水质关键因素光谱遥感监测技术分析

针对传统水体水质分析方法过度依赖于实地测量和实验室化学分析,需要耗费大量人力物力且效率不高的问题,从水质遥感监测数据获取手段、典型反演监测模型、不同水体光谱遥感监测应用状况、水质遥感监测技术应用及前景等方面分析归纳了使用遥感技术监测水质的新方法。从可用数据类型、数据特征等方面对水质遥感监测数据获取的3种主要手段进行了比较;从复杂程度、使用场景、优缺点等方面对4种典型的反演模型进行了归纳;对遥感数据和模型在Ⅰ类和Ⅱ类水体应用中的常用组合方式进行了分析总结。     

面向蓝藻的洱海气象监测站布局方法

针对洱海流域蓝藻预警研究所需的气象数据不足的问题,提出洱海气象监测站优化布局方法,采用环境影响统计概念模型分析了对环境产生影响的主要经济因素,根据水体污染指标将洱海各个行政区分为高污染区和低污染区,再考虑汇入洱海支流是否流经高污染区,认为在高污染区支流汇入口是蓝藻发生概率较高的区域。依据2个主要参数:区域污染程度和支流入口,部署气象监测站,该监测站能为洱海蓝藻预警研究提供必要、准确和可靠的水面气温、降雨量以及日照长度等气象参数,将对水环境的监测和研究具有重大意义和广泛应用前景。     

Monitoring of water stress in wheat using multispectral indices derived from Landsat-TM

Detection of crop water stress is crucial for efficient irrigation water management. Potential of Satellite data to provide spatial and temporal dynamics of crop growth conditions makes it possible to monitor crop water stress at regional level. This study was conducted in parts of western Uttar Pradesh and Haryana. Multi-temporal Landsat data were used for detecting wheat crop water stress using vegetation indices (VIs), viz. vegetation water stress index (VWSI) and land surface wetness index water stress factor (Ws_LSWI). The estimated water stress from satellite data-based VIs was validated by water stress factor (Ws) derived from flux-tower data. The study observed Ws_LSWI to be better index for water stress detection. The results indicated that Ws_LSWI was superior over other index showing RMSE = 0.12, R² = 0.65, whereas VWSI showed overestimated values with mean RD 4%.     

Origin and evolution of geothermal fluids from Las Tres Vírgenes and Cerro Prieto fields,Mexico – Co-genetic volcanic activity and paleoclimatic constraints

Major and trace elements, noble gases, and stable (δD, δ¹⁸O) and cosmogenic (³H, ¹⁴C) isotopes were measured from geothermal fluids in two adjacent geothermal areas in NW-Mexico, Las Tres Vírgenes (LTV) and Cerro Prieto (CP). The goal is to trace the origin of reservoir fluids and to place paleoclimate and structural-volcanic constraints in the region. Measured ³He/⁴He (R) ratios normalized to the atmospheric value (R_a = 1.386 × 10⁻⁶) vary between 2.73 and 4.77 and are compatible with mixing between a mantle component varying between 42 and 77% of mantle helium and a crustal, radiogenic He component with contributions varying between 23% and 58%. Apparent U–Th/⁴He ages for CP fluids (0.7–7 Ma) suggest the presence of a sustained ⁴He flux from a granitic basement or from mixing with connate brines, deposited during the Colorado River delta formation (1.5–3 Ma). Radiogenic in situ ⁴He production age modeling at LTV, combined with the presence of radiogenic carbon (1.89 ± 0.11 pmC – 35.61 ± 0.28 pmC) and the absence of tritium strongly suggest the Quaternary infiltration of meteoric water into the LTV geothermal reservoir, ranging between 4 and 31 ka BP. The present geochemical heterogeneity of LTV fluids can be reconstructed by mixing Late Pleistocene – Early Holocene meteoric water (58–75%) with a fossil seawater component (25–42%), as evidenced by Br/Cl and stable isotope trends. CP geothermal water is composed of infiltrated Colorado River water with a minor impact by halite dissolution, whereas a vapor-dominated sample is composed of Colorado River water and vapor from deeper levels. δD values for the LTV meteoric end-member, which are 20‰–44‰ depleted with respect to present-day precipitation, as well as calculated annual paleotemperatures 6.9–13.6 °C lower than present average temperatures in Baja California point to the presence of humid and cooler climatic conditions in the Baja California peninsula during the final stage of the Last Glacial Pluvial period. Quaternary recharge of the LTV geothermal reservoir is related to elevated precipitation rates during cooler-humid climate intervals in the Late Pleistocene and Early Holocene. The probable replacement of connate water or pore fluids by infiltrating surface water might have been triggered by enhanced fracture and fault permeability through contemporaneous tectonic–volcanic activity in the Las Tres Vírgenes region. Fast hydrothermal alteration processes caused a secondary, positive δ¹⁸O-shift from 4‰ to 6‰ for LTV and from 2‰ to 4‰ for CP geothermal fluids since the Late Glacial infiltration.     

Deciphering As and Cu cycling in sediment pore waters in a large marina (Port Camargue,southern France) using a multi-tracer (Fe,Mn, U,Mo) approach

The sediments of the Port Camargue marina (South of France) are highly polluted by Cu and As (Briant et al., 2013). The dynamics of these pollutants in pore waters was investigated using redox tracers (sulfides, Fe, Mn, U, Mo) to better constrain the redox conditions.In summer, pore water profiles showed a steep redox gradient in the top 24 cm with the reduction of Fe and Mn oxy-hydroxides at the sediment water interface (SWI) and of sulfate immediately below. Below a depth of 24 cm, the Fe, Mn, Mo and U profiles in pore waters reflected Fe and Mn reducing conditions and, unlike in the overlying levels, sulfidic conditions were not observed. This unusual redox zonation was attributed to the occurrence of two distinct sediment layers: an upper layer comprising muddy organic-rich sediments underlain by a layer of relatively sandy and organic-poor sediments. The sandy sediments were in place before the building of the marina, whereas the muddy layer was deposited later. In the muddy layer, large quantities of Fe and Mo were removed in summer linked to the formation of insoluble sulfide phases. Mn, which can adsorb on Fe-sulfides or precipitate with carbonates, was also removed from pore waters. Uranium was removed probably through reduction and adsorption onto particles. In winter, in the absence of detectable pore water sulfides, removal of Mo was moderate compared to summer.Cu was released into solution at the sediment water interface but was efficiently trapped by the muddy layer, probably by precipitation with sulfides. Due to efficient trapping, today the Cu sediment profile reflects the increase in its use as a biocide in antifouling paints over the last 40 years.In the sandy layer, Fe, Mn, Mo and As were released into solution and diffused toward the top of the profile. They precipitated at the boundary between the muddy and sandy layers. This precipitation accounts for the high (75 μg g⁻¹) As concentrations measured in the sediments at a depth of 24 cm.     

青藏高原地区云水时空变化特征及其与降水的联系

利用1984-2009年ISCCP的云量、云光学厚度(COT)、云水路径(CWP)资料,分析了青藏高原云水的分布特征、变化趋势,及其与夏秋季降水、冬春季降雪的联系.结果表明:青藏高原地区大气中的云水有着显著的季节变化与水平分布差异;青藏高原春夏季总云量、高云云量高于秋冬季,CWP、COT与总云量的分布特征具有较好的一致性.高原云量高值区位于喀喇昆仑山与高原东南部;可可西里地区由于羌塘高压的下沉作用为云量低值区.青藏高原总云量在1984-2009年间呈现减少趋势;而CWP在高原总体以增加为主,但在各区域上的变化不一致,高原东部CWP增加而西部出现较弱的减小,这与来自孟加拉湾的水汽输送增加有关.青藏高原中东部地区夏秋季降水受云量减少影响较小而与CWP的增加相一致呈增长趋势;该地区冬春季降雪略有减少,与总云量的年际变化具有正相关.     

鄂尔多斯盆地晚三叠世延长期古湖盆生物相带划分及地质意义

鄂尔多斯盆地晚三叠世发育大型坳陷型湖盆。湖水的升降影响着湖盆水体面积的大小、深浅以及沉积体系发育分布,进而影响全盆地晚三叠延长统地层生储盖组合的发育特征。通过野外剖面、钻井岩芯中古生物化石的鉴定,结合古生物组合特征对鄂尔多斯盆地晚三叠世湖盆的古生物生态环境进行了恢复。确定鄂尔多斯晚三叠世湖盆是一个最大水深不超过60 m的浅水湖盆,属于温暖潮湿的淡水-半咸水环境。从湖岸到湖心,可以划分为预测古水深1～2 m的河流-沼泽生物相带;预测古水深3～15 m的滨岸-河口三角洲生物相带;预测古水深15～35 m的浅湖生物相带;预测古水深在35～60 m范围的半-深湖生物相带。这些生物相带的划分,为恢复鄂尔多斯盆地晚三叠世时期的岩相古地理奠定了基础,为盆地延长组沉积边界、盆地内沉积体系发育展布以及沉积相带的划分提供了坚实的地质依据,具有理论与实际意义。     

The genus Perissocytheridea Stephenson, 1938 (Crustacea: Ostracoda) and evidence of brackish water facies along the Oligo-Miocene,Pirabas Formation,eastern Amazonia,Brazil

Perissocytheridea Stephenson is characteristic of brackish water facies. In 57 samples from the Upper Oligocene to Lower Miocene, from five localities, Pirabas Formation, Pará State, Brazil eleven species have been identified. Among these species, four are new reports: Perissocytheridea punctoreticulata n. sp., Perissocytheridea largulateralis n. sp., Perissocytheridea colini n. sp. and Perissocytheridea pirabensis n. sp.; five species in open nomenclature: Perissocytheridea sp. 1, P. sp. 2, P. sp. 3, P. sp. 4, and P. sp. 5 and two species left in “aff.” abbreviation: Perissocytheridea aff. Perissocytheridea pumila and Perissocytheridea aff. Perissocytheridea brachyforma subsp. excavata. The distributional pattern of the Perissocytheridea combined with the occurrence of foraminifera Elphidium and Ammonia in the studied sections supports the presence of the brackish water facies to the respective layers. Their quantitative variation through the studied sections indicate more than one phase of salinity reduction (about >5 and <30 ppm) and/or the decrease of the sea level, forming lagoon along the Pirabas Formation. This genus has a wide paleobiogeographical occurrence and stratigraphic distribution ranging from the Cretaceous to Recent, and already been recorded in the northern of South America, especially in the Neogene of Solimões Basin, but this is the first report of a neotropical genus to the Oligo-Miocene deposits of Pirabas Formation, northern Brazilian Coast, Pará State.     

Reaction time scales for sulphate reduction in sediments of acidic pit lakes and its relation to in-lake acidity neutralisation

Sulphate reduction is a key reaction to remove acidity from water bodies affected by acid mine drainage. In this study, ³⁵SSO₄²⁻ reduction rates determined in sediments from a variety of acidic lignite pit lakes have been compiled. The rates decreased with pH and are strongly dependent on carbon substrate. The rates were fitted to a Monod model adapted to the specific conditions of acidic pit lakes (APL) sediments: i) sulphate reduction rate is independent from sulphate concentration due to the high concentration typically observed in APL systems (10–30 mM), ii) the observed pH dependency of sulphate reduction was accounted for by an inhibition function F_inihibt which considers the occurrence of low cell numbers of sulphate reducing bacteria at pH values < 4.75. Simulated steady-state sulphate reduction rates are predicting measured rates at carbon substrate concentrations of <10 μM. Estimated steady-state reaction time scales range between 2.4 h at pH 7 and 41 h at pH 3 at a carbon half-saturation constant of K_C−S = 100 μM and are increasing with increasing K_C−S values. Time scales at low pH are too long to allow for significant generation of alkalinity during the time of residence of groundwater passing through the top and hence most reactive zone of APL sediments which has important implications for the remediation of acidic pit lakes.     

早白垩世泥炭地净初级生产力及其控制因素--来自二连盆地吉尔嘎郎图凹陷6号煤的证据

现代泥炭地中蕴藏着巨量的碳,泥炭地生产力的高低会影响全球碳循环及全球气候变化。前人对全新世以来泥炭地生产力做了大量研究,但对前第四纪的“深时”阶段的泥炭地生产力则极少涉及,其主要原因是缺少精确的定年方法。以二连盆地吉尔嘎郎图凹陷早白垩世6号煤为例,利用地球物理测井信号进行频谱分析并获得煤层中米兰科维奇旋回周期参数（123 ka（偏心率）:38.1 ka（斜率）:22.1 ka（岁差））,将米兰科维奇旋回作为“深时”地层时间的“度量”工具,计算出6号煤层碳的聚集速率为35.1~38.9 g C/（m2·a）,进一步推算出其所代表的泥炭地的碳聚集速率为46.2~51.2 g C/（m2·a）,净初级生产力（NPP）为231~256 g C/（m2·a）。将该计算结果与全新世同一纬度带泥炭地生产力水平比较,并结合前人研究成果综合分析影响因素,得出早白垩世泥炭地生产力水平主要受温度和大气中二氧化碳含量控制,而这两种因素又与气候相关联,则泥炭地生产力的研究可能对进一步了解古气候提供帮助。