Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.     

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,     

Boron isotopic geochemistry of karst groundwater in Guiyang City, China

Boron has two stable isotopes （^10B and ^11B） with relative abundances of about 20% and 80%, respectively. Boron isotopic ratios in natural materials show a huge range of variations, from -70‰ to ＋60‰, when expressed with the classical δ^11B notation. Most of these isotopic variations occur at the surface of the Earth. Hence, boron isotopic composition can be used as a sensitive tracer in geochemical study, for instance, to identify the different sources of contamination and factors controlling the salinity of groundwater. During the last decade, boron isotopes have been used to discriminate between the influences of seawater intrusion and anthropogenic discharge. But few of those researches can precisely identify the different sources of contamination. We measured the boron concentrations and boron isotopic ratios of groundwater samples collected in Guiyang City, as well as the major ions. The results indicate that the major ion composition of the groundwater in the investigated area is mainly controlled by the interactions between water and the dominant rock i.e. carbonates. All the water compositions are characterized by high concentrations of Ca^2＋, Mg^2＋, HCO3^-, SO4^2-, and NO3^-, which are the dominant contaminants. Both dissolved boron concentrations and isotopic ratios show large variations among the ground waters, from 2 μg/L to 90 μg/L and from -6‰ to ＋26‰, respectively. The boron concentrations and isotopic ratios indicate that the river across the studied city has been seriously contaminated by urban discharge. Boron concentrations of fiver water samples varied from 20 μg/L to 140 μg/L, with an average δ^11B value of ＋2.0‰. Using boron isotopic compositions and different geochemical indices allowed us to clearly identify and distinguish the two major sources of contamination, agricultural activity and urban wastewater. Both of the two sources are characterized by high boron concentrations but their boron isotopic compositions significantly differ.     

Carbonates calibrated against oceanographic parameters along a latitudinal transect in the Gulf of California, Mexico

Trophic resources are an important control governing carbonate production. Though this importance has long been recognized, no calibration exists to quantitatively compare biogenic assemblages within trophic resource fields. This study presents a field calibration of carbonate producers in a range of settings against high‐resolution in situ measurements of nutrients, temperature and salinity. With its latitudinal extent from 30° to 23° N, the Gulf of California, Mexico, spans the warm‐temperate realm and encompasses nutrient regimes from oligo‐mesotrophic in the south to eutrophic in the north. Accordingly, from south to north carbonates are characterized by: (i) coral‐dominated shallow carbonate factories (5–20 m water depth) with average sea‐surface temperatures of 25 °C (min. 18 °C, max. 31 °C), average salinities of 35·06‰ and average chlorophyll a levels, which are a proxy for nutrients, of 0·25 mg Chl a m^?3 (max. 0·48, min. 0·1). (ii) Red algal‐dominated subtidal to inner‐shelf carbonate formation (10–25 m) in the central Gulf of California exhibiting average temperatures of 23 °C (min. 18 °C, max. 30 °C), average salinities of 35·25‰, and average Chl a levels of 0·71 Chl a m^?3 (max. 5·62, min. 0). (iii) Molluskan bryozoan‐rich inner to outer shelf factories in the northern Gulf of California (20–50 m) with average sea surface temperatures of only 20 °C (min. 13 °C, max 29 °C), average salinities of 35·01‰, and average contents of 2·2 mg Chl a m^?3 (max. 8·38, min. 0). By calibrating sedimentological data with in situ measured oceanographic information in different environments, the response of carbonate producers to environmental parameters was established and extrapolated to carbonates on a global scale. The results demonstrate the importance of recognizing and quantifying trophic resources as a dominant control determining the biogenic composition and facies character of both modern and fossil carbonates.     

Hydrology and hydrogeology of Sakaryabaşı Karstic springs, Çifteler, Turkey

The Sakarya River is one of the largest rivers in Turkey and is fed mainly from Sakaryabaşı springs. The Sakaryabaşı springs are located in the Central Anatolia and issue from confined/semi-confined karst having a thermal component and therefore, having quite different hydrogeological characteristics as compared to the Taurus Karst region, a typical example of the Mediterranean type of karst. The karstic carbonate rocks that form the groundwater reservoir are overlain by a thick semi-pervious overburden of mainly clastics of Neogene age. Tectonics is the major factor controlling the occurrence of the karst springs in the area where topography is rather flat. This study aimed at explaining the occurrence and movement of the karst groundwater within the system by use of hydrogeological, chemical, and isotopic tools. Isotopic composition of the waters revealed that all waters in the region are of meteoric origin and the thermal component is due to deep circulation. The catchment area of the hydrogeological system extends to the south and groundwater movement is towards the outlets, which are in a depression along a major fault. The movement of the groundwater, based on analysis of remotely sensed images, is controlled mainly by structural elements.     

Testing earthquake prediction methods: «The West Pacific short-term forecast of earthquakes with magnitude MwHRV ≥ 5.8»

Analyzing the tables and probability maps posted by Yan Y. Kagan and David D. Jackson in April 2002–September 2004 at http://scec.ess.ucla.edu/~ykagan/predictions_index.html and the catalog of earthquakes for the same period, the conclusion is drawn that the underlying method could be used for prediction of aftershocks, while it does not outscore random guessing when main shocks are considered.     

Correlations in aftershock and seismicity patterns

Correlations in space and time play a fundamental role in earthquake processes. One direct manifestation of the effects of correlations is the occurrence of aftershocks due to the stress transfer in the vicinity of a main shock. Less obvious and more speculative changes in correlations may occur in the background seismicity before large earthquakes. Using statistical physics it is possible to introduce a measure of spatial correlations through a correlation length. This quantity characterizes how local fluctuations can influence the occurrence of earthquakes over distances comparable with the correlation length. In this work, the physical basis of spatial correlations of earthquakes is discussed in the context of critical phenomena and the percolation problem. The method of two-point correlation function is applied to the seismicity of California. Well defined variations in time of the correlation length are found for aftershock sequences and background seismicity. The scaling properties of our obtained distributions are analyzed with respect to changes in several scaling parameters such as lower magnitude cutoff of earthquakes, the maximum time interval between earthquakes, and the spatial size of the area considered. This scaling behavior can be described in a unified manner by utilizing the multifractal fit. Utilizing the percolation approach the time evolution of clusters of earthquakes is studied with the correlation length defined in terms of the radius of gyration of clusters. This method is applied to the seismicity of California.     

Effects of magnetic interactions in anisotropy of magnetic susceptibility: Models, experiments and implications for igneous rock fabrics quantification

Besides granites of the ilmenite series, in which the anisotropy of magnetic susceptibility (AMS) is mainly controlled by paramagnetic minerals, the AMS of igneous rocks is commonly interpreted as the result of the shape-preferred orientation of unequant ferromagnetic grains. In a few instances, the anisotropy due to the distribution of ferromagnetic grains, irrespective of their shape, has also been proposed as an important AMS source. Former analytical models that consider infinite geometry of identical and uniformly magnetized and coaxial particles confirm that shape fabric may be overcome by dipolar contributions if neighboring grains are close enough to each other to magnetically interact. On these bases we present and experimentally validate a two-grain macroscopic numerical model in which each grain carries its own magnetic anisotropy, volume, orientation and location in space. Compared with analytical predictions and available experiments, our results allow to list and quantify the factors that affect the effects of magnetic interactions. In particular, we discuss the effects of (i) the infinite geometry used in the analytical models, (ii) the intrinsic shape anisotropy of the grains, (iii) the relative orientation in space of the grains, and (iv) the spatial distribution of grains with a particular focus on the inter-grain distance distribution. Using documented case studies, these findings are summarized and discussed in the framework of the generalized total AMS tensor recently introduced by Cañon-Tapia (Cañon-Tapia, E., 2001. Factors affecting the relative importance of shape and distribution anisotropy in rocks: theory and experiments. Tectonophysics, 340, 117–131.). The most important result of our work is that analytical models far overestimate the role of magnetic interaction in rock fabric quantification. Considering natural rocks as an assemblage of interacting and non-interacting grains, and that the effects of interaction are reduced by (i) the finite geometry of the interacting clusters, (ii) the relative orientation between interacting grains, (iii) their heterogeneity in orientation, shape and bulk susceptibility, and (iv) their inter-distance distribution, we reconcile analytical models and experiments with real case studies that minimize the role of magnetic interaction onto the measured AMS. Limitations of our results are discussed and guidelines are provided for the use of AMS in geological interpretation of igneous rock fabrics where magnetic interactions are likely to occur.     

Contemporary vertical crustal deformation in Cascadia

Data from 29 tide gauges and 113 pairs of first and second order leveling lines are analyzed to determine the pattern of vertical deformation in the Pacific Northwest of the United States. The data span nearly 100 years and represent the interseismic elastic deformation related to the great earthquake cycle. Uplift rates calculated from leveling surveys are adjusted to a model surface in the tidal reference frame using a robust, weighted, linear, least square technique. Rapid uplift occurs in two distinct broad regions along the coast separated by a narrow zone of slow subsidence. Vertical deformation rates range from > 4 mm/year of uplift on southern Vancouver Island to > 2 mm/year of subsidence in northern coastal Oregon. The deformation pattern is consistent with the results of previous studies and subduction models.     

Aftershocks series monitoring of the September 18, 2004 M = 4.6 earthquake at the western Pyrenees: A case of reservoir-triggered seismicity?

On September 18, 2004, a 4.6 mbLg earthquake was widely felt in the region around Pamplona, at the western Pyrenees. Preliminary locations reported an epicenter less than 20 km ESE of Pamplona and close to the Itoiz reservoir, which started impounding in January 2004. The area apparently lacks of significant seismic activity in recent times. After the main shock, which was preceded by series of foreshocks reaching magnitudes of 3.3 mbLg, a dense temporal network of 13 seismic stations was deployed there to monitor the aftershocks series and to constrain the hypocentral pattern. Aftershock determinations obtained with a double-difference algorithm define a narrow epicentral zone of less than 10 km², ESE–WNW oriented. The events are mainly concentrated between 3 and 9 km depth. Focal solutions were computed for the main event and 12 aftershocks including the highest secondary one of 3.8 mbLg. They show mainly normal faulting with some strike-slip component and one of the nodal planes oriented NW–SE and dipping to the NE. Cross-correlation techniques applied to detect and associate events with similar waveforms, provided up to 33 families relating the 67% of the 326 relocated aftershocks. Families show event clusters grouped by periods and migrating from NW to SE. Interestingly, the narrow epicentral zone inferred here is located less than 4 km away from the 111-m high Itoiz dam. These hypocentral results, and the correlation observed between fluctuations of the reservoir water level and the seismic activity, favour the explanation of this foreshock–aftershock series as a rapid response case of reservoir-triggered seismicity, burst by the first impoundment of the Itoiz reservoir. The region is folded and affected by shallow dipping thrusts, and the Itoiz reservoir is located on the hangingwall of a low angle southward verging thrust, which might be a case sensible to water level fluctuations. However, continued seismic monitoring in the coming years is mandatory in this area to infer more reliable seismotectonic and hazard assessments.