三角褐指藻体分泌物质对汞的络合作用

本文测定了一次培养实验和连续培养实验中三角褐指藻胞外产物的变化及其与汞的络合性能。28天的培养过程中测得胞外产物与汞的络合容量C_L为2.6×10~(-5)mol/dm~3;表观稳定常数K′为6.1×10~(10)。该结果解释了细胞培养过程中胞外有机物的释放对汞的解毒机理及对介质中汞形态的转化。     

Prediction of Load Carrying Capacity of Corroded Reinforced Concrete Beam

A novel method for prediction of the load carrying capacity of a corroded reinforced concrete beam (CRCB) is presented in the paper. Nine reinforced concrete beams, which had been working in an aggressive environment for more than 10 years, were tested in the laboratory. Comprehensive tests, including flexural test, strength test for corroded concrete and rusty rebar, and pullout test for bond strength between concrete and rebar, were condueted. The flexural test results of CRCBs reveal that the distribution of surface cracks on the beams shows a fractal behavior. The relationship between the fractal dimensions and mechanical properties of CRCBs is then studied. A prediction model based on artificial neural network (ANN) is established by the use of the fractal dimension as the corrosion index, together with the basic intbrmation of the beam. The validity of the prediction model is demonstrated through the experimental data, and satisfactory resuits are achieved.     

半封闭海湾潮间带部分围垦后纳潮量计算的商榷——以胶州湾为例

传统的海湾(泻湖)纳潮量计算方法不能精确地反映潮间带被部分围垦后纳潮量的实际情况,本考虑围堤的影响,将纳潮量分解为堤基以下的“梯形”区和堤基以上的“矩形”区两部分之和,在理论上更加严密。根据改进后方法算出的胶州湾近期纳潮量比传统方法算出的纳潮量大15％左右。可见,半个多世纪以来胶州湾的纳潮量只减少了约15％．而不是传统方法得出的约25％。     

极谱法测定海水介质的铜络合容量

采用新极谱技术(1.5次微分)的阳极溶出伏安滴定方法测定天然海水的铜络合容量和条件稳定常数。对测试条件、EDTA回收率和有关问题进行了探讨。青岛近岸水样的九次平行测定表明,铜的表现络合容量为3.01×10~(-7)mol/dm~3,条件稳定常数为7.34×10~7,相对标准偏差分别为9.2％和13.8％。     

Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.     

Experimental Study on Stability of Breakwaters with Penetrating Box Foundations

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Calculation of Environmental Capacity of Petroleum Hydrocarbon in Jiaozhou Bay

The method has been established to calculate the environmental capacity (ECo),surplus environment capacity (SECo) of water with respect to marine petroleum hydrocarbons associated with oil (PHAOs) and the self-purification capacity (SPCo) of main self-purification process to PHAOs in the Jiaozhou Bay, China, according to the dynamic model for distribution of marine PHAOs among multiphase environments. The variation of concentration of PHAOs in the Jiaozhou Bay is well simulated by the dynamic model. Based on the model.the ECo, SECo of water with respect to PHAOs in the Jiaozhou Bay were calculated during the last 10 years under the first-class and second-class quality standard requirement, according to SPCoof main self-purification process to PHAOs. The results show that about 200 tons of PHAOs could be discharged into the Jiaozhou Bay for maintaining the first class seawater quality standard, and about 600 tons of PHAOs for the second class seawater quality standard later.     

深层搅拌法在超软弱港口地基上的工程应用

某港口堆场地基上部5．0m系吹填而成，地表下18m范围均属软土，经真空预压初级加固后地基承载力仅在80—90kPa，局部区域上部淤泥土层土性指标较差，含水量大于50％，地基承载力不足60kPa。为了使地基达到230kPa的承载要求，设计采用深层搅拌法加固超软弱地基。通过现场成桩工艺试验和检测表明，桩身水泥土强度在90d龄期时大于1．80MPa，单桩承载力标准值大于150kN，以φ600桩径、桩长13．5m、置换率为0．308和φ500桩径、桩长13．5m、置换率为0．267两种方案布置的复合地基承载力标准值均超过了230kPa的设计要求。试验结果表明，深层搅拌法在港口超软弱地基土应用只要施工工艺适当，完全可以使地基承载力提高2—3．5倍以土，从而节省大量的工程投资。     

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.