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1.
Anoop A. Krishnan P.K. Krishnakumar M. Rajagopalan 《Estuarine, Coastal and Shelf Science》2007,71(3-4):641-646
The incidence of a large scale Trichodesmium erythraeum bloom along the southwest coast of India (Arabian Sea) observed in May 2005 is reported. Around 4802 filaments of T. erythraeum ml−1 seawater was observed and a colony consisted of 3.6 × 105 cells. The bloom was predominant off Suratkal (12° 59′N and 74° 31′E) with a depth of about 47 m, covering an area of 7 km in length and 2 km width. The concentrations of Zinc, Cadmium, Lead, Copper, Nickel and Cobalt were determined in samples collected from the bloom and non-bloom sites using stripping voltammetry. The observed hydrographical and meteorological parameters were found to be favorable for the bloom. The concentrations of Zinc, Cadmium and Nickel were found to be higher at bloom stations, while the concentrations of Lead, Copper and Cobalt were found to be very low at bloom stations. Elevated concentrations of Cadmium and Cobalt were observed at Valappad mainly due to the decomposition of detrital material produced in the bloom. Statistically significant differences (P > 0.01) in metal concentrations between the bloom and non-bloom stations were not observed except for Copper. Metals such as Lead, Copper and Cobalt were removed from the seawater at all places where bloom was observed. Cadmium was found to be slowly released during the decaying process of the bloom. 相似文献
2.
Yoann Louis Cdric Garnier Vronique Lenoble Stphane Mounier Neven Cukrov Dario Omanovi Ivanka Pieta 《Marine Chemistry》2009,114(3-4):110-119
An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (Kiequ), total ligands concentration (LiT) and association/dissociation rate constants (ki1,ki- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K1equ: 11.2–13.0, log K2equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k11:6.1–20 × 103 (M s)− 1, k21: 1.3–6.3 × 103 (M s)− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µMC, i.e. 1 mgCL− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM). 相似文献
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Measurements of zinc and zinc complexation by natural organic ligands in the northeastern part of the Atlantic Ocean were made using cathodic stripping voltammetry with ligand competition. Total zinc concentrations ranged from 0.3 nM in surface waters to 2 nM at 2000 m for open-ocean waters, whilst nearer the English coast, zinc concentrations reached 1.5 nM in the upper water column. In open-ocean waters zinc speciation was dominated by complexation to a natural organic ligand with conditional stability constant (log KZnL′) ranging between 10.0 and 10.5 and with ligand concentrations ranging between 0.4 and 2.5 nM. The ligand was found to be uniformly distributed throughout the water column even though zinc concentrations increased with depth. Organic ligand concentrations measured in this study are similar to those published for the North Pacific. However the log KZnL′ values for the North Atlantic are almost and order of magnitude lower than those reported by Bruland [Bruland, K.W., 1989. Complexation of zinc by natural organic-ligands in the central North Pacific. Limnol. Oceanogr., 34, 269–285.] using anodic stripping voltammetry for the North Pacific. Free zinc ion concentrations were low in open-ocean waters (6–20 pM) but are not low enough to limit growth of a typical oceanic species of phytoplankton. 相似文献
5.
产自广东省梅州市玉水铜矿的景文矿,属于含水、重稀土-矾-铝硅酸盐矿物(简写为HREE-V-铝硅酸盐矿物),其化学结构式为Y2Al2V24+(SiO4)2O4(OH)4,该矿物在全球属首次发现,暂未开展相关研究。相对于含轻稀土矿物,含重稀土矿物在电子探针分析过程中,当被高压电子束轰击时,被激发出来的特征X射线线系繁多,线系之间分布更加密集,彼此之间相互重叠的现象也更为严重,要获得理想数据的难度很大,是亟待解决和突破的技术难题。本文对该矿物进行了精细的电子探针定量分析,获得理想的化学成分数据,为新矿物命名提供了理论数据技术支撑。通过对实验方法的探索和总结获得以下结果:①利用15kV加速电压、100nA束流对试样进行全元素扫描,以此确定出17种元素;②在定量分析过程中,对重叠峰进行了剥离;③利用仪器软件中的Zoom-Peak ID程序,选择出17种元素的分析线系、精确的峰位及上下背景值;④选取合适的标样及测试时间等定量分析条件,最终获得理想的定量分析结果(平均总量97.41wt%)。上述四条也是确保获得理想定量分析数据的关键因素。
相似文献6.
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柴达木盆地具有丰富的油气资源,柴北缘、柴西、粜东三湖地区分别以侏罗系、古近系、新近系和第四系为主要勘探目的层.随着北疆石炭系研究的进展和钻探的成功,石炭系已经成为中国西部地区重要的勘探层系,柴达木盆地的石炭系也引起了勘探家的注意,地面地质调查表明石炭系为柴达木盆地一套潜在烃源岩.为了落实石炭系在柴达木盆地内的分布,笔者充分利用近10年来在柴达木盆地及周缘完成的重、磁、电等资料进行了针对石炭系的资料解释、剥层反演和综合研究,明确了石炭系的分布特征,为柴达木盆地石炭系油气勘探指明了方向. 相似文献
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This study documents the stratigraphic evolution of the Castagnola ponded turbidite mini-basin through analysis of a detailed base-to-top section measured in the central part of the basin. Vertical variations in facies characteristics, thickness ratio of mud cap vs. sandstone of event beds and net/gross are argued to be good proxies for pinpointing the stratigraphic transition from dominantly ponded deposition, where most of the flow is trapped by the confining topography, to a flow-stripping – dominated phase in which an increasingly large part of incoming flows can escape the basin by spilling over the enclosing topography. Thickness statistics of sandstones and mud caps of event beds from the case study show that in the initial stage of turbidite deposition only part of the mud of exceptionally large volume flows escaped the confining topography; as the basin was progressively infilled, nearly all inbound flows were affected by flow stripping, with part of the sand and most of the mud escaping the basin. In the latest recorded stage of deposition the abundance of by-pass features coupled with significant modification of the sandstone bed thickness population suggests that the turbidite system was no longer obstructed frontally, and could step forward onto a healed topography. In order to assess whether the documented trends of turbidite bed characteristics indicative of the ‘fill to spill’ transition could be recognised from wireline log data alone, synthetic logs were prepared by up-scaling the field data to resolutions typical of borehole geophysical log data. Vertical trends of average bed thickness and net/gross recognisable in the synthetic data suggest that the transition from ponded to spill-dominated situations should be resolvable in geophysical log data. 相似文献
10.
渤海湾北部海域表层海水的表观铜络合容量 总被引:2,自引:1,他引:2
为给渤海湾北部海域重金属铜环境容量研究提供科学依据,采用阳极溶出伏安法对该海域12个站位表层海水样品的表观铜络合容量(ACuCC)和条件稳定常数(K)以及络合容量指数(CCI)进行了测定和计钟:。得到该海区表层海水的表观铜络合容量在228.0~673.4nmol/L之间,平均值为437.5nmol/L,条件稳定常数对数值(IgK)变化范围在7.41~8.84之间,平均值为7.89,络合容量指数在72.69%~92、92%之间,平均值为82.93%。表明该海域表层海水对重金属铜具有较强的络合能力。 相似文献