稀土矿床：基本特点与全球分布规律

本文介绍了全球稀土资源供需历史、现状和对未来的展望。从矿床成因视角切入，将稀土矿床分为内生和外生两大类型，其中内生稀土矿床包括碳酸岩型、碱性岩型、碱性岩型- 碳酸岩型、氧化铁铜金型、热液脉型，外生稀土矿床包括风化壳离子吸附型、沉积岩型、沉积矿产(煤矿、铝土矿和沉积磷矿)伴生型、砂矿和现代海洋底部含稀土的锰结核、结壳和软泥型。归纳总结了主要类型矿床的基本特点和时空分布；认为内生稀土矿床产出于四类构造环境，包括裂谷环境、碰撞后伸展环境、大陆碰撞环境和后俯冲伸展环境；从构造演化入手，探讨了在外生与内生地质过程中稀土元素的迁移和富集规律，建立了涵盖主要矿床类型的构造- 成矿模型。     

祁连山南部地区三叠纪弧后前陆盆地——基于沉积填充与大地构造的证据

本文通过对祁连山南部地区三叠纪沉积充填特征的研究,建立了盆地形成过程中沉积充填与区域构造演化的关联。依据沉积充填特征、构造接触关系及区域地质背景,认为祁连山南部地区三叠纪盆地具有弧后前陆盆地的构造属性;综合分析年代学、沉积物性和盆地内部填充单元的差异划分出与柴达木岛弧带和祁连山南部弧后前陆盆地相关的区域大地构造单元。认为早三叠世-中三叠世中期,南部遭受俯冲作用持续向北挤压推覆导致盆地挠曲沉降;中三叠世中期-晚三叠世中期发生弧(东昆仑-柴北缘)-陆(巴颜喀拉地块)碰撞,祁连山南部盆地挠曲沉降增大,其间形成区域性断裂和不整合等盆地记录的地质事件;晚三叠世晚期祁连山南部盆地发生过补偿陆相填充,弧后前陆盆地消亡。     

The influence of a flood event on phytoplankton succession

The effect of the August 1987 River Reuss flood event on the phytoplankton biocoenosis in Lake Uri (Urnersee, part of Lake Lucerne, Switzerland) was investigated firstly by comparing biological, chemical and physical data sampled before the event with equivalent data sampled after the event; and secondly by comparing the phytoplankton succession in 1987 with that occurring in the floodfree year 1989. As a consequence of the flood, the physical and chemical environment of the phytoplankton was found to have undergone a change which resulted in an alteration in the composition of the phytoplankton community. The phytoplankton community existing previous to the flood event, which had been dominated byTabellaria fenestrata sensu Husted 1930 (K-strategist), was replaced by a biocoenosis characterized mainly by various species of flagellates, which represent a typical spring successional stage (r-strategists). After the externally-imposed perturbation, the return to stable physical and chemical conditions was followed by the re-establishment of the successional stage which had existed before the flood (termed reversion by Reynolds, 1980).     

Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

Interactive effects of the type of milling media and CuSO4 addition on the flotation performance of sulphide minerals from Merensky ore Part II: Froth stability

The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (k_t and k_w). The rate constant (k_w) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and k_t was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically.     

Strength and stability of frictional sliding of gabbro gouge at elevated temperatures

To investigate the strength of frictional sliding and stability of mafic lower crust, we conducted experiments on oven-dried gabbro gouge of 1 mm thick sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) at slip rates of 1.22 × 10^− 3 mm/s and 1.22 × 10^− 4 mm/s and elevated temperatures up to 615 °C. Special attention has been paid to whether transition from velocity weakening to velocity strengthening occurs due to the elevation of temperature.Two series of experiments were conducted with normal stresses of 200 MPa and 300 MPa, respectively. For both normal stresses, the friction strengths are comparable at least up to 510 °C, with no significant weakening effect of increasing temperature. Comparison of our results with Byerlee's rule on a strike slip fault with a specific temperature profile in the Zhangbei region of North China shows that the strength given by experiments are around that given by Byerlee's rule and a little greater in the high temperature range.At 200 MPa normal stress, the steady-state rate dependence a − b shows only positive values, probably still in the “run-in” process where velocity strengthening is a common feature. With a normal stress of 300 MPa, the values of steady-state rate dependence decreases systematically with increasing temperature, and stick-slip occurred at 615 °C. Considering the limited displacement, limited normal stress applied and the effect of normal stress for the temperatures above 420 °C, it is inferred here that velocity weakening may be the typical behaviour at higher normal stress for temperature above 420 °C and at least up to 615 °C, which covers most of the temperature range in the lower crust of geologically stable continental interior. For a dry mafic lower crust in cool continental interiors where frictional sliding prevails over plastic flow, unstable slip nucleation may occur to generate earthquakes.     

大变形有限元法分析边坡稳定性

边坡稳定性分析的重要任务是确定边坡潜在滑面的位置及相应的安全系数,鉴于坡体位移可在现场监测中直接得到,提出边坡潜在滑面确定的位移判据,采用大变形有限元首先计算出边坡的位移场,然后在开挖面的不同高度作塑性区内的水平位移参考线,依次连接参考线上的位移突变点即得到边坡失稳的潜在滑面位置,分析滑面上的应力以及岩体抗剪强度即得到边坡的整体安全系数。     

双坡面临空岩质边坡滑动破坏模式下的稳定性分析

多数岩质边坡稳定性分析已基本解决了常走向单坡面临空的边坡平面滑动问题。然而,在路堑边坡工程和自然边坡中有很多边坡坡面并不是平面,它包含多个坡面。多坡面边坡包含两个或多个不同走向的坡面。多坡面边坡几何特征不同于单坡面边坡,所以滑动条件也不一样。在赤平投影图上,多坡面的滑动包络线是组成边坡的每个坡面单独投影包络线的组合。为了探讨方便,只讨论了双坡面临空岩质边坡的滑动破坏模式,并将其分为双坡面临空下的平面破坏和楔形体破坏。在赤平投影图上,双坡面滑动区域定义为双坡面边坡滑动包络图中两侧坡面的真倾线之间的面积。如果有一两个节理面真倾向线落在滑动区内,滑动破坏才可能发生。