<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.     

X-ray diffraction investigation of native Si-Fe alloy minerals from Luobusha, Tibet

The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction pattern shows that the minerals are composed of FeSi, FeSi₂, β-FeSi₂ and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from early to late FeSi→FeSi₂→native silicon, accompanied by gradually increasing deoxidization. Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志]     

福建港口体系结构研究

阐述了福建港湾自然条件和港口开发现状,采用赫希曼-赫芬达尔指数分析近20年来港口体系空间结构的动态演变规律,结果表明,福建港口体系空间结构演变总趋势呈分散化。这说明了港口间的竞争大于合作,职能结构趋同,因而形成合理分工与协作的福建港口群是当务之急。鉴于此,运用模糊聚类、货种区位商等分析技术,对其体系内的港口等级层次、职能结构的基本特征进行探讨,并在此基础上提出了各港口职能分工的发展方向。     

Whole mantle SH velocity model constrained by waveform inversion based on three-dimensional Born kernels

A whole mantle SH velocity model is obtained by using a unique data set and techniques. Body and surface waveforms including major and multi-orbit phases are used as a data set and are inverted by using 3-D Born kernels. The resultant model, SH18CE, reveals the different natures of the two major upwelling systems: the strong low velocity anomalies beneath Africa extend for more than 1000 km from the core–mantle boundary (CMB), whereas those beneath the Pacific are restricted to 300–400 km from the CMB. The results also show the variable natures of stagnant slabs on the 670 discontinuity around Japan: the depths of the strongest high velocity anomalies within the stagnant slabs are different region by region, which is consistent with the detailed delay time tomography model in this area.     

Lithology-derived structure classification from the joint interpretation of magnetotelluric and seismic models

Magnetotelluric and seismic methods provide complementary information about the resistivity and velocity structure of the subsurface on similar scales and resolutions. No global relation, however, exists between these parameters, and correlations are often valid for only a limited target area. Independently derived inverse models from these methods can be combined using a classification approach to map geologic structure. The method employed is based solely on the statistical correlation of physical properties in a joint parameter space and is independent of theoretical or empirical relations linking electrical and seismic parameters. Regions of high correlation (classes) between resistivity and velocity can in turn be mapped back and re-examined in depth section. The spatial distribution of these classes, and the boundaries between them, provide structural information not evident in the individual models. This method is applied to a 10 km long profile crossing the Dead Sea Transform in Jordan. Several prominent classes are identified with specific lithologies in accordance with local geology. An abrupt change in lithology across the fault, together with vertical uplift of the basement suggest the fault is sub-vertical within the upper crust.     

Modelling and inversion of single-ended refraction data from the shot gathers of multifold deep seismic reflection profiling—an approach for deriving the shallow velocity structure

A multifold crustal-scale deep seismic near-vertical reflection profile generates a large number of single-ended shot gathers, which provide redundant data sets because of overlapping coverage of the shallow refractors. We present an approach for deriving the shallow velocity structure by modelling and inversion of single-ended seismic refraction first arrival traveltime data. We apply this method to a data set acquired with a 12-km long spread with 100 m spacing of shots and receivers, of the Neoproterozoic Marwar basin in the NW Indian shield. The approach is shown to be quite successful for delineating the shallow refractor depths, steep dips and velocities, even in the absence of regular reverse refraction profiles. The study reveals two-layered sedimentary formations, Malani volcanics and a complicated basement configuration of the Marwar basin, and provides a measure of resolution and uncertainty of the estimated model parameters. A seismic section of the near-trace gather is found to be qualitatively consistent with the derived structural features of the basin. The relative highs and lows, observed in the Bouguer gravity profile, further corroborate the derived velocity model. The present approach can be especially useful in offshore areas and elsewhere, where the single-ended multifold seismic profiles are the only available data sets.     

Crustal structure using receiver function in the east part of A＇nyemaqen suture belt

Twenty broadband seismographs were deployed along Hongyuan, Sichuan to Wuwei, Gansu. 81 teleseismic events were recorded in one year. We computed receiver functions from teleseismic waveform data and obtained S wave velocity structure beneath each station along the profile by using receiver function inversion method. The results revealed that the crustal structure is very complex and crustal average S wave velocity is to be on the low side. Low velocity structure generally exists in the depth range of 10～40 km in the crust between Aba arc fault and northern edge fault of Qinling earth＇s axis and it is a tectonic feature of complex geological process such as ancient A＇nyemaqen Tethys ocean from closing and side colliding to subducted plate exhumed or thrust rock slice lifted. The Moho is about 50 km depth along the profile and is slightly deeper in the south than in the north.     

A non‐baseline algorithm for damage locating in flexural structures using dynamic distributed macro‐strain responses

The concept of distributed strain‐sensing techniques has been proposed in our recent research, which was dedicated to utilizing the strain distributions throughout the full or partial areas of structures to detect arbitrary and unforeseen damage. An algorithm not requiring a detailed analytical model is presented for damage locating in flexural structures through the direct use of dynamic responses recorded by distributed long‐gauge strain sensors. The modal macro‐strain vector (MMSV), which has been proven to have a mapping relation with displacement mode shape, can be extracted directly from macro‐strain time‐series data, from which a damage evaluating index can be derived and used as an indicator for locating damage. Numerical examples are simulated to verify the sensitivity and effectiveness of the index in different cases. Furthermore, experimental investigations on a cantilevered beam with various long‐gauge fibre optic sensors placements are carried out to examine the feasibility and applicability of the proposed method. Copyright © 2007 John Wiley & Sons, Ltd.