The control of maturity and kerogen type on quantitative analytical pyrolysis data

Quantitative pyrolysis-gas chromatography has been performed on 96 kerogen samples isolated from 17 wells on the Norwegian Continental shelf. Petrographic and bulk geochemical measurements were also performed on the samples, and a combined data set of 117 variables for each sample was analysed using principal components analysis (PCA). This approach provides an objective and reproducible means of kerogen characterisation, which can be easily automated. In addition to objective kerogen characterisation and facile visualisation of facies and maturity related chemical trends, the method has the potential to allow objective prediction of key geochemical parameters such as maturity level from pyrogram data.     

长春地区粉质黏土导热系数与其物性参数相关性研究

为研究导热系数与影响因素之间的相关关系,建立导热系数的推算公式,以长春地区粉质黏土为研究对象,对原状土样的导热系数与其物理参数之间的相关性进行回归分析。制作9个重塑土样,测其相关的参数值,以验证回归方程的适用性。结果表明,回归分析建立导热系数与2个物理参数之间的关系式不成立;考虑天然密度、含水率和孔隙度为自变量,其分别对应的相关性系数T检验显著值(Sig)都0. 05,复决定系数为0. 886,建立的回归方程成立,自变量能准确解释因变量的变化,且含水率与导热系数呈负相关,天然密度和孔隙度呈正相关。重塑土样相关参数代入回归方程得到的导热系数值与实验实测值之间相对误差低于4%,验证了该回归方程的普遍性和适用性。     

海平面上升对长江三角洲海堤、航运和水资源的影响

分析了２０５０ 年长江三角洲地区相对海平面上升５０～７０ ｃｍ 时,将对该地区沿海海堤、航运及海岸带水资源的影响,并就相应的适应对策提出了建议。     

引黄水在北大港水库蓄存期水质咸化的研究

依据引黄水在北大港水库蓄存期水质咸化的事实以及传质理论,定性地分析了引黄水水质咸化的主要原因,包括盐碱土传质作用、蒸发浓缩作用以及风的扰动加速传质作用等.在北大港水库旁修建了一个模拟试验水池,进行了现场模拟试验研究.依据水量平衡和氯离子总量平衡的原理,分别定量地计算了传质作用和蒸发浓缩作用对水质咸化影响的比重.结果表明,在模拟水池蓄水后的30 d内,传质作用对水质咸化影响的比重有随时间增加而增长的趋势;30 d后,传质作用对水质咸化影响的比重稳定在80%,蒸发浓缩作用对水质咸化影响的比重稳定在20%,说明导致水质咸化的最主要因素是盐碱土传质作用.     

Integrating lysimeter drainage and eddy covariance flux measurements in a groundwater recharge model

Abstract

Field-scale water balance is difficult to characterize because controls exerted by soils and vegetation are mostly inferred from local-scale measurements with relatively small support volumes. Eddy covariance flux and lysimeters have been used to infer and evaluate field-scale water balances because they have larger footprint areas than local soil moisture measurements. This study quantifies heterogeneity of soil deep drainage (D) in four 12.5-m² repacked lysimeters, compares evapotranspiration from eddy covariance (ET_EC) and mass balance residuals of lysimeters (ETwb_Lys), and models D to estimate groundwater recharge. Variation in measured D was attributed to redirection of snowmelt infiltration and differences in lysimeter hydraulic properties caused by surface soil treatment. During the growing seasons of 2010, 2011 and 2012, ETwb_Lys (278, 289 and 269 mm, respectively) was in good agreement with ET_EC (298, 301 and 335 mm). Annual recharge estimated from modelled D was 486, 624 and 613 mm for three calendar years 2010, 2011 and 2012, respectively. In summary, lysimeter D and ET_EC can be integrated to estimate and model groundwater recharge.

Editor D. Koutsoyiannis     

Impacts of systematic precipitation bias on simulations of water and energy balances in Northwest America

At high latitudes and in mountainous areas, evaluation and validation of water and energy flux simu-lations are greatly affected by systematic precipitation errors. These errors mainly come from topographic effects and undercatch of precipitation gauges. In this study, the Land Dynamics （LAD） land surface model is used to investigate impacts of systematic precipitation bias from topography and wind-blowing on water and energy flux simulation in Northwest America. The results show that topographic and wind adjustment reduced bias of streamflow simulations when compared with observed streamflow at 14 basins. These systematic biases resulted in a -50%-100% bias for runoff simulations, a -20%-20% bias for evapotranspiration, and a -40%-40% bias for sensible heat flux, subject to different locations and adjustments, when compared with the control run. Uncertain gauge adjustment leads to a 25% uncertainty for precipitation, a 20% 100% uncertainty for runoff simulation, a less-than-10% uncertainty for evapotranspiration, and a less-than-20% uncertainty for sensible heat flux.     

离子色谱法测定夏县温泉水中阴离子含量

利用离子色谱法对水中常见的7种阴离子进行定性和定量的分析,在既定的条件下,分别建立校正曲线法(外标法)及单点校正法模板,并对温泉水样校正分析。结果显示,外标法测得离子数据较为平稳,相对偏差均小于5%,适用于观测温泉水中其含量的变化。     

利用微波辐射计AMSR-E反演陆地上空大气水汽的研究

目前的大气水汽算法只适用于晴空条件,但是全球大部分时间云层覆盖都处于40%～60%之间。因此,只适用于晴空条件下的大气水汽反演算法,是不能满足应用需求的。而微波具有一定的穿透能力这一特点,使得其在全天候大气水汽探测方面具有很大的发展潜力。本文发展了基于微波辐射计AMSR-E的数据反演大气水汽的算法,利用不同波段间地表发射率之间的线性关系,消去辐射计信号中的地表信息,而AMSR-E的23.8GHz对大气水汽比较敏感,因此用其反演大气水汽,反演的结果和MODIS以及实测的数据进行对比,算法优势明显。     

黑河干流拟建水利工程对下游生态环境的影响分析

依据典型年份实际调查资料和以往研究成果, 采用地下水均衡方法, 定量对比分析了黑河拟建水利工程对下游地区地下水资源变化趋势, 并利用Visual Modflow三维地下水非稳定流软件系统模型对下游盆地未来20 a(2008—2028年)地下水位及其生态环境变化趋势进行了预测.结果表明: 在拟建工程实施20 a后黑河下游地下水位总体上处于下降趋势, 但下降幅度呈逐年减少状态直至趋于新的动态平衡.金塔-鼎新盆地地下水位下降幅度最大的地段是黑河沿岸为0.51~0.87 m, 但由于人工农业绿洲补充, 故生态环境不会有大的改变.额济纳盆地地下水位下降幅度最大的地段是古日乃及外围, 分别为1.0 m以上和0.5~1.0 m, 将引起植被的衰亡和种群的更替变化; 大部分地段地下水位下降幅度介于0.0~0.50 m之间, 对现有的生态与环境影响不显著; 桃来三达-额济纳旗以北地下水位呈现上升趋势, 上升幅度为0.10~0.87 m, 东居延海一带上升幅度大于0.87 m, 这一地区植被长势趋于良好, 植被覆盖率会有所增加, 将形成围绕海子的天然绿洲.     

黄河三角洲地下水动态变化及其与地面沉降的关系

为了分析黄河三角洲地下水动态及其与地面沉降的关系, 利用多年地下水和地面沉降监测数据, 发现黄河三角洲广饶县和东营区的地下水动态变化剧烈且地面沉降严重, 含水层多处于超采状态, 浅、深层地下水降落漏斗先后出现.深层地下水降落漏斗中心水位下降速度达2~3m/a.近年来, 东营和广饶地面沉降漏斗中心沉降量和速率分别为155.1mm、28.2mm/a和356.0mm、64.7mm/a.借助GIS技术及数理统计法, 发现深层地下水降落漏斗与沉降漏斗空间耦合良好, 深层地下水位与地面高程呈线性正相关, 相关系数为0.92, 深层地下水过度开采已成为影响沉降的最根本因素.井灌区第三粘性压缩层成为地面沉降主要贡献层, 且深层地下水降落漏斗中心的地下水位已低于第三承压含水层临界水位, 沉降趋于严重.