酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

矿井涌水量混沌时间序列分析与预测

矿井地下水系统是个非线性系统,由于地下水系统的复杂性,很难完全确定影响矿井涌水量的因素,因此传统的矿井涌水预测表现出较大的局限性。而混沌时间序列分析能够利用单变量处理方法,分析矿井地下水系统中,由于多因素耦合作用所产生的矿井涌水量时间序列。通过对某矿区1985年9月至2005年2月矿井涌水量时间序列资料的分析,显示矿井涌水量时间序列具有混沌特征;通过对比预测值和实测值,表明预测精度高。因此,混沌时间序列分析方法用于矿井涌水量预测是可行的。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.     

动态最小二乘支持向量机学习算法

针对大样本集的训练问题和动态训练样本的模型更新问题,提出了动态最小二乘支持向量机学习算法.该算法充分利用已建好的模型,逐渐加入新样本,并可删除位于任何位置的非支持向量,避免了矩阵求逆运算,保证了算法的高效率.大坝变形及电离层延迟两个时间序列的预报实例表明,该算法具有计算时间短、预报精度高的特点.     

Rare Earth Deposits of North America

Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

DCT域遥感影像融合算法

提出一种基于离散余弦变换(Discrete Cosine Transform,DCT)与IHS变换的多光谱与全色遥感影像融合方法及其改进算法。本文方法依据DCT系数的特点在DCT域进行遥感影像融合,适合压缩格式的遥感影像快速融合。目视效果与客观评价表明,相比常用遥感影像融合方法,本文方法能在提高空间分辨率与保持光谱特性之间得到更好的折衷。     

葛店矿双庙扩大区三维地震勘探

葛店煤矿双庙扩大区位于豫、皖两省交界处。勘探区为一轴向北北东向的不对称向斜构造,地层倾角26°～30°,测区深部有岩浆岩侵入体,严重影响煤层赋存形态;地表条件复杂,村庄密集、河流较多,测区东侧塌陷区水塘大面积分布．三维地震勘探野外施工难度大。本区地震勘探观测系统设计为12线18炮制,为避免偏移归位及叠加次数降低等问题,在向斜轴部两侧、村子周边及河岸处适当加密炮点,并在塌陷区利用钢钎插置检波器以保证CDP点完整性。数据处理采取了叠前反褶积、叠前时间偏移等技术,数据处理效果显著。遵循多波组对比、多个数据体综合解释的原则,以纵向、横向和任意时间剖面相结合,充分利用三维可视化技术进行地震资料解释。本次勘探成果查明了主采煤层三2^2、二2煤层的构造形态及埋藏深度;解释落差5m以上断层34条,其中修改原有断层5条;另外新发现小于5m的异常断点22个。经巷道验证煤层底板标高误差0．43％～1．96％,巷道已揭露断层7条,与解释成果基本一致。     

第二次土地调查若干问题探讨

第二次土地调查的目的是全面查清全国土地利用状况,掌握真实的土地基础数据,如何保证调查的质量?文章以江阴市为例进行探讨。     

Group Time Delay in the Reflection of P-Polarized Electromagnetic Plane Waves at a Stratigraphic Interface

The group time delay (GTD) formulae of quasi-total reflection of inhomogeneous P-polarized electromagnetic waves (P-PEW, whose electric field parallels to the plane of incidence), caused by the Goos–Hänchen effect, is derived by the phase shift of the wave. A numerical example where the frequency equals to 1 GHz is given. The curves of calculating results show that there are three discontinuous points at the critical angle of phase shift vector, the critical angle of attenuation vector and 90^○. When the angle of incidence is equal to one of these three angles, the GTD will become infinite, and the electromagnetic wave will propagate along the interface. The GTD will be very large, when the angle of incidence is close to one of these three angles. The results indicate that there is an important relationship between the two critical angles and the conductivity and permittivity of the two strata, and that the GTD has an important relationship with the angle of incidence. These results can be used to determine the lithology of the strata and to delimit the interfaces of strata more effectively. It is suggested that this research may prove useful in electromagnetic logging analysis and, perhaps, in the design of logging instruments.