basalt, andesite and peridotite solutions down to a dilution factor of 100. Detection limits in silicate rocks were 40, 2, 1 and 0.1 ng g-1 for Zr, Nb, Hf and Ta, respectively. This technique required only 0.1 ml of sample solution, and thus is suitable for analysing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates. We also present newly determined data for the Zr, Nb, Hf and Ta concentrations in USGS silicate reference materials DTS-1, PCC-1, BCR-1, BHVO-1 and AGV-1, GSJ reference materials JB-1, -2, -3, JA-1, -2 and -3, and the Smithsonian reference Allende powder.     

Petrography and Geochemistry of Peridotite Xenoliths from Hannuoba and Significance for Lithospheric Mantle Evolution

Mantle-derived xenoliths and xenocrysts in Pale-ozoic diamondiferous ki mberlites in Mengyin (Shan-dong Province) and Fuxian (Liaoning Province) showthe presence of a cold,thick lithospheric mantle be-neath the North China craton ( NCC) in the MiddleOrdovician ( Griffin et al ., 1998 ; Menzies et al .,1993 ;Fan and Menzies ,1992) . However ,studies onmantle peridotites captured in the Tertiary to Neo-gene basalts of the NCC have revealed the existenceof a thin, hot and fertile lithosph…     

地幔中自然铁-偏离正常矿物化学成分的矿物交生体与深源流-岩作用

报道了金伯利岩的橄榄岩捕虏体中自然铁－偏离正常矿物化学成分的矿物（ＮＳＭ）文象交生体的电子探针分析结果。该交生体可能是含自然铁和偏离正常矿物化学成分的方铁矿组合构成的深源流体作用于岩石圈地幔并经过固溶体分解的产物。     

大陆科学钻探先导孔（CCSD—P1）橄榄岩地幔属性及动力学意义

早中生代的扬子大陆向华北大陆的深俯冲碰撞作用以及中、新生代的华北东部岩石圈减薄作用是国际大陆动力学问题研究的两个热点。然而，把它们有机联系起来，探讨深部岩石圈演化动力学过程的研究还很少。报道了中国大陆科学钻探先导孔（CCSD-PP1）橄榄岩的矿物岩石化学分析结果。这些橄榄岩亏损玄武质组分（如低w（CaO＋Al2O3）、高Mg^#等），并经历了中元古代来自软流圈的碳酸岩熔体的交代作用和早中生代的超高压再平衡过程。结合已发表的华北捕虏体橄榄岩资料，对这一橄榄岩的原始地幔属性进行了分析。发现CCSD-PP1橄榄岩与华北古老岩石圈地幔组成相似，是早中生代来自华北岩石圈的构造侵入体。早中生代华北岩石圈的伸展减薄与苏鲁超高压变质岩石的折返提供了早期软流圈物质上涌的构造体制。     

内蒙古北山地区芨芨台子-小黄山蛇绿岩构造属性及与成矿关系:来自阿民乌素地幔橄榄岩印证

阿民乌素地幔橄榄岩属芨芨台子-小黄山蛇绿岩带一部分,该构造带南北两侧地质体无明显差异,不具分界断裂的构造特征。本文对阿民乌素地幔橄榄岩与月牙山地幔橄榄岩进行岩石化学、地球化学对比分析,为芨芨台子-小黄山蛇绿岩构造属性提供新依据,并对阿民乌素蛇绿岩成矿潜力进行分析研究。笔者所在团队在地幔橄榄岩上部的辉长岩中获得LA-ICP-MS锆石U-Pb同位素年龄值为462.5±3.2 Ma,属中奥陶世。其上发育奥陶纪-志留纪公婆泉组岛弧拉斑玄武岩。该期地幔橄榄岩轻重稀土之比LR/HR＝1.63~3.68, (La/Sm)N＝1.70~6.92,(Gd/Yb)N＝0.36~0.52,表明岩石轻稀土略富集,稀土配分曲线呈不规则“U”型,估算其为原始地幔橄榄岩经过10%~20%部分熔融的残留物。原始地幔标准化蛛网图富集高场强元素U、Zr、Hf、Yb和大离子亲石元素Rb、Sr,亏损高场强元素Nb、Ti和大离子亲石元素Ba。与月牙山地幔橄榄岩标准化蛛网图对比,最大区别在于阿民乌素地幔橄榄岩明显亏损高场强元素Ti。初步研究认为阿民乌素地幔橄榄岩属SSZ型、高压型蛇绿岩,是岛弧裂谷的产物。该橄榄岩具有形成大型铬铁矿的成矿构造背景,是寻找蛇绿岩型铬铁矿的有利部位。     

Alpine olivine- and titanian clinohumite-bearing assemblages in the Erro-Tobbio peridotite (Voltri Massif, NW Italy)

The microstructures in the Erro-Tobbio peridotite indicate several stages of recrystallization of olivine + titanian clinohumite-bearing assemblages. The development of these assemblages is closely associated with serpentinite mylonites, in which they occur in shear bands and foliations and are inferred to have grown synkinematically, in veins, and as post-kinematic radial aggregates. In the peridotite wall-rock adjacent to these mylonites, the same assemblages have recrystallized statically at the expense of original olivine and pyroxenes, mesh-textured chrysolite and antigorite veins. In addition, the olivine-bearing assemblage occurs in widespread vein systems. The brittle deformation of the peridotite resulting in the development of these vein systems is closely related to ductile deformation of metagabbroic dykes in the peridotite. Although early metasomatism resulted in extensive rodingitization of the gabbros, some dykes show an eclogitic assemblage of Na-clinopyroxene + garnet + chloritoid + chlorite ± talc. These observations, the microstructures and the mineral chemistry all suggest that the assemblages in the ultramafic rocks and metagabbros developed during a prograde evolution towards high pressures (>13–16 kbar, 450–550° C), and during subsequent decompression. This metamorphic evolution is considered to be related to Late Cretaceous intraoceanic subduction in the Alps-Apennine system and closure of the Piedmont-Ligurian basin.     

Mineral chemistry of spinel peridotite xenoliths from Baengnyeong Island, South Korea, and its implications for the paleogeotherm of the uppermost mantle

Abstract   The mantle-derived xenoliths entrained in the Pliocene basanite from Baengnyeong Island, South Korea, are spinel lherzolites and spinel harzburgites. The overall compositional range of the Baengnyeong xenoliths matches that of the post-Archean xenoliths of lithospheric mantle origin from eastern China, but without any compositional evidence for a refractory Archean mantle root. Mineral compositions of the xenoliths have been used to estimate the equilibrium temperatures and pressures, and to construct a paleogeothermal gradient of the source region. The xenolith-derived paleogeotherm is constrained from about 820°C at 7.3 kbar to 1000°C at 20.6 kbar. Like those from the post-Archean Chinese xenoliths of lithospheric mantle origin, the Baengnyeong geotherm is considerably elevated relative to the conductive models at the depth of the crust–mantle boundary, reflecting a thermal perturbation probably related to lithospheric thinning. There is no significant P / T difference between harzburgite and lherzolite, which suggests that the harzburgites are interlayered with lherzolites within the depth interval beneath Baengnyeong Island.