Modeling diffusion advection in the mass transfer of water vapor through martian regolith

Diffusion advection is an effect in diffusive multicomponent mass transfer that occurs when the flux vectors of the individual components do not add up to zero. This can be a significant effect for the mass transfer of water vapor from subsurface ice or liquid reservoirs through porous regolith at martian temperatures and pressures. Ignoring diffusion advection and using Fick's law alone to calculate the flux under these conditions will result in an erroneously small value while using a measured flux to calculate a diffusivity will result in an erroneously high value. The inaccuracy in both cases increases with temperature. The literature contains several examples of erroneous treatment of this effect. The correct approach is well-known from other applications of mass transfer and takes diffusion advection into account in the appropriate amount regardless of the temperature and pressure and reduces to the simple Fick's law when conditions warrant. In this way, there is no need to decide under what conditions diffusion advection is or is not important. It can be used in the transition region to pure Knudsen diffusion in a fashion similar to that used with the more limited Fickian approach.     

Tropospheric Wet Refractivity Tomography Based on the BeiDou Satellite System简

This paper presents a novel approach for assessing the precision of the wet refractivity field using BDS （BeiDou navigation satellite system） simulations only,GPS,and BDS＋GPS for the Shenzhen and Hongkong GNSS network.The simulations are carried out by adding artificial noise to a real observation dataset.Instead of using the δ and σ parameters computed from slant wet delay,as in previous studies,we employ the Bias and RMS parameters,computed from the tomography results of total voxels,in order to obtain a more direct and comprehensive evaluation of the precision of the refractivity field determination.The results show that：（1） the precision of tropospheric wet refractivity estimated using BDS alone （only 9 satellites used） is basically comparable to that of GPS; （2） BDS＋GPS （as of current operation） may not be able to significantly improve the data＇s spatial density for the application of refractivity tomography; and （3） any slight increase in the precision of refractivity tomography,particularly in the lower atmosphere,bears great significance for any applications dependent on the Chinese operational meteorological service.     

地热回灌的发展现状

地热回灌是一种避免地热废水直接排放引起的热污染和化学污染的措施,并对维持热储压力,保证地热田的开采技术条件具有重要的作用.目前回灌已经成为世界范围内数十个重要的地热田生产运行中的一项日常工作,在美国、新西兰、冰岛、意大利、法国、日本、罗马尼亚、丹麦、菲律宾和萨尔瓦多等十多个国家得到了广泛的应用.在国内,北京、天津的地热回灌也已经有了良好的开端.回灌是地热田管理中最为复杂的一项技术,为了避免因回灌而引起热储冷却,需要进行回灌试验和示踪试验,并在回灌过程进行全面的监测工作.     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

井中地震用于陆相储层分析的几项技术

中国陆相储层分布广泛，类型复杂，横向变化大，勘探开发成本高，进行储层分析要求采用高新技术和综合利用多种方法。本文总结了在我国几个油区进行陆相储层分析的几项地震技术即：垂直地震剖面（ＶＳＰ）技术，多偏移距和井间层析成象技术以及多参数分析和综合解释技术，在适应我国经济发展的水平和现状的条件下，用以解决我国复杂的陆相油气储层分析的问题。     

S2O, polysulfuroxide and sulfur polymer on Io's surface?

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.     

寻找相似天气过程的一种数学模型

该文介绍了一种寻找相似天气过程的数学模型，利用Saaty论述的方法[1]构造判别矩阵进行判别，从而计算出相似排序及相似度。该方法在3年多的预报业务中应用，效果良好。     

宽波段傅里叶变换太阳光谱仪等光程差采样系统设计

太阳成像光谱探测是诊断太阳大气磁场和热力学参数的主要手段. 傅里叶变换太阳光谱仪(Fourier Transform Solar Spectrometer, FTSS)具有宽波段的优势, 是当前中红外高分辨率太阳光谱探测的最佳选择. FTSS通过采集目标辐射等光程差干涉图, 反演获得光谱图, 等光程差采样的间隔决定了反演光谱波长范围. 因此从FTSS宽波段光谱观测对不同等光程差采样间隔需求出发, 基于现场可编程门阵列(Field Programmable Gate Array, FPGA)技术, 采用全数字分频、倍频方案, 设计了一套宽波段FTSS等光程差采样系统. 采用分布式余数补偿方法, 有效解决了在参考激光干涉信号倍频过程中, 输出采样信号在输出信号周期间误差累积问题, 并降低了输出采样信号的误差及非均匀性; 经功能仿真及实验测试, 系统在200Hz--50kHz频率范围内, 频率误差delta $<$ 0.04%, 可有效满足FTSS的300nm--25μm宽波段的光谱观测数据采集需求, 为后续可见和红外波段FTSS的研制奠定了技术基础.     

Bias of ostracod stable isotope data caused by drying of sieve residues from water

Stable isotope analysis of ostracod shells is used routinely for palaeoenvironmental studies of ostracod-bearing records. Sample treatment usually involves the disaggregation of sediments and sieving; before the sieving residues were washed with water onto petri dishes and oven-dried. In our study, we compared δ¹⁸O and δ¹³C values of shells that were oven-dried from water and from ethanol alternatively. Large isotopic differences of up to 3‰ were determined for δ¹⁸O values, whereas differences in δ¹³C values were less pronounced with differences of up to 1.6‰. Stable isotope values of shells dried from water were lower for both oxygen and carbon as a result of calcite crystals precipitated on the shell surfaces during the drying process. Therefore, ostracod shells for stable isotope analysis should not be prepared by drying from water. Instead, shells should be dried from ethanol to obtain reliable stable isotope data; likewise freeze-drying is expected to provide trustworthy results.