Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.     

TEMPORAL TRENDS IN SOIL PRODUCTIVITY EVALUATIONS*

Studies of soil productivity must compensate for the effects of temporal trends in order to examine the pattern of crop yields along spatial gradients. An analysis of the published yield estimates for 30 soils in 233 counties, however, did not find consistent yield increases over the past three decades. On the contrary, the yield estimates for many soils were markedly uniform since 1972. The uniformity appears to have two causes: the acknowledged difficulty of making yield estimates in a time of increasing variability in soil and crop management, both within and between regions, and surveyors' awareness of data stored in a national soils data base. The effect is to cast doubt on soil productivity data reported in county soil surveys published between 1973 and 1988.     

Scattered light models of the dust shell around HD 179821

The dust shell around the evolved star HD 179821 has been detected in scattered light in near-IR imaging polarimetry observations. Here, we subtract the contribution of the unpolarized stellar light to obtain an intrinsic linear polarization of between 30 and 40 per cent in the shell that seems to increase with radial offset from the star. The J - and K -band data are modelled using a scattering code to determine the shell parameters and dust properties. We find that the observations are well described by a spherically-symmetric distribution of dust with an r ⁻² density law, indicating that when mass-loss was occurring, the mass-loss rate was constant. The models predict that the detached nature of a spherically-symmetric, optically-thin dust shell, with a distinct inner boundary, will only be apparent in polarized flux. This is in accordance with the observations of this and other optically-thin circumstellar shells, such as IRAS 17436+5003. By fitting the shell brightness we derive an optical depth to the star that is consistent with V -band observations and that, assuming a distance of 6 kpc, gives an inner-shell radius of     , a dust number density of     at r _in and a dust mass of     . We have explored axisymmetric shell models but conclude that any deviations from spherical symmetry in the shell must be slight, with an equator-to-pole density contrast of less than 2:1. We have not been able to fit simultaneously the high linear polarizations and the small     colour excess of the shell and we attribute this to the unusual scattering properties of the dust. We suggest that the dust grains around HD 179821 either are highly elongated or consist of aggregates of smaller particles.