The origin of magnetization and geochemical alteration in a fault zone,Kilve, England

The origin of an apparently syndeformational chemical remanent magnetization (CRM) and geochemical alteration in a fault zone in the Bristol Channel Basin, southwest England, was investigated. Deformation in the fault zone occurs in Jurassic aged, organic-rich limestones and consists of numerous normal and oblique-slip faults and associated folds. Migration of basinal, radiogenic fluids is indicated by elevated ⁸⁷Sr/⁸⁶Sr values for calcite veins that occur throughout the fault zone. Some of the calcite veins contain hydrocarbons sourced from deeper strata. Elevated ⁸⁷Sr/⁸⁶Sr values in the host Jurassic limestones indicate that they were also extensively altered by radiogenic fluids that migrated through microfractures in addition to major fault and fracture planes. Folded and tilted host limestones contain a pervasive secondary CRM residing in magnetite that was acquired during deformation in the Tertiary. The association between this pervasive CRM and the pervasive geochemical alteration is consistent with a genetic connection between the orogenic fluids and the CRM although the timing of CRM acquisition (Tertiary) is not consistent with structural interpretations for the timing of most veining. An alternative remagnetization mechanism which is not triggered by externally derived fluids, such as diagenesis of hydrocarbons, might account for the CRM. Hydrocarbon-bearing veins also contain a CRM that resides in magnetite, although the time for remanence acquisition is not well constrained by field tests. © 1998 John Wiley & Sons, Ltd.     

超临界流体中MoO3与WO3溶解度实验探讨

超临界地质流体以其独特的性质对金属成矿元素具有超强的萃取、层析和搬运能力,在热液矿床成矿机制研究中对揭示成矿物质的源、流和汇起着特殊和重要作用。本利用分析纯H2MoO3在高温下脱水制备了MoO3(白色斜方晶系),在冷封式高压釜中实验测定了417℃超临界条件下,MoO3在纯水中的溶解度分别为7．3(29MPa)、14．2(45MPa)、21．6(55MPa)、27．7(78MPa)、32．5(100MPa)、和34．2(150MPa)mmol／1,热液中钼的存在形式为H2M004。依据前人的实验方案,补充测定了WO3在4．0％NaCl水溶液中于450℃条件下的溶解度,其值分别为27．51(50MPa)和30．52(100MPa)mmol／l,结合前人研究结果发现,MoO3、WO3的溶解度在临界区域内具有超临界现象,在超临界条件下其溶解度与石英的超临界溶解度行为基本相似,表现为溶解度随体系温度和压力的升高而增大,这对揭示岩浆热液型和石英脉型钨、钼矿床的形成机制具有重要指导作用。     

伊宁吐拉苏火山盆地热液活动与金成矿关系

吐拉苏火山盆地中与金成矿有关的热液富含K^＋、Na^＋、F、SO4^2-和N2、O2等，是一种主要来源于岩浆．火山的热液，有大气水参于的次生热液．平均均一温度96～158℃，平均盐度0．26％～1．08％，热液活动深度0．26～0．67km，具有低温、低盐度、在地壳浅部活动的基本特征．热液活动生成围绕金矿体由内向外环状展布的黄英岩化、高级泥化、泥化和绿泥石碳酸盐化4个围岩蚀变带．与其有关的金成矿期分为原生沉积富集和次生热液交代蚀变2期，后者包括毒砂黄铁矿化、面状硅化、脉状硅化和绿泥石碳酸盐化4个成矿阶段．金富集成矿主要与黄英岩化蚀变带和面状硅化、脉状硅化2个成矿阶段密切相关．     

Three-dimensional mapping of salt stores in the Murray-Darling Basin,Australia: 2. Calculating landscape salt loads from airborne electromagnetic and laboratory data

Salt is widespread in the Australian landscape – in soil, regolith and groundwater – leading to concerns that land management practices may be putting much agricultural land and important water resources at risk of salinisation. Defining the location and nature of salt stores is an important first step in understanding the processes leading to salinity of soils, streams and groundwater resources, and predicting areas that may be at risk. Airborne geophysics can define subsurface salt stores and mobilisation pathways. Airborne electromagnetics (AEM) can map the three-dimensional conductivity structure of the landscape but does not, intrinsically, quantify the amount of salt. Salinity, moisture content, porosity and mineralogy all contribute to the electromagnetic signal, and each can vary significantly throughout the landscape.In the Lower Balonne catchment, Queensland, the relationship between AEM and the amount of salt in the landscape was quantified using laboratory analyses of pore fluids from core samples. A general statistical relationship was established between AEM conductivity and salt load (defined as the product of pore fluid salinity, porosity and moisture content)—with a significant positive correlation although data were generally widely dispersed. Comparison of calculated salt load with borehole electromagnetic logs gives insight into the factors contributing to dispersion in the AEM data.The relationship transforms bulk conductivity to salt load in 5 m layers, allowing the generation of a three-dimensional map of the salt load. This is a powerful tool for identifying areas that may require monitoring and management interventions to reduce salinity risk. An example is given of salt loads beneath an established irrigation area in the Lower Balonne catchment, Queensland.     

我国地震地下流体观测台网调整与优化方案探讨

本文首先简要介绍了我国地震地下流体观测台网的现状,然后针对其存在的主要问题提出了调整与优化的建议: ① 调整布局,重点加强我国中西部地区(105°E以西)的监测; ② 扩大规模,观测井(泉)数要达到1000个左右; ③ 全面提高观测井质量,淘汰不符合规范要求的观测井(泉),改造不完全符合规范要求的观测井,新建一批完全符合规范的观测井; ④ 优化观测项目的组合,大力发展观测井(泉)水流量观测,强化以H₂、 He、 CO₂等为主测项的断层带土壤气观测,建立断层带土壤气观测网; ⑤ 优化现有的观测模式,开展平面上的台阵式观测与垂向的多层次立体化观测; ⑥ 完善与提升现有数字化观测技术水平.      

The Mandel–Cryer effect in chemoporoelasticity

Chemoporoelastic theory is an extension of classical Biot poroelasticity that accounts for coupling with the presence and the transport of ions in the pore fluid. The impact of this extra level of coupling can be both substantial and complex. This paper relies on the two variations of Mandel's classical problem, which has become a canonical illustration of the complexity that poromechanical coupling can bring to an otherwise straightforward system. To this end, solutions for a chemoporoelastic shale cylinder and a spherical shale ball are derived. These solutions are then used to demonstrate that chemoporoelastic coupling leads to a coupled pore pressure response that is not only non‐monotonic, as in Mandel's classical case, but also demonstrates the consequences of the semi‐permeable membrane‐like nature of the shale and of the problem's two diffusion‐related timescales. This paper concludes with a discussion of the implications of these results for experimentation and modeling of so‐called reactive shales using chemoporoelastic theory. Copyright © 2009 John Wiley & Sons, Ltd.     

Reservoir rainfall‐runoff geomorphological model. II: analysis,calibration and validation

The model presented in the complementary document entitled, Reservoir rainfall‐runoff geomorphological model I: parameter application and analysis is analysed, calibrated and validated in this paper. The accuracy of simulated hydrographs is analysed by means of the efficiency defined by Nash and Sutcliffe. The sensitivity of the influence of five parameters on the behaviour of the model developed is analysed. Two different calibration and validation processes of Reservoir rainfall‐runoff geomorphological model are performed in Aixola watershed. Twelve events have been selected for calibrations and 25 for validations. With the first calibration and validation process, the model parameters are set by assigning the medians' values of the distributions obtained by means of the optimum results. The second process is performed by calibrating the most determinant parameter in the adjustment, which is the one that indicates the proportion of infiltrated water that is retained and does not flow; this is done with an empirical formulation depending on the event characteristics. Subsequently, the obtained results are validated. This last process has achieved very good adjustments in both calibrated and validated events. Copyright © 2012 John Wiley & Sons, Ltd.     

新城金矿稳定同位素地球化学特征及成矿物质的来源

新城金矿是胶东金矿集区招远—莱州成矿带的一个"焦家式"蚀变型金矿床。本文主要通过C、H、O、S、Pb同位素研究,对新城金矿成矿流体、物质来源和成矿作用进行探讨和研究。新城金矿矿石中δD值范围为-116‰~-91‰,δ18O水值范围为3.8‰~7.2‰,表明成矿流体早期来源于岩浆水,成矿晚期混入大气降水。矿石硫化物、郭家岭花岗闪长岩、玲珑花岗岩和胶东群δ34S平均值分为7.9‰、6.5‰、8.5‰和6.2‰,认为矿石硫具有对矿区地层及岩浆岩硫的继承性。硫化物矿石206Pb/204Pb=17.115~17.414,207Pb/204Pb=15.460~15.577,208Pb/204Pb=37.912~38.196,显示铅具有壳幔混合来源的特征。碳、氢、氧、硫、铅同位素反映新城金矿成矿物质和流体主要来源于深部岩浆。     

粤北302铀矿床同位素地球化学研究

位于粤北诸广山岩体东南部的302铀矿床是我国规模较大、埋藏较深的花岗岩型铀矿床之一。该矿床产于印支期油洞岩体和燕山早期长江岩体的断裂蚀变带内,矿区内NWW向基性岩脉十分发育,矿体呈似脉状、扁豆状或透镜状。同位素研究表明,矿石的沥青铀矿Sm-Nd和U-Pb等时线年龄（70 Ma）与油洞岩体（232 Ma）、长江岩体（160 Ma）的年龄相差巨大;主成矿期成矿流体的δDH2O值为-65‰～-82‰（平均为-75‰）,δ18OH2O值为6.8‰～0.6‰（平均为3.9‰）,反映出成矿流体主要由地幔流体组成;方解石的δ13C值为-8.4‰～-5.3‰,表明矿化剂ΣCO2也来自地幔;矿区内辉绿岩的（87Sr/86Sr）i值为0.70861～0.70882,花岗岩的（87Sr/86Sr）i值为0.73519～0.77152,萤石的（87Sr/86Sr）i值为0.71474～0.71697,表明成矿组分Sr可能来源于基性脉岩（幔源）与赋矿花岗岩体（壳源）,并呈不同程度的混合,而主成矿组分铀主要来源于赋矿花岗岩体。     

Cleaning Using CO2‐Based Solvents

Cleaning with hierarchy of CO₂‐based solvents is advantageous from an environmental point of view because CO₂ is non‐flammable, virtually inert, and abundant. After cleaning, the only waste stuffs generated are the contaminants that are removed from the cleaned parts. The technology is especially well suited for precision cleaning applications in which parts have intricate geometries or for applications in which parts are sensitive to water or high temperature. This review will first introduce aqueous cleaning concepts and mechanism, which is helpful to understand how to design cleaning systems using high pressure CO₂. Recent microelectronic processes for cleaning and rising of circuit wafers using CO₂‐based solvents are the main focus of the review. Additional cleaning topics include dry cleaning, separation of dyestuffs, and extraction of contaminations from soils and regeneration of catalysts.