Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

THE POSITION AND ROLES OF PORTS AND RAILWAYS IN THE EURASIA LAND BRIDGE TRANSPORTATION IN NORTHEAST CHINA

This paper systematically analyzes and proves the favorable factors of utilizing the ports and the railways in Northeast China for the Asia-Europe land bridge transportation. It will be more beneficial to Dalian Port and HaDa (Harbin-Dalian) and Binzhou (Harbin-Manzhouli) railways in Northeast China to the Siberia railway in Russia than 1) to other ports and the corresponding railways in China, 2) to the Nakhodka Port in Russia and the corresponding railways and 3) to the Chongjin Port in North Korea and the corresponding railways. This paper also puts forward the reform measures to adopt the ports and the railways in the northeast region in China for the land bridge transportation and the problems in transportation policies and management systems.     

Canonical theory of perturbations using eccentric anomaly as independent variable

It is shown in this paper how to build a canonical transformation of variables, so that the eccentric anomaly becomes the new independent variable. In the case of eccentric elliptical orbits it changes the equations of motion so, that they can be integrated analytically to any order of approximation comparatively easy.     

中国1∶100万景观生态制图设计

中国1∶100万景观生态图系借鉴国内外传统景观制图方法和制图规范,在遥感、地理信息系统先进技术的支持下,设计研制其制图方法、制图内容、样图和技术流程,同时提出初步的景观分类系统,为今后编制中国1∶100万景观生态图奠定基础。