Effects of cation disordering in a natural MgAl2O4 spinel observed by rectangular parallelepiped ultrasonic resonance and Raman measurements

At moderate temperatures, the elastic properties of natural MgAl₂O₄ spinel differ in several significant ways from properties of synthetic spinels. Below 1000 K, the ultrasonic resonant frequencies of an ordered natural spinel change significantly after heat treatment; at higher temperatures, both types of spinels have similar resonant responses. The temperature derivatives of the elastic constants of an ordered spinel also differ from those of disordered spinels at moderate temperatures; again, at higher temperatures, both types of spinels have similar behaviors. The Raman spectra also differ below 1000 K for ordered natural and disordered spinels and are similar at higher temperatures and after cooling to ambient temperature. We associate these changes in ultrasonic resonance and Raman spectra of spinel with cation disordering at high temperature which may be quenched by cooling. We deduce estimates of the inversion parameter from the relative intensities of the two A_1g Raman modes in very good agreement with estimates made from other measurements. We find thatC ₁₁ andC ₁₂ decrease by 4 and 8%, respectively, with 20% inversion in spinel;C ₄₄ is less sensitive to cation order. These results imply that previous measurements of the adiabatic elastic constants of spinels at ambient conditions have been affected by the state of cation disorder of the specimen.     

工程地震勘探综述

本文对工程地震勘探作为一门年轻的、独立的学科，其诞生和发展的历史进行了评述。文中对工程地震勘探涉及的研究内容。与地震勘探的关系，所取得的成果进行了论述。对应用超声地震模型技术模拟解决工程地震勘探实际问题发表了见解，并对工程地震勘探未来的发展进行了展望。     

Sonic anemometers in aeolian sediment transport research

Fast-response wind and turbulence instruments, including sonic anemometers, are used more and more in aeolian sediment transport research. These instruments give information on mean wind, but also on fluctuations and turbulent statistics, such as the uw covariance, which is a direct measure of Reynolds' stress (RS) and friction velocity. This paper discusses the interpretation of sonic anemometer data, the transformations needed to get proper results and turbulence spectra, and how they are influenced by instrument size, sampling frequency, and measurement height.Turbulence spectra characterize how much the different frequencies in the turbulent signals contribute to the variance of wind speed, or to the covariance of horizontal and vertical wind speed. They are important in determining the measurement strategy when working with fast-response instruments, such as sonic anemometers, and are useful for interpreting the measurement results. Choices on the type of sonic anemometer, observation height, sampling period, sampling frequency, and filtering can be made on the basis of expected high and low-frequency losses in turbulent signals, which are affected by those variables, as well as wind speed and atmospheric stability.Friction velocity and RS, important variables in aeolian sediment transport research, are very sensitive to tilt or slope errors. During a field experiment, the slope sensitivity of the RS was established as 9% per degree of slope, which is 1.5 times the value reported in literature on the basis of theoretical considerations. An important reason for the difference probably is the large influence of streamline curvature on turbulence statistics and thereby on the slope sensitivity of the RS. An error of 9% per degree of slope in the RS will translate into an error of approximately 4% per degree of slope in the calculated friction velocity.Space–time correlation of the horizontal wind speed is much larger than that of the vertical wind speed and the instantaneous RS. This largely explains why, in previous studies, a poor correlation was found between instantaneous RS measured at 3 m height and saltation flux near the surface, whereas the correlation between wind speed at some height and saltation flux was much better. Therefore, the poor correlation between RS away from the surface and saltation flux does not contradict that saltation flux is caused by RS.     

岩石孔隙流体对纵横波速度影响的实验研究及意义

我们用ＭＴＳ的超声波测试系统研究了地表岩样饱和水及孔隙压力对纵横波速度的影响。在实验研究中,分别在常温常压条件下测量了干燥岩石和完全饱水岩石的纵横波速度,并在模拟地层条件下,测量了岩石纵横波速度随孔隙压力的变化。实验结果显示：（１）岩石完全饱和水后,与干燥时相比,纵波速度将明显增加,最大可增加３０％,且岩石在干燥时的纵波速度越低速度增大的比例越大,但纵波速度增大的比例与孔隙度无明显关系。饱水前后横波速度几乎保持不变。（２）在模拟地层的温压条件下,当孔隙压力由低到高,纵横波速度均将线性减小,且横波速度比纵波速度下降的比例更大。据此,得到了识别地层异常高压和地层含气的地震速度标志。     

A new ultrasonic interferometer for the determination of equation of state parameters of sub-millimeter single crystals

A new giga-Hertz ultrasonic interferometer has been developed, based on ultrasonic microscopy technology. The interferometer operates from 0.3 GHz to 1.5 GHz. The high frequency and associated small wavelengths together with the large bandwidth make it possible to measure travel times in samples with thicknesses of several microns and allow for unprecedented accuracy in bond corrections. An absolute accuracy of 1 part in 10⁵ in travel time measurements is achievable in single crystals (thickness of 200 microns) or glasses of interest to the earth sciences. The high precision travel time data, combining with sample length measurements using a laser interferometer built in our laboratory, yield very high precision ultrasonic velocities.The interferometer is intended for use in conjunction with a newly developed 4 GPa gas piston cylinder apparatus (Getting andSpetzler, 1993) for equation of state measurements under simultaneous pressure and temperature. A separate correction for the bond will be made for each datum at every point in temperature pressure space.     

Turbulence Structure in the Wake Region of a Meteorological Tower

A meteorological tower significantly modifies the air flow, the mean windspeed and wind direction as well as the turbulencestructure of the air. Suchchanges can be noticed in particular in the wake region of the tower.Measurementson the 200 m tower ofForschungszentrum Karlsruhewere carried outusing Solent sonic anemometers in the lee of the towerand cup anemometers on both sides.In the wake region, spectral energydensity is increased in the high-frequency range. Superposition of this disturbance spectrum on the undisturbedspectrum yields a `knee' in the resulting spectrum. In the case of low turbulence intensity with stable stratification,a plateau with a constant energy content is observed in front of the knee.This effect is caused by the new production of turbulence energy from the mean flow as well as by an energy transfer fromlarger to smaller vortices. Power spectra in strongly stable conditionsshow a more rapid decrease of intensity in the region where the inertialsubrange is expected.The relevant scales of wake turbulence are derived from the maximum of the disturbance spectrum.Locations of the high-frequency peak do not depend on atmospheric stability,but are controlled mainly by mean wind speed.Apart from the reduction of the mean wind speed, the spectra and cospectra exhibit a strong anisotropy for such cases.The results demonstrate the significant influence of a tower on turbulence spectra in the wake region.     

超声波透射法在检测大直径灌注桩完整性中的应用

介绍了超声波透射法检测大直径灌注桩桩身完整性的原理、方法和现场检测技术。通过现场检测实例,给出了基桩存在缺陷时声参量的几种特征。检测结果表明:超声波透射法能够相当准确的判别长桩的多处缺陷。     

Extraction of organochlorine pesticides in sediments using soxhlet,ultrasonic and accelerated solvent extraction techniques

The application of soxhlet, ultrasonic and accelerated solvent extraction techniques to the analysis of six organochlorine pesticides (α-HCH, β-HCH, γ-HCH, o, p'-DDT, p,p'-DDT and p, p'-DDE) in Taihu Lake sediment samples is described. It was found that the limits of quantification ranged from 0.002μgg-1 to 0.004μgg-1, and the recoveries of organochlorine pesticides with the three extraction techniques were acceptable (>80.7%). With a mass selective detector, better results were obtained by accelerated solvent extraction using hexane-acetone (1:1) as compared with soxhlet and ultrasonic extraction. It was shown that the accelerated solvent extraction was the optimum technique for the analysis of organochlorine pesticides in sediments. The general features of the three extraction techniques are also presented.