Ultrasonic-assisted condensation of chitosan with salicylaldehyde

In order to synthesize an improved adsorbent for heavy metal ions, we studied the condensation reaction of chitosan with salicylaldehyde in ethanol to form a Schiff base. The effect irradiating the reaction using an ultrasonic liquid processor was contrasted with conventional methods. The IR spectra of condensed chitosan prepared by the two methods showed that their molecular structures were identical. The reaction conditions, including solvents, ultrasonic power density and irradiation time, pH, and reactant ratio, were optimized by orthogonal design. A shorter reaction time and a higher product yield were obtained using ultrasonic-assisted synthesis compared with the traditional method. A condensation degree of 89.63% was achieved using the optimized conditions: i.e. ultrasonic irradiation at 180 W for 60 min; 95% ethanol as the solvent, pH 4.0, and salicylaldehyde:chitosan ratio of 6:1.     

超声提取-气相色谱法测定覆盖区土壤中的六六六和滴滴涕

将超声波提取技术引入到覆盖区土壤样品六六六、滴滴涕组分的预处理中,建立了超声提取,磺化法净化,气相色谱测定的分析方法。对被测组分在超声波提取中的稳定性进行了试验,对超声提取时间、提取温度、提取溶剂用量以及磺化净化过程可能导致组分损失的各种相关条件逐个试验筛选,采用样品加标回收法对六六六、滴滴涕的8种组分进行了两种浓度的精密度和准确度试验,RSD值均小于10％,平均回收率92．5％-103．9％。方法对各种异构体的六六六、滴滴涕的最低检测浓度为0．30-3．89ng／g。     

High Pressure-Differential Thermal Analysis and Ultrasonic Wave Amplitude Analysis of Ice-Water Equilibrium at 1.5-5.0GPa

Water is the most active component in all geological systems.It has an important effect on the physical properties of minerals and melts.It also plays a key role in the evolution of the Earth.Accurate thermodynamics data on water are currently confined to pressures below 1.0GPa and temperatures below 900℃.Presented in this paper are new data available on the P-T properties of water at pressures up to 5.0GPa,develoged from differential thermal analysis and ultrasonic wave amplitude analysis.It has been found that there may exist another ternary point at 3.0GPa and that ultrasonic wave amplitude change of ice-water transition shows two inflection points above 2.0GPa, consistent with the two peaks of differential thermal curves above 2.0GPa .It may be a new phenomenon which needs further study.     

超声电视测井图像中异常点剔除算法

针对超声电视测井图像中经常会出现的异常点问题,提出了一种采用全变分的修复算法（TV算法）来剔除异常点。该方法先在选定的区域里根据阈值来确定要剔除的异常点,然后利用全变分的图像修复算法去修复这些异常点。实验结果证明,该方法能够很好地对异常点进行剔除,保证测井图像的完整性,明显地改善图像质量,对实际测井资料的处理具有很重要实际意义。     

高温后花岗岩巴西劈裂抗拉实验及超声特性研究

采用非金属超声检测分析仪和液压伺服试验系统装置,研究不同温度（25 ℃～1 000 ℃)作用后花岗岩的超声特性,分析不同温度条件下花岗岩的劈裂抗拉强度。结果表明,（1）高温后花岗岩的纵波波速、超声波形以及劈裂抗拉强度都与温度的变化密切相关;（2）随着温度的增高,花岗岩试样的纵波波速和劈裂抗拉强度逐渐减小,经历1 000 ℃高温后,纵波波速下降90%,劈裂抗拉强度下降65%,并且,纵波波速和抗拉强度间存在一定的相关性;（3）超声波波形随温度升高由整齐变混乱,由密集变稀疏,尤其在800 ℃波形变化最明显;（4）花岗岩试样的热损伤不断增加,经历1 000 ℃热损伤后,试样的脆性增加,变得轻脆易碎。     

超声波振动下不同应力条件对岩石强度影响的试验

振动有助于碎岩,以往关于振动碎岩机理的研究大多在低频率段展开。为填补超高频率段下振动碎岩机理的空白,采用单轴动静组合加载模式,开展了超声波振动下不同应力条件对岩石强度影响的试验研究,其中超声波振动频率为20kHz,预压范围为100～500N。研究结果表明:当预压小于200N时,岩石内部应力状态无法满足强度准则,岩石强度下降不明显;当预压大于等于200N时,岩石强度随振动时间的增加而逐渐降低且存在最优预压力值(400N)使得岩石强度最低。缩短振动频率与岩石固有频率的差值有利于提高超声波振动碎岩效率。     

采空区二维超声波物理模型实验研究

由于对资源矿产的过度开采使得矿山地区(尤其是煤矿)出现了采空区,从而引起地表塌陷等地质灾害。为了深入了解地震方法在采空区调查中的应用效果,从超声波物理模型实验研究出发,论述了物理模型的原理和制作,研究了采空区的地震波场特征,并利用W inse is软件对所采集的二维超声波实验数据进行了处理。由叠偏剖面推断的采空区的位置与实际模型相符,从而验证了超声波采空区物理模型试验是有效的、可信的;同时可以为实际探测采空区提供进一步的理论依据。     

循环冻融条件下安山岩和花岗岩的物理力学特性试验研究

结合青藏铁路块石护坡路基处于青藏高原特殊的气候条件,对用于青藏铁路护坡的两种主要岩石（花岗岩和安山岩）进行循环冻融试验.结果表明:两种岩石在经历了数次冻融循环后都出现了微细裂纹;声波监测表明,超声波速同冻融循环周期呈指数下降关系,显示了冻融循环对岩石风化的影响以及循环后岩石物理力学参数变化的趋势.结果说明,花岗岩的冻融...     

超声波测风仪风速的不同算法误差分析

超声波测风仪与气象业务用风向标测风仪相比具有诸多优势,可为气象业务中风向风速观测急需解决的较多问题提供解决方案。为促成超声波风速仪尽早在气象部门业务应用,同时解决资料同化等问题,研究和选择适用于超声波测风仪的风速平均(平滑)算法显得极为重要。为此,从超声波测风仪测量原理出发,介绍了超声波测风仪获取数据的特点;利用台站获取的超声波测风仪风速的秒数据,采用不同时段、不同平均(平滑)方法,计算风速多种形式的平均值,通过统计、分析和比较,获得了标量和矢量不同算法下风速平均值的特性差异及其之间的误差,进一步验证了标量平均大于矢量平均的结论。通过对超声波测风仪的风速算法研究及其误差分析,对减小因算法带来的风速测量误差提供方法,同时探讨了超声波测风仪在气象业务使用的可能和方向。     

Summer boundary-layer height at the plateau site of Dome’C,antarctica

Measurements of the mean and turbulent structure of the planetary boundary layer using a sodar and a sonic anemometer, and radiative measurements using a radiometer, were carried out in the summer of 1999–2000 at the Antarctic plateau station of Dome C during a two-month period. At Dome C strong ground-based inversions dominate for most of the year. However, in spite of the low surface temperatures (between −50 and −20 °C), and the surface always covered by snow and ice, a regular daytime boundary-layer evolution, similar to that observed at mid-latitudes, was observed during summertime. The mixed-layer height generally reaches 200–300 m at 1300–1400 LST in high summer (late December, early January); late in the summer (end of January to February), as the solar elevation decreases, it reduces to 100–200 m. A comparison between the mixed-layer height estimated from sodar measurements and that calculated using a mixed-layer growth model shows a rather satisfactory agreement if we assign a value of 0.01–0.02 m s⁻¹ to the subsidence velocity at the top of the mixed layer, and a value of 0.003–0.004 K m⁻¹ to the potential temperature gradient above the mixed layer.