Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting. 相似文献
In the Dabieshan, the available models for exhumation of ultrahigh-pressure (UHP) rocks are poorly constrained by structural data. A comprehensive structural and kinematic map and a general cross-section of the Dabieshan including its foreland fold belt and the Northern Dabieshan Domain (Foziling and Luzenguang groups) are presented here. South Dabieshan consists from bottom to top of stacked allochtons: (1) an amphibolite facies gneissic unit, devoid of UHP rocks, interpreted here as the relative autochton; (2) an UHP allochton; (3) a HP rock unit (Susong group) mostly retrogressed into greenschist facies micaschists; (4) a weakly metamorphosed Proterozoic slate and sandstone unit; and (5) an unmetamorphosed Cambrian to Early Triassic sedimentary sequence unconformably covered by Jurassic sandstone. All these units exhibit a polyphase ductile deformation characterized by (i) a NW–SE lineation with a top-to-the-NW shearing, and (ii) a southward refolding of early ductile fabrics.
The Central Dabieshan is a 100-km scale migmatitic dome. Newly discovered eclogite xenoliths in a Cretaceous granitoid dated at 102 Ma by the U–Pb method on titanite demonstrate that migmatization post-dates HP–UHP metamorphism. Ductile faults formed in the subsolidus state coeval to migmatization allow us to characterize the structural pattern of doming. Along the dome margins, migmatite is gneissified under post-solidus conditions and mylonitic–ultramylonitic fabrics commonly develop. The north and west boundaries of the Central Dabieshan metamorphics, i.e. the Xiaotian–Mozitan and Macheng faults, are ductile normal faults formed before Late Jurassic–Early Cretaceous. A Cretaceous reworking is recorded by synkinematic plutons.
North of the Xiaotian–Mozitan fault, the North Dabieshan Domain consists of metasediments and orthogneiss (Foziling and Luzenguang groups) metamorphosed under greenschist to amphibolite facies which never experienced UHP metamorphism. A rare N–S-trending lineation with top-to-the-south shearing is dated at 260 Ma by the 40Ar/39Ar method on muscovite. This early structure related to compressional tectonics is reworked by top-to-the-north extensional shear bands.
The main deformation of the Dabieshan consists of a NW–SE-stretching lineation which wraps around the migmatitic dome but exhibits a consistently top-to-the-NW sense of shear. The Central Dabieshan is interpreted as an extensional migmatitic dome bounded by an arched, top-to-the-NW, detachment fault. This structure may account for a part of the UHP rock exhumation. However, the abundance of amphibolite restites in the Central Dabieshan migmatites and the scarcity of eclogites (found only in a few places) argue for an early stage of exhumation and retrogression of UHP rocks before migmatization. This event is coeval to the N–S extensional structures described in the North Dabieshan Domain. Recent radiometric dates suggest that early exhumation and subsequent migmatization occurred in Triassic–Liassic times. The main foliation is deformed by north-verging recumbent folds coeval to the south-verging folds of the South Dabieshan Domain. An intense Cretaceous magmatism accounts for thermal resetting of most of the 40Ar/39Ar dates.
A lithosphere-scale exhumation model, involving continental subduction, synconvergence extension with inversion of southward thrusts into NW-ward normal faults and crustal melting is presented. 相似文献
Natural production of the radionuclide chlorine-36 (36Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear
weapons, has also produced large amounts of 36Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production
prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the
probable preanthropogenic levels of 36Cl in groundwater in the United States. Although significant local variations exist, they are superimposed on a broad regional
pattern of 36Cl/Cl ratios in the United States. Owing to the influence of atmospherically transported ocean salt, natural ratios of 36Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States.
Electronic Publication 相似文献
An evaluation of the distribution of P concentrations in streamflow, P fractions andthe microbial biomass P pool was made of bed and bank sediments along a lowlandstream in New Zealand. Agricultural intensification increased downstream. However,most P fractions decreased downstream (total P decreased from c. 400 to 250 mg kg-1) in bed sediments, while P in streamflow remained relatively constant (generally < 0.005 mg l-1) and sediment microbial P increased from 2 to 8 mg kg-1. An investigation of P release from dried and rewetted sediments showed that solution P (CaCl2-P) increased, on average > 300%, and proportional to the size of the microbial biomass P pool before drying, except in sediments with much organic carbon (OC). When supplied with a P source (1 mg l-1) and then simultaneously with a C source (glucose, 100 mg l-1), all sediment behaved similarly and biotic sorption accounted for, on average, 27 and 34% of the total sediment uptake, respectively (maximum of 58%). The quantity of P taken up was related to the initial size of the microbial biomass P pool, and the availability of P as influenced by organic P complexes and OC. The sediment microbial biomass represents a transient, but small store of P could be useful to indicate bioavailable P inputs. 相似文献
Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m2. Calculated seismic velocities (Vp) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm3. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (LaN/YbN=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton. 相似文献
Whole-rock Pb isotopic signatures and U/Pb geochronology refute a Rodinian correlation of northeastern Laurentia and proto-Andean Amazonia. According to this previously proposed model, the Labrador–Scotland–Greenland Promontory (LSGP) of northeastern Laurentia collided with the proto-Andean margin of Amazonia, at the Arica Embayment, during the Grenville/Sunsás Orogeny (ca. 1.0 Ga). Links between the two margins were based upon the correlation of the LSGP with Arequipa-Antofalla Basement (AAB), a Proterozoic block along the proto-Andean margin of Amazonia adjacent to the Arica Embayment. Specifically, similarities in 1.8–1.0 Ga basement rocks in both regions suggested that the AAB was originally a piece of the LSGP. Furthermore, similarities in unique, post-collisional, but pre-rift, glacial sedimentary sequences also supported a link between the AAB and LSGP.Tests of these apparent similarities fail to support correlation of the AAB and the LSGP and, thus, eliminate a direct link between northeastern Laurentia and southwestern Amazonia in Rodinia. However, Pb isotopic compositions and U/Pb geochronology provide the basis for two new correlations, namely, (1) the ca. 1.3–1.0 Ga basement in the central and southern Appalachians may be an allochthonous block that was transferred to Laurentia from Amazonia at ca. 1.0 Ga, and (2) an allochthonous AAB may be a piece of the Kalahari Craton that was transferred to Amazonia at ca. 1.0 Ga. Based on these new correlations and a previously proposed Grenvillian connection between southern Laurentia (Llano) and Kalahari, we propose that Amazonia may have collided with a contiguous southeastern Laurentia/Kalahari margin at ca. 1.0 Ga. 相似文献