Experimental Petrology of the 1991-1995 Unzen Dacite, Japan. Part II: Cl/OH Partitioning between Hornblende and Melt and its Implications for the Origin of Oscillatory Zoning of Hornblende Phenocrysts

High-temperature–pressure experiments were carried outto determine the chlorine–hydroxyl exchange partitioncoefficient between hornblende and melt in the 1992 Unzen dacite.Cl in hornblende and melt was analyzed by electron microprobe,whereas OH in hornblende and melt was calculated assuming anionstoichiometry of hornblende and utilizing the dissociation reactionconstant for H₂O + O = 2(OH) in water-saturated melt, respectively.The partition coefficient strongly depends on the Mg/(Mg + Fe)ratio of hornblende, and is expressed as ln K₁ = (Cl/OH)_hb/(Cl/OH)_melt= 2·37 – 4·6[Mg/(Mg + Fe)]_hb at 2–3kbar and 800–850°C. The twofold variation in Cl contentin the oscillatory zoned cores of hornblende phenocrysts inthe 1991–1995 dacite cannot be explained by the dependenceof the Cl/OH partition coefficient on the Mg/(Mg + Fe)_hb ratio,and requires c. 80% variation of the Cl/OH ratio of the coexistingmelt. Available experimental data at 200 MPa on Cl/OH fractionationbetween fluid and melt suggest that c. 1·2–1·8wt % degassing of water from the magma can explain the required80% variation in the Cl/OH ratio of the melt. The negative correlationbetween Al content and Mg/(Mg + Fe) ratio in the oscillatoryzoned cores of the hornblende phenocrysts is consistent withrepeated influx and convective degassing of the fluid phasein the magma chamber. KEY WORDS: chlorine; element partitioning; hornblende; oscillatory zoning; Unzen volcano     

信阳市燃气混气站断裂活动性和场地稳定性系统研究

运用多学科、多手段相结合的方法，从区域构造稳定性、构造岩研究、构造裂隙统计分析、红外相位法位移监测，高密度电阻率法、钻探验证、年代学研究、新构造运动分析、遥感图像解译、地震安全性评价、数值模拟、工程地质条件分析等方面入手，对信阳市燃气混气站的断裂活动性和场地稳定性进行了全面而系统的论证；指出场区断裂规模小，第四纪无大规模差异升降运动，无活动断裂通过，邻区地震活动小且弱，区域构造稳定性高，应力平缓，工程地质条件良好，是一个稳定的“岛区”，井指出系统而全面的综合研究方法是研究工程稳定性项目行之有效的手段。     

矿物表面活性及其量度

矿物及其材料的表面活性及其表面反应性的具体表征，它是由矿物表面功能基所控制。由于矿物表面金属原子的电负性不同，以及它所处的配位环境不同，常表现出不同的极性、荷电性和Lewis酸碱性，它与溶质和溶剂分子之间反应（成键）能力也不同。在热力学上表现为反应自由能变化也不同。因此，量度矿物表面活性就是量度其表面极性、荷电性和Lewis酸碱性，它既可用化学方法，也可用热力学的方法。前者是通过反应作用量来量度，后者通过反应作用能来量度。然而现代矿物谱学的方法更能给出矿物及其材料表面反应活性的本质和详细信息。     

相山邹家山铀矿区某钻孔岩心高光谱蚀变矿物特征及地质意义

文章基于高光谱蚀变矿物提取方法,利用邹家山地区某钻孔岩心的高光谱数据进行蚀变矿物提取和编录,提取的蚀变矿物主要有富铝水云母、贫铝水云母、绿泥石、蒙脱石、碳酸盐、地开石、高岭石。其中水云母化、绿泥石化、赤铁矿化与铀矿化密切相关;富铝水云母在钻孔上部含量多而下部含量减少;贫铝水云母在钻孔上部含量少,而在下部尤其是矿化段含量明显增多,不同蚀变矿物分布形态不同且不同部位蚀变矿物组合不同,反映了矿区经历了不同期次和性质的热液活动。     

下扬子区新生代断陷盆地的断裂构造特征与活动规律

下扬子海陆域新生代沉积盆地是中国东部主要含油气盆地之一,成盆断裂特征与活动规律是该区油气勘探研究的基 础。文章基于高覆盖率的地震勘探测线,以构造断裂解析为突破口,探究盆地断裂的变形特征与活动规律。依据断裂组合 样式与构造活动特征,断裂可分为伸展、走滑、挤压-反转三种样式,构造活动分为伸展断裂与伸展-走滑断裂两种构造 体系。成盆断裂显著受控于郯庐断裂右行走滑变形,主要与郯庐断裂带不同构造走向的区段位置和与郯庐断裂带的距离这 两个因素或变量有关,盆地断裂呈现了“东西有别,中部不同”的特点。下扬子区新生代多变应力场,控制着作为油气运 移通道断裂的开闭状态,是油气资源评价的重要依据。     

Petrology and Geochemistry of the Volcanic Rocks Dredged from the Geophysicist Seamount in the Kurile Basin: Evidence for the Existence of Thinned Continental Crust

Dredged samples from the Geophysicist seamount volcano in the northeastern part of the Kurile Basin include volcanic and volcanoclastic rocks ranging from basalt to andesite. The rocks have geochemical features typical of high-K island-arc calc-alkaline volcanism. They are enriched in LILE and depleted in Zr, Ti, Nb, Ta and Y. The chondrite-normalized REE patterns are characterized by enrichment of LREE similar to those of island-arc lava from the submarine volcanoes of rear-arc zone of the Kurile Island Arc. The volcanic rocks have a wide range of ⁸⁷Sr/⁸⁶Sr ratios (0.70287-0.70652), varying ¹⁴³Nd/¹⁴⁴Nd and Pb isotopic ratios. Their trace-element compositions and Sr-Nd-Pb isotope signatures may be explained by a small addition of crustal continental component to mantle-derived magmas that suggest the existence of thinned continental basement under the eastern part of the Kurile Basin.     

湖北襄樊-广济断裂第四纪活动特征初步探讨

利用近年在襄樊-广济断裂研究中获得的有关资料,对该断裂第四纪以来的活动特征进行了初步分析,认为断裂3个几何段自第四纪以来均有不同程度的活动,断层切割地貌面、断层带物质的TL、ESR法年龄结果多集中分布在700～300 ka之间(平均值约500 ka),说明襄樊-广济断裂在第四纪中更新世早中期有过明显活动.历史及现今地震...     

Generation of Porphyritic and Equigranular Mafic Enclaves During Magma Recharge Events at Unzen Volcano, Japan

Mafic to intermediate enclaves are evenly distributed throughoutthe dacitic 1991–1995 lava sequence of Unzen volcano,Japan, representing hundreds of mafic recharge events over thelife of the volcano. This study documents the morphological,textural, chemical, and petrological characteristics of theenclaves and coexisting silicic host lavas. The eruptive productsdescribed in this study appear to be general products of magmamingling, as the same textural types are seen at many othervolcanoes. Two types of magmatic enclaves, referred to as Porphyriticand Equigranular, are easily distinguished texturally. Porphyriticenclaves display a wide range in composition from basalt toandesite, are glass-rich, spherical and porphyritic, and containlarge, resorbed, plagioclase phenocrysts in a matrix of acicularcrystals and glass. Equigranular enclaves are andesitic, non-porphyritic,and consist of tabular, medium-grained microphenocrysts in amatrix glass that is in equilibrium with the host dacite magma.Porphyritic enclaves are produced when intruding basaltic magmaengulfs melt and phenocrysts of resident silicic magma at theirmutual interface. Equigranular enclaves are a product of a moreprolonged mixing and gradual crystallization at a slower coolingrate within the interior of the mafic intrusion. KEY WORDS: mafic enclaves; quenched mafic inclusions; magma mingling; Unzen volcano; Unzen Scientific Drilling Project; resorbed plagioclase     

石家庄市地下水中氮污染分析

通过对石家庄市地下水中“三氮”污染状况的分析，发现硝酸盐是地下水中的主要氮污染物，利用氮同位素方法分析了地下水中硝酸盐氮的来源，讨论了人类开采地下水和施放环境物质对地下水中氮聚集的影响，在人类活动影响强度小的地区，地下水中的硝酸盐污染强度大大低于市区。NO3-浓度与硬度变化趋势表明：氮污染与硬度等指标值升高有一定的联系，但在不同的水文地球化学环境中，在迁移和转化等方面又有着自己的特性。     

青藏高原新生代岩浆活动与地热关系探讨

青藏高原地热资源丰富,具有分布广、温度高、潜力大等特点。为了更好地评价该区地热资源潜力,探索符合青藏高原地热资源特点的勘查、开发方案,需要对地热资源分布规律及成因进行研究。在总结前人对青藏高原新生代岩浆活动和地热资源特征的基础上,从青藏高原地质演化的角度分析地热资源分布的控制因素,探讨新生代岩浆活动与地热资源的空间展布关系,重点讨论藏南地区地热区划和雅鲁藏布缝合带岩浆活动之间的关系。结果表明: 青藏高原地热活动受控于地质构造演化,具有南强北弱的分布特点; EW向区域性构造缝合带和SN向深大断裂的交汇部位是地热的主要活跃区域,不同的岩浆活动为地热提供热源。