四川石棉独立碲矿床蚀变岩的地质地球化学研究

四川石棉大水沟独立碲矿床堪称世界首例，其矿体两侧的围岩蚀变较窄，且蚀变带与矿脉及未蚀变岩呈清楚而截然的接触关系。主要围岩蚀变为白云石化、白（绢）云母化、云英岩化及电气石化等。这些蚀变作用分别发生于１７７．７～１６５．１Ｍａ和９１．７１～８０．１９Ｍａ。蚀变作用过程中ＳｉＯ２大量析出，Ａｌ２Ｏ３、ＴｉＯ２、ＣａＯ、ＭｇＯ、Ｋ２Ｏ、Ｈ２Ｏ、ＣＯ２、Ｆｅ２Ｏ３、ＭｎＯ则有不同程度地带入。与此同时，ＲＥＥ在此过程中包集体迁出，Ｔｅ、Ｂｉ、ＡＳ等元素的含量则决定于蚀变作用及其强度，而与原岩无关。     

山东内生金矿矿床谱系及其致矿地质异常

矿床谱系是对成矿多样性的理论概括,而成矿多样性又是由不同级别、不同性质的致矿地质异常决定的.本文论述了山东省内生金矿矿床谱系及其致矿地质异常.     

凤太矿田层控铅锌(铜)矿床的成矿物质来源探讨

秦岭凤太矿田层控铅锌(铜)矿床的金属物质、硫和成矿溶液主要来自深部基底的岩石,属海底喷流—沉积成因矿床。从这一理论认识出发可进一步分析控矿地质条件及今后在该区有效地寻找同类矿床。     

黄金的成色

黄金的成色并不是一成不变的，它成色的高低是与成矿温度、成矿阶段、深度、时代、变质程度、水溶液及风化作用等有一定关系，我们从这些关系中可以寻找到我们找矿的捷径和依据。     

Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。     

内蒙古正蓝旗羊蹄子山-磨石山钛矿区硅质岩地球化学特征及沉积环境意义

文章通过详细的野外地质调查和系统的岩石化学、稀土元素、微量元素及硅、氧同位素等研究,探讨了羊蹄子山-磨石山钛矿区无矿白色硅质岩和富钛硅质岩的成因及形成地质构造环境。研究结果表明,呈厚层状产出的无矿白色硅质岩具较高的SiO2、Al2O3含量及Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值,稀土元素总量很低,其北美页岩标准化配分模式为向右倾的曲线,无明显铈异常和铕异常,表明其形成于受陆源影响的大陆边缘构造环境;赋矿岩系中薄层状富钛硅质岩的TiO2、Fe2O3、Cu、V含量较高,但Al/(Al Fe Mn)、Al2O3/(Al2O3 Fe2O3)比值较低,稀土元素总量较高,北美页岩标准化曲线为明显左倾型-平坦型,具弱的负铈异常,表明其形成于洋脊及附近环境。两种硅质岩的δ30Si值为变化较小的负值,与热水沉积和某些生物成因硅质岩的硅同位素组成相似,两者的δ18O值范围和平均值均相似。两类硅质岩的成因及形成构造环境不同,富钛硅质岩的地球化学特征表明,该矿床的形成与本区元古宙海底火山热液喷流作用有关。     

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。     

江西浒坑钨矿含矿石英脉的地质特征及成矿构造演化

位于赣西武功山地区的江西浒坑钨矿是一个大型石英脉型钨矿床,与赣南典型的“五层楼”模式不同,矿脉主要集中在岩体内接触带。含矿石英脉除了普通的块状构造以外,还普遍存在条带状构造。详细的野外编录和镜下研究表明含矿块状石英脉在形成后遭受不同程度的韧性剪切,从而形成不同成分的分异条带。剪切带以出现新生的面理和线理（拉伸线理）为特征。岩石学研究表明条带状矿石属于糜棱岩,具有丰富的塑性变形显微构造特征。通过对含矿石英脉的构造解析,认为与岩浆岩有关的原生节理系统基本上是同时形成的,沿节理充填的石英脉经历了长期的、多期次的构造运动,从而形成了复杂的石英脉和矿石类型。建立了原生节理形成→石英充填→韧性剪切发生→二期石英充填→脆性碎裂的矿区构造演化序列。韧性剪切作用的动力学背景可能是受后期岩浆侵入的影响,最后的脆性破裂应与区域上存在南北向的压应力有关。