Changes in material fluxes from the Changjiang River and their implications on the adjoining continental shelf ecosystem

This study aims to examine the changing patterns of Changjiang material fluxes, which are influenced by anthropogenic activities, and the resultant modifications to the coastal and shelf oceanographic conditions, and to propose future research about the effect of these changes on the estuarine and shelf ecosystem. Within the catchment basin of the Changjiang River, the construction of more than 48,000 dams has caused significant sediment discharge reduction, together with modifications to the timing of seasonal freshwater discharge. In the future, the mean freshwater discharge will decrease following the completion of the water-diverting project for water supply to northern China. At the same time, the riverine nutrient loadings (N and P) have increased due to the extensive use of chemical fertilizers and the large discharge of industrial wastewater and domestic sewage. These changes are modifying the oceanographic conditions of the estuarine and shelf waters. The flushing time for the river water becomes longer in wet seasons but shorter in dry seasons. An increase in salinity can be expected after the completion of the water-diverting project. Nutrient concentrations will be enhanced in the shelf waters. In contrast to the decrease in the suspended sediment concentration of the river water, field measurements have not shown well-defined patterns of changes within the estuary; nevertheless, net sediment accumulation and carbon burial rates would be reduced in the deltaic areas because of the reduced sediment discharge. Finally, increase in the nutrient input appears to enhance the primary production in the East China Sea region, which, in turn, may enhance the fishery catch.     

Deducing the spatial variability of exchange within a longitudinal channel water balance

Developing an appropriate data collection scheme to infer stream–subsurface interactions is not trivial due to the spatial and temporal variability of exchange flowpaths. Within the context of a case study, this paper presents the results from a number of common data collection techniques ranging from point to reach scales used in combination to better understand the spatial complexity of subsurface exchanges, infer the hydrologic conditions where individual influences of hyporheic and groundwater exchange components on stream water can be characterized, and determine where gaps in information arise. We start with a tracer‐based, longitudinal channel water balance to quantify hydrologic gains and losses at a sub‐reach scale nested within two consecutive reaches. Next, we look at groundwater and stream water surface levels, shallow streambed vertical head gradients, streambed and aquifer hydraulic conductivities, water chemistry, and vertical flux rates estimated from streambed temperatures to provide more spatially explicit information. As a result, a clearer spatial understanding of gains and losses was provided, but some limitations in interpreting results were identified even when combining information collected over various scales. Due to spatial variability of exchanges and areas of mixing, each technique frequently captured a combination of groundwater and hyporheic exchange components. Ultimately, this study provides information regarding technique selection, emphasizes that care must be taken when interpreting results, and identifies the need to apply or develop more advanced methods for understanding subsurface exchanges. Copyright © 2013 John Wiley & Sons, Ltd.     

Air--sea gaseous exchange of PCB at the Venice lagoon (Italy)

Water bodies are important storage media for persistent organic pollutants (POPs) such as polychlorinated biphenyls (PCBs) and this function is increased in coastal regions because their inputs are higher than those to the open sea. The air-water interface is extensively involved with the global cycling of PCBs because it is the place where they accumulate due to depositional processes and where they may be emitted by gaseous exchange. In this work the parallel collection of air, microlayer and sub-superficial water samples was performed in July 2005 at a site in the Venice lagoon to evaluate the summer gaseous flux of PCBs. The total concentration of PCBs (sum of 118 congeners) in air varies from 87 to 273 pg m(-3), whereas in the operationally defined dissolved phase of microlayer and sub-superficial water samples it varies from 159 to 391 pg L(-1). No significant enrichment of dissolved PCB into the microlayer has been observed, although a preferential accumulation of most hydrophobic congeners occurs. Due to this behaviour, we believe that the modified two-layer model was the most suitable approach for the evaluation of the flux at the air-sea interface, because it takes into account the influence of the microlayer. From its application it appears that PCB volatilize from the lagoon waters with a net flux varying from 58 to 195 ng m(-2)d(-1) (uncertainty: +/-50-64%) due to the strong influence of wind speed. This flux is greater than those reported in the literature for the atmospheric deposition and rivers input and reveals that PCB are actively emitted from the Venice lagoon in summer months.     

Sediments and water fluxes in a muddy coastline: interplay between waves and tidal channel hydrodynamics

Tidal channels are ubiquitous in muddy coastlines and play a critical role in the redistribution of sediments, thus dictating the general evolution of intertidal landforms. In muddy coastlines, the morphology of tidal channels and adjacent marshes strongly depends on the supply of fine sediments from the shelf and on the resuspension of sediments by wind waves. To investigate the processes that regulate sediment fluxes in muddy coastlines, we measured tidal velocity and sediment concentration in Little Constance Bayou, a tidal channel in the Rockefeller State Wildlife Refuge, Louisiana, USA. The tidal measurements were integrated with measurements of wave activity in the bay at the mouth of the channel, thus allowing the quantification of feedbacks between waves and sediment fluxes. Results indicate that the sediment concentration in the channel is directly related to the wave height in the adjacent bay during flood and high slack water, whereas the concentration during ebb depends on local channel velocity. Moreover, the sediment flux during ebb is of the same order of magnitude as the sediment flux during the previous flood, indicating that only a small fraction of transported sediments are stored in the marsh during a tidal cycle. Finally, very low tides, characterized by high ebb velocities, export large volumes of sediment to the ocean. Copyright © 2010 John Wiley & Sons, Ltd.     

Prediction of depth‐integrated fluxes of suspended sediment in the Amazon River: particle aggregation as a complicating factor

Large rivers have been previously shown to be vertically heterogeneous in terms of suspended particulate matter (SPM) concentration, as a result of sorting of suspended solids. Therefore, the spatial distribution of suspended sediments within the river section has to be known to assess the riverine sedimentary flux. Numerous studies have focused on the vertical distribution of SPM in a river channel from a theoretical or experimental perspective, but only a few were conducted so far on very large rivers. Moreover, a technique for the prediction of depth‐integrated suspended sediment fluxes in very large rivers based on sediment transport dynamics has not yet been proposed. We sampled river water along depth following several vertical profiles, at four locations on the Amazon River and its main tributaries and at two distinct water stages. Depending on the vertical profile, a one‐ to fivefold increase in SPM concentration is observed from river channel surface to bottom, which has a significant impact on the ‘depth‐averaged’ SPM concentration. For each cross section, a so‐called Rouse profile quantitatively accounts for the trend of SPM concentration increase with depth, and a representative Rouse number can be measured for each cross section. However, the prediction of this Rouse number would require the knowledge of the settling velocity of particles, which is dependent on the state of aggregation affecting particles within the river. We demonstrate that in the Amazon River, particle aggregation significantly influences the Rouse number and renders its determination impossible from grain‐size distribution data obtained in the lab. However, in each cross section, the Rouse profile obtained from the fit of the data can serve as a basis to model, at first order, the SPM concentration at any position in the river cross section. This approach, combined with acoustic Doppler current profiler (ADCP) water velocity transects, allows us to accurately estimate the depth‐integrated instantaneous sediment flux. Copyright © 2010 John Wiley & Sons, Ltd.     

Impact of grid resolution on the integrated and distributed response of a coupled surface–subsurface hydrological model for the des Anglais catchment,Quebec

Digital elevation models (DEMs) at different resolutions (180, 360, and 720 m) are used to examine the impact of different levels of landscape representation on the hydrological response of a 690‐km² catchment in southern Quebec. Frequency distributions of local slope, plan curvature, and drainage area are calculated for each grid size resolution. This landscape analysis reveals that DEM grid size significantly affects computed topographic attributes, which in turn explains some of the differences in the hydrological simulations. The simulations that are then carried out, using a coupled, process‐based model of surface and subsurface flow, examine the effects of grid size on both the integrated response of the catchment (discharge at the main outlet and at two internal points) and the distributed response (water table depth, surface saturation, and soil water storage). The results indicate that discharge volumes increase as the DEM is coarsened, and that coarser DEMs are also wetter overall in terms of water table depth and soil water storage. The reasons for these trends include an increase in the total drainage area of the catchment for larger DEM cell sizes, due to aggregation effects at the boundary cells of the catchment, and to a decrease in local slope and plan curvature variations, which in turn limits the capacity of the watershed to transmit water downslope and laterally. The results obtained also show that grid resolution effects are less pronounced during dry periods when soil moisture dynamics are mostly controlled by vertical fluxes of evaporation and percolation. Copyright © 2010 John Wiley & Sons, Ltd.     

Asymmetric fluxes of water and sediments in a mesotidal mudflat channel

The hydrodynamics of a small tributary channel and its adjacent mudflat is studied in Willapa Bay, Washington State, USA. Velocity profiles and water levels are simultaneously measured at different locations in the channel and on the mudflat for two weeks. The above tidal flat and channel hydrodynamics differ remarkably during the tidal cycle. When the water surface level is above the tidal flat elevation, the channel is inactive. At this stage, the above tidal flat flow is predominantly aligned along the Bay axis, oscillating with the tide as a standing wave with peak velocities up to 0.3 m/s. When the mudflat becomes emergent, the flow concentrates in the channel. During this stage, current velocities up to 1 m/s are measured during ebb; and up to 0.6 m/s during flood. Standard equations for open-channel flow are utilized to study the channel hydrodynamics. From the continuity equation, a lateral inflow is predicted during ebb, which likely originates from the drainage of the mudflat through the lateral runnels. Both advective acceleration and lateral discharge terms, estimated directly from the velocity profiles, play a significant role in the momentum equation. The computed drag coefficient for bottom friction is small, due to an absence of vegetation and bottom bedforms in the channel. Sediment fluxes are calculated by combining flow and suspended sediment concentration estimated using the acoustic backscatter signal of the instruments. A net export of the sediment from the channel is found during ebb, which is not balanced by the sediment import during flood. When the mudflat is submerged, ebb-flood asymmetries in suspended sediment concentration are present, leading to a net sediment flux toward the inner part of the Willapa Bay. Finally, a residual flow is detected inside the channel at high slack water, probably associated with the thermohaline circulation.     

Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.     

DAYTIME HEAT BALANCE FOR ESTIMATING NON-RADIATIVE FLUXES OF LAKE BANYOLES,SPAIN

Combining a six-term heat balance equation and a seasonal thermocline model, a new equation to calculate non- radiative fluxes of Lake Banyoles has been determined. Mean daily measurements of global solar radiation, downward longwave radiation, wind speed, air temperature and water surface temperature were used as input data and lake temperature as the calculated output data of the model. To calibrate performance of the new equation, calculated lake temperature was compared with measured lake temperature during both the mixing and the stratified period of the lake. The new coefficients in the wind function to calculate the non-radiative fluxes at the water surface were assumed to depend on the variability of the wind speed, the air temperature of the study area and the surface temperature of the lake. In addition, the results were used to estimate the heat balance of the air–water interface of Lake Banyoles over a period of two years. The processes that have been taken into account are shortwave and longwave radiation, back-radiation emitted by the lake, sensible and latent heat and throughflow.