The Upper Devonian Kellwasser event recorded in a regressive sequence from inner shelf to lagoonal pond,Catalan Coastal Ranges,Spain

This study, conducted in the Catalan Coastal Ranges, north‐east Spain, describes the Upper Devonian Kellwasser event in a shallowing‐upward sequence of black shales, siltstones and quartz arenites. This sequence was deposited in a progradational and regressive coastal system where the sedimentary environment evolved from the inner shelf to a lagoonal pond located landward of the shoreline. Three anomalous succeeding steps have been identified by geochemical analysis. The first one, detected on the inner shelf, was characterized by oxygen depletion and high organic productivity. The second, detected in the nearshore, was caused by hydrothermal activity occurring under normal oxic conditions. The third and most intense step was identified in the muds of the lagoonal pond and has been linked to strong anoxic conditions, elevated clastic input derived from changes in the weathering regime at the source area and moderate hydrothermal activity. The Kellwasser event is thus defined in the study area as stepwise and multi‐causal. This is the first time that the Kellwasser event has been identified in a sedimentary environment behind the shoreline. It is also the first time that it has been reported in the Catalan Coastal Ranges.     

莱州湾南岸潍河下游地区咸水入侵灾害成因及特征

通过对莱州湾南岸咸水入侵较严重地潍河下游地区晚更新世以来沉积特征及现代自然环境条件变化的分析，探讨了沉积相对咸水入侵产生及空间范围特征的环境机理。晚更新世以来的三次海平面升降变化造成了潍河下游地区海陆沉积环境交替，形成了巨厚的海陆交互相沉积层。海进时期，大面积的滨海平原被淹没，在近海平原洼地滞留的海水经过蒸发、浓缩变为卤水，成为咸水入侵的物源；海退后陆源碎屑在滨海地区沉积形成了巨厚的古河道砂层。20世纪70年代末期以来，随着对地下淡水的过度开采，淡咸水水头压力差减小．卤水通过古河道砂层快速南侵。通过对潍河下游地区100余个地质钻孔水化学连续监测资料分析，阐明了咸水入侵的特征，有针对性地提出了咸水入侵的防治措施。     

平凉隐伏岩溶水环境同位素研究

地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性.     

地下洞库勘察中的深斜孔钻探和压水试验技术

青岛市黄岛区拟建设海底地下油气储藏库,前期地质勘察工作要求施工倾角45°、深220m的取心钻孔4个,并在孔内分段进行压水试验.本文介绍了如何利用XY-4型金刚石小口径钻机施工基岩深斜孔及压水试验技术.     

Optimization of grid-drilling using computer simulation

A computer simulation method has been developed to find efficient drilling grids for mineral deposits. A well-known ore deposit is used as a model to develop an efficient pattern for undiscovered ore bodies in the same area or in other prospects where similar geometry is suspected. The model for this study is the Austinville, Virginia deposit, a Mississippi Valley-type deposit composed of 17 ore bodies totaling 34 million short tons (30 million metric tons). The method employs a computer program that simulates drilling the model deposit with different patterns, including various levels of follow-up drilling. Follow-up holes are drilled in fences at one half the original spacing around holes in the grid that show ore-grade mineralization. Each pattern is drilled 100 times from random starting locations to provide a range of outcomes of drilling, including the best, worst, and most likely. For this study, patterns of 100 drill holes were composed of 10 fences spaced 1000–5000 feet (305–1524 m) apart, each with 10 holes spaced 200–1000 feet (61–305 m) apart. In all, 25 grids were used with zero to three levels of follow-up drilling. The 600/2000 grid, with drill holes spaced 600 feet (183 m) apart in fences spaced 2000 feet (610 m) apart, was compared with the 200/5000 grid because they represented contrasting outcomes. The 600/2000 grid penetrated many ore bodies consistently but with few multiple hits to individual ore bodies; whereas the 200/5000 grid inconsistently penetrated few ore bodies with many multiple hits. The 600/2000 grid was more efficient than the 200/5000 grid at hitting large ore bodies of 1,000,000 short tons or greater (900,000 metric tons or greater) and was made more effective by adding one cycle of follow-up drilling. The 600/2000 grid had a 97% chance of hitting one or more large ore bodies with at least one drill hole per ore body, and the 200/5000 grid had a 64% chance. Once hit, there was an 82% chance that the largest ore body would be penetrated by three or more holes when using the 600/2000 grid and an 88% chance using the 200/5000 grid.     

The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

Fluid infiltration during contact metamorphism of interbedded marble and calc-silicate hornfels, Twin Lakes area, central Sierra Nevada, California

Abstract In the Twin Lakes area, central Sierra Nevada, California, most contact metamorphosed marbles contain calcite + dolomite + forsterite ± diopside ± phlogopite ± tremolite, and most calc-silicate hornfelses contain calcite + diopside + wollastonite + quartz ± anorthite ± K-feldspar ± grossular ± titanite. Mineral-fluid equilibria involving calcite + dolomite + tremolite + diopside + forsterite in two marble samples and wollastonite + anorthite + quartz + grossular in three hornfels samples record P± 3 kbar and T± 630° C. Various isobaric univariant assemblages record CO₂-H₂O fluid compositions of χCO₂= 0.61–0.74 in the marbles and χCO₂= 0.11 in the hornfelses. Assuming a siliceous dolomitic limestone protolith consisting of dolomite + quartz ° Calcite ± K-feldspar ± muscovite ± rutile, all plausible prograde reaction pathways were deduced for marble and hornfels on isobaric T-XCO₂ diagrams in the model system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂. Progress of the prograde reactions was estimated from measured modes and mass-balance calculations. Time-integrated fluxes of reactive fluid which infiltrated samples were computed for a temperature gradient of 150 °C/km along the fluid flow path, calculated fluid compositions, and estimated reaction progress using the mass-continuity equation. Marbles and hornfelses record values in the range 0.1–3.6 × 10⁴ cm³/cm² and 4.8–12.9 × 10⁴ cm³/cm², respectively. For an estimated duration of metamorphism of 10⁵ years, average in situ metamorphic rock permeabilities, calculated from Darcy's Law, are 0.1–8 × 10^?6 D in the marbles and 10–27 × 10^?6 D in the hornfelses. Reactive metamorphic fluids flowed up-temperature, and were preferentially channellized in hornfelses relative to the marbles. These results appear to give a general characterization of hydrothermal activity during contact metamorphism of small pendants and screens (dimensions ± 1 km or less) associated with emplacement of the Sierra Nevada batholith.     

Contribution of storms to groundwater recharge in the semi‐arid region of Karnataka,India

This paper describes the application of environmental isotopes and injected tracer techniques in estimating the contribution of storms as well as annual precipitation to groundwater recharge and its circulation, in the semi‐arid region of Bagepalli, Kolar district, Karnataka. Environmental isotopes ²H, ¹⁸O and ³H were used to study the effect of storms on the hydrological system, and an isotope balance was used to compute the contribution of a storm component to the groundwater. Some of the groundwater samples collected during the post‐storm periods were highly depleted in stable isotope content with higher deuterium excess relative to groundwater from the pre‐storm periods. Significant variation in deuterium excess in groundwater from the same area, collected in two different periods, indicates the different origin of air masses. The estimated recharge component of a storm event of 600 mm to the groundwater was found to be in the range of 117–165 mm. There was no significant variation in environmental tritium content of post‐storm and pre‐storm groundwater, indicating the fast circulation of groundwater in the system. After completion of the environmental isotope work, an injected radiotracer ³H technique was applied to estimate the direct recharge of total precipitation to the groundwater. The estimated recharge to the groundwater is 33 mm of the 550 mm annual precipitation during 1992. Copyright © 2003 John Wiley & Sons, Ltd.     

ANALYSIS ON THE SPATIAL DISTRIBUTION VARIATION CHARACTERISTIC OF URBAN HEAT ENVIRONMENTAL QUALITY AND ITS MECHANISM——A Case Study of Hangzhou City

Urban heat environmental quality(UHEQ) is affected by the interacting of weather condition and underlying surface framework of urban area .In the last two decades,many researchers from domestic and overseas have studied many problems at the aspect of urban heat environment such as urban heat islands ,urban air temperature and their rela-tion with urban land cover,city population,air pollution etc,In the recent years,Hangzhou,acting as a center city of Zhejiang Province in China,its urbanization quantum and quantity have both changed greatly,in particular ,representing as business affairs building,resident real property and all kins of specialty market having arisen in built-up zone,Based on Landsat TM images data in 1991 and 1999,urban underlying surface temperature value and Normalized Difference Vegetation Index (NDVI) were calculated using image interpreting and supervised classification technique by remote sensing software ERDAS image 8.4,The relation model between urban underlying surface temperature (UUST )and urban air temperature was setup according to the certain correlation patten .Reference to the relational standard of assessing human comfort and other meteorology data of Hangzhou City in summer,the spatial distribution characteristic and the spatial varia-tion degree of human comfort of heat environmental quality are estimated and mapped on a middle scale,that is ,in six districts of Hangzhou City .Then the paper reveals the main characteristic of spatial variation from 1991 to 1999.Lastly,the change mechanism is analyzed and discussed from the viewpoint of city planning,construction and environmental protec-tion.