Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

Aspherical correction for free vibration of elastically anisotropic solid by means of theXYZ algorithm

By applying the perturbation theory to theXYZ algorithm (a kind of variational method), the difference f in free vibration frequencies between sphere and ellipsoid was approximated as , where i and _i (i = x,y andz) (i=x, y andz) are aspherical coefficients and asphericities of the ellipsoid, respectively. We developed an analytic method to compute the aspherical coefficients719-4 by using theXYZ algorithm. A numerical example was given for an ellipsoidal olivine, and an attempt was made to estimate the asphericities of the specimen by a least-squares method, based on the relationship between frequency shift and asphericity.     

Environmental impacts of bench blasting at Hisarcik Boron open pit mine in Turkey

This paper presents the results of ground vibration measurements carried out in Hisarcik Boron open pit mine located on the west side of central Anatolia near Kütahya province in Turkey. Within the scope of this study to predict peak particle velocity (PPV) level for this site, ground vibration components were measured for 304 shots during bench blasting. In blasting operations, ANFO (blasting agent), gelatin dynamite (priming), and delay electric detonators (firing) were used as explosives. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured for all blast events using two different types of vibration monitors (one White Mini-Seis and one Instantel Minimate Plus Model). The absolute distances between shot points and monitor stations were determined using GPS. The equation of square root scaled distance extensively used in the literature was taken into consideration for the prediction of PPV. Then, the data pairs of scaled distance and particle velocity obtained from the 565 event records were analyzed statistically. At the end of statistical evaluation of the data pairs, an empirical relation which gives 50% prediction line with a reasonable correlation coefficient was established between PPV and scaled distance.     

激光剥蚀等离子体质谱分析中激光剥蚀参数对信号响应的影响

探讨了激光剥蚀等离子体质谱固体微区分析中激光剥蚀参数对元素分析信号灵敏度及稳定性的影响。这些参数包括激光功率、脉冲频率、剥蚀孔经、散焦距离、剥蚀方式等。讨论了优化的激光剥蚀等离子体质谱信号采集及数据处理方式。在全质量范围内选用具有代表性的元素作为研究对象,建立了激光剥蚀的一般性特征规律和266nm紫外激光系统的最佳操作条件。在选定的激光剥蚀参数下,大多数被测元素的检出限为22.8~457ng/g,能够满足固体微区分析的要求。     

超声与振荡提取沉积物中松散结合态磷的比较

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。     

Multi‐objective optimal design of FLC driven hybrid mass damper for seismically excited structures

Structural vibration control using active or passive control strategy is a viable technology for enhancing structural functionality and safety against natural hazards such as strong earthquakes and high wind gusts. Both the active and passive control systems have their limitations. The passive control system has limited capability to control the structural response whereas the active control system depends on external power. The power requirement for active control of civil engineering structures is usually quite high. Thus, a hybrid control system is a viable solution to alleviate some of the limitations. In this paper a multi‐objective optimal design of a hybrid control system for seismically excited building structures has been proposed. A tuned mass damper (TMD) and an active mass driver (AMD) have been used as the passive and active control components of the hybrid control system, respectively. A fuzzy logic controller (FLC) has been used to drive the AMD as the FLC has inherent robustness and ability to handle the non‐linearities and uncertainties. The genetic algorithm has been used for the optimization of the control system. Peak acceleration and displacement responses non‐dimensionalized with respect to the uncontrolled peak acceleration and displacement responses, respectively, have been used as the two objectives of the multi‐objective optimization problem. The proposed design approach for an optimum hybrid mass damper (HMD) system, driven by FLC has been demonstrated with the help of a numerical example. It is shown that the optimum values of the design parameters of the hybrid control system can be determined without specifying the modes to be controlled. The proposed FLC driven HMD has been found to be very effective for vibration control of seismically excited buildings in comparison with the available results for the same example structure but with a different optimal absorber. Copyright © 2002 John Wiley & Sons, Ltd.     

Probabilistic analysis of peak response of MDOF systems with uncertain PSD function

The use of uniform hazard spectra which have the same probability of exceedance at different frequencies has been proposed for the future version of the National Building Code of Canada. Commonly used combination rules to estimate the peak responses of multi‐degree‐of‐freedom (MDOF) systems are the square root of sum of squares rule and the complete quadratic combination rule. However, the probability that the peak response of a MDOF system exceeds the one estimated by using these rules with the peak modal responses from the uniform hazard spectra cannot be inferred directly. The assessment of the probability of exceedance of the peak response of MDOF systems is presented by considering that the uncertainty in seismic excitation due to all potential earthquakes can be lumped in the power spectral density function of the ground acceleration with uncertain model parameters. This probability is evaluated based on the random vibration of linear systems and the first‐order reliability method. It is found that the under‐ or over‐estimations are less than about 5 or 10% if the modal contributions are not within 10–90% of, or not within 20–80% of, the absolute sum of the effective modal peak responses, respectively. Otherwise, severe under‐ or over‐estimation could result. Copyright © 2002 John Wiley & Sons, Ltd.     

全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.     

Torsional vibrations of elastic foundation on saturated media

A comprehensive analytical solution is developed to examine the torsional vibration of an elastic foundation on a semi-infinite saturated elastic medium for the first time. First, the governing equations of saturated media are solved by use of Hankel transform techniques. Then, based on the assumption that the contact between the foundation and the half-space is perfectly bonded, this dynamic mixed boundary-value problem can lead to dual integral equations, which are further reduced to the standard Fredholm integral equations of the second kind and solved by numerical procedures. Numerical examples are given at the end of the paper. The numerical results indicate that the response of the elastic foundation strongly depends on the material and geometrical properties of both the saturated soil-foundation system and the load acting on the foundation. In most of the cases, the dynamic behavior of an elastic foundation on saturated media significantly differs from that of a rigid plate bearing on the elastic half-space.     

Hybrid vibration experiments with a bridge foundation system model

In order to improve seismic design technology of bridges, it is necessary to evaluate the vibration characteristics of a bridge–soil system that consists of soil, foundation structure, pier and superstructure. However, there have been few experimental studies on seismic behavior of bridge–soil system. In this paper, we conducted the hybrid vibration experiment on seismic behavior of bridge–soil system, and examined the applicability of hybrid vibration experiment to study seismic response of bridge–soil system. Based on the experiment results, seismic response of bridge was quantitatively studied.