基于主体功能区约束的大气污染物总量控制目标分配研究

考虑经济发展水平、污染物排放现状、污染物治理水平、空气质量,特别是国家主体功能区环境目标约束等因素,构建大气污染物排放总量分配的指标体系,用改进的等比例分配方法对2015年国家SO2,NOx总量控制目标进行区域分配。分配结果表明:SO2和NOx削减量大的省份主要集中在华北平原及其周围地区,这些地区污染物排放量大、空气质量较差;削减比例较大的地区主要集中在西部地区以及北京、天津2个直辖市,这些地区单位GDP能耗高、工业污染物去除率低、空气质量差;削减量相对较小的地区主要集中在西南和南部一些省份;削减比例较小的地区主要集中在中南部和南部几个省份,这些地区污染物排放量相对较少,空气质量好于其他省份。     

Intensity of in‐lake processes in floodplain lakes within the Bug River zone of fluvial activity

The paper presents a new approach to calculating the erosion and deposition values of floodplain lake basins, the erosion–deposition index (EDI). The EDI is a sum of the basin geometry indices (BGIs), which can be calculated for a separate cross section of the lake. The distribution of processes within the basin was investigated in two selected floodplain lakes with the use of BGIs. Field research was carried out in the Bug River valley from 1 November 2006 to 31 October 2011. The highest erosion was observed in the lakes located close to the parent river. Deposition processes were observed in lakes with high inflow of groundwater. The results showed that EDI values of 48 out of the 71 floodplain lakes ranged from ?0.2 to 0.2. Spatial distribution of erosion and deposition processes within the lake basins resulted from a velocity of water inflowing or flowing through the basin. This was observed especially in contrafluent–confluent lake. Inflow of rivers water via upstream crevasse occurred later than via downstream one, but energy of flowing water was higher, which favoured erosion of this part of the lake basin. Copyright © 2013 John Wiley & Sons, Ltd.     

Modelling sediment deposition and phosphorus retention in a river floodplain

Phosphorus (P) is one of the major limiting nutrient in many freshwater ecosystems. During the last decade, attention has been focused on the fluxes of suspended sediment and particulate P through freshwater drainage systems because of severe eutrophication effects in aquatic ecosystems. Hence, the analysis and prediction of phosphorus and sediment dynamics constitute an important element for ecological conservation and restoration of freshwater ecosystems. In that sense, the development of a suitable prediction model is justified, and the present work is devoted to the validation and application of a predictive soluble reactive phosphorus (SRP) uptake and sedimentation models, to a real riparian system of the middle Ebro river floodplain. Both models are coupled to a fully distributed two‐dimensional shallow‐water flow numerical model. The SRP uptake model is validated using data from three field experiments. The model predictions show a good accuracy for SRP concentration, where the linear regressions between measured and calculated values of the three experiments were significant (r² ≥ 0.62; p ≤ 0.05), and a Nash–Sutcliffe coefficient (E) that ranged from 0.54 to 0.62. The sedimentation model is validated using field data collected during two real flooding events within the same river reach. The comparison between calculated and measured sediment depositions showed a significant linear regression (p ≤ 0.05; r² = 0.97) and an E that ranged from 0.63 to 0.78. Subsequently, the complete model that includes flow dynamics, solute transport, SRP uptake and sedimentation is used to simulate and analyse floodplain sediment deposition, river nutrient contribution and SRP uptake. According to this analysis, the main SRP uptake process appears to be the sediment sorption. The analysis also reveals the presence of a lateral gradient of hydrological connectivity that decreases with distance from the river and controls the river matter contribution to the floodplain. Copyright © 2014 John Wiley & Sons, Ltd.     

Variability in the vertical hyporheic water exchange affected by hydraulic conductivity and river morphology at a natural confluent meander bend

River confluences and their associated tributaries are key morphodynamic nodes that play important roles in controlling hydraulic geometry and hyporheic water exchange in fluvial networks. However, the existing knowledge regarding hyporheic water exchange associated with river confluence morphology is relatively scarce. On January 14 and 15, 2016, the general hydraulic and morphological characteristics of the confluent meander bend (CMB) between the Juehe River and the Haohe River in the southern region of Xi'an City, Shaanxi Province, China, were investigated. The patterns and magnitudes of vertical hyporheic water exchange (VHWE) were estimated based on a one‐dimensional heat steady‐state model, whereas the sediment vertical hydraulic conductivity (K_v) was calculated via in situ permeameter tests. The results demonstrated that 6 hydrodynamic zones and their extensions were observed at the CMB during the test period. These zones were likely controlled by the obtuse junction angle and low momentum flux ratio, influencing the sediment grain size distribution of the CMB. The VHWE patterns at the test site during the test period mostly showed upwelling flow dominated by regional groundwater discharging into the river. The occurrence of longitudinal downwelling and upwelling patterns along the meander bend at the CMB was likely subjected to the comprehensive influences of the local sinuosity of the meander bend and regional groundwater discharge and finally formed regional and local flow paths. Additionally, in dominated upwelling areas, the change in VHWE magnitudes was nearly consistent with that in K_v values, and higher values of both variables generally occurred in erosional zones near the thalweg paths of the CMB, which were mostly made up of sand and gravel. This was potentially caused by the erosional and depositional processes subjected to confluence morphology. Furthermore, lower K_v values observed in downwelling areas at the CMB were attributed to sediment clogging caused by local downwelling flow. The confluence morphology and sediment K_v are thus likely the driving factors that cause local variations in the VHWE of fluvial systems.     

Paleogene of the Huanghekou Sag in the Bohai Bay Basin,NE China: deposition–erosion response to a slope break system of rift lacustrine basins

The sequence architecture and depositional systems of the Paleogene lacustrine rift succession in the Huanghekou Sag, Bohai Bay Basin, NE China were investigated based on seismic profiles, combined with well log and core data. Four second‐order or composite sequences and seven third‐order sequences were identified. The depositional systems identified in the basin include: fan delta, braid delta, meander fluvial delta, lacustrine and sublacustrine fan. Identification of the slope break was conducted combining the interpretation of faults of each sequence and the identification of syndepositional faults, based on the subdivision of sequence stratigraphy and analysis of depositional systems. Multiple geomorphologic units were recognized in the Paleogene of the Huanghekou Sag including faults, flexures, depositional slope break belts, ditch‐valleys and sub‐uplifts in the central sag. Using genetic division principles and taking into consideration tectonic features of the Paleogene of the Huanghekou Sag, the study area was divided into the Northern Steep Slope/Fault Slope Break System, the Southern Gentle Slope Break System and T10 Tectonic Slope Break System/T10 Tectonic Belt. Responses of slope break systems to deposition–erosion are shown as: (1) basin marginal slope break is the boundary of the eroded area and provenance area; (2) ditch‐valley formed by different kinds of slope break belts is a good transport bypass for source materials; (3) shape of the slope break belt of the slope break system controls sediments types; (4) the ditch‐valley and sub‐sag of a slope break system is an unloading area for sediments; and (5) due to their different origins, association characteristics and developing patterns, the Paleogene slope break belt systems in the Huanghekou Sag show different controls on depositional systems. The Northern Fault Slope Break system controls the deposition of a fan delta‐lacustrine‐subaqueous fan, the Southern Gentle Slope Break system controls the deposition of a fluvial–deltaic–shallow lacustrine and sublacustrine fan, and the T10 Tectonic Slope Break System controls the deposition of shallow lacustrine beach bar sandbodies. The existence of a slope break system is a necessary but not a sufficient condition for studying sandbody development. The formation of effective sandbodies along the slope break depends on the reasonable coupling of effective provenance, necessary association patterns of slope break belt, adequate unloading space and creation of definite accommodation space. Copyright © 2013 John Wiley & Sons, Ltd.     

湖南宝山矿床花岗岩类硫-铅同位素和流体包裹体研究及其成因意义

宝山铜铅锌多金属矿床是湖南重要的铅锌生产基地。矿床内矽卡岩型铜(钼)矿化受侏罗纪花岗闪长斑岩的控制,而主要的铅锌矿体则产于远离岩体的碳酸盐地层中,且缺乏可靠的矿化年龄限制。为了查明宝山铅锌矿体与花岗闪长斑岩之间的成因关系,文章对宝山花岗岩类中浸染状黄铁矿的硫同位素和钾长石的铅同位素,以及铅锌矿石萤石脉石的流体包裹体进行了测试和研究,并与前人报道的铅锌硫化物矿石的硫、铅同位素进行了对比,尝试为宝山铅锌矿化的物质来源及成因提供依据。研究表明,花岗闪长斑岩中浸染状黄铁矿的δ34S值为+1.5‰~+3.5‰,与铅锌矿石硫化物(方铅矿、闪锌矿及黄铁矿)相一致;同时,花岗岩类中钾长石的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.4789~18.7668、15.6835~15.7220和38.7903~39.1035,具有壳源的特征,且与铅锌矿石硫化物的铅同位素分布范围相吻合。宝山矿床的硫、铅同位素特征表明,花岗闪长斑岩应是铅锌矿化的主要硫源及金属来源。宝山矿床铅锌矿石萤石中的流体包裹体具有低温(130~150℃)、低盐度(8%)的特征,可能是岩浆热液演化到晚期的产物。结合已有的有关资料加以对比和分析,研究认为,宝山铅锌矿床的成矿物质应来源于花岗闪长岩的岩浆期后热液,在热液演化晚期迁移到远端地层中沉淀,形成了宝山的主要铅锌矿体。     

香港世界地质公园晚侏罗世荔枝庄组岩石组合及其成岩地质过程解析

中国东南大陆晚侏罗世地层普遍缺失,仅零星见于个别地区,香港新界东北的荔枝庄组即为其一。荔枝庄组出露于香港世界地质公园沉积岩园区的荔枝庄地区,自下往上由火山岩—沉积岩—火山岩组合而成,沉积岩中发育大型包卷层理和滑塌构造等典型沉积构造,是香港地区最具代表性的晚侏罗世火山—沉积岩系。通过实测地层剖面研究,确定其成岩过程大体上可划分为早期普林尼式火山爆发、中期破火山口湖相沉积和晚期普林尼式火山爆发三个阶段,以湖相沉积作用为主、火山喷发作用为辅;受晚期火山岩浆活动的影响,沉积岩层普遍发生硅化或炭化。荔枝庄组独特的岩石组合与形成的古地理环境,为探讨中国东南大陆中生代火山活动—沉积作用方式与成岩过程,提供了难得的研究实例。     

陕北风沙区含砾石工程堆积体坡面产流产沙试验

采用室内人工模拟降雨方法,研究了陕北风沙区含砾石工程堆积体边坡的产流产沙过程。结果表明:①砾石存在改变了坡面入渗速率,径流系数受入渗速率的影响,随砾石含量的增加先线性递减后线性递增,并在10%砾石含量处存在阈值;径流系数随降雨强度的增加线性递增。②含砾石堆积体坡面流速较纯土堆积体降低,且随雨强增大,砾石延缓径流流动的作用越显著;雨强对径流流速的影响随砾石含量增加持续减弱。③土壤剥蚀率在产流24~33 min后显著增加,砾石主要对显著增加后的平均剥蚀率产生影响。④雨强1.0 mm/min时,砾石存在促进降雨侵蚀,产沙量增大;雨强大于1.0 mm/min时,砾石具有显著的减沙效应。     

Closely related thyasirid bivalves associate with multiple symbiont phylotypes

Species of thyasirid bivalves are considered to be representative of early stages of chemosymbiosis, given that bacterial symbionts occur outside gill epithelial cells, vary among species in their abundance and nutritional importance, and are environmentally acquired. For these reasons, assessing the extent of host–symbiont specificity in thyasirids could provide valuable information on the evolution of chemosymbiosis. We show that individuals of two closely related and sympatric Thyasira cf. gouldi operational taxonomic units collected from three sites in a fjord in Newfoundland, Canada, associate with one of three distinct, closely related symbiont phylotypes. While associations show some site‐specificity, there is flexibility in host–symbiont pairings within the fjord, further supporting an early and relatively unspecific stage of chemosymbiosis in this family. Morphologic differences observed both within and among symbiont phylotypes suggest physiologic variation, possibly induced by small‐scale differences in sedimentary conditions.     

The source of sulfur in sulfide deposits in the Siberian Platform traps (from isotope data)

The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ³⁴S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ³⁴S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ³⁴S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ³⁴S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ³⁴S = 21.6‰), in sulfate veins cutting dolomites (δ³⁴S = 33‰), and in subsidence caldera sulfates in basalts (δ³⁴S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ³⁴S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ³⁴S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ³⁴S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ³⁴S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and P_ch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation.