俯冲带碳酸盐化对深部碳循环的启示:以中国西南天山碳酸盐化云母片岩为例

俯冲带可将地球表层碳输送至深部地幔,同时也记录着俯冲板片来源碳质流体的迁移沉淀机制,对地球深部碳循环具有重大影响。近年来,俯冲带脱碳机制的研究表明流体溶解脱碳作用是冷的大洋俯冲板片释放COH流体的重要方式,而上覆板块(尤其地幔楔)则被认为是缓冲这些COH流体的重要场所,甚至是俯冲带CO_2的唯一"归宿"。事实上,俯冲带岩石本身的固碳能力却受到了忽视,而对俯冲带岩石捕获和固存CO_2(carbon capture and storage,CCS)能力的评估对全球碳通量的估算尤为重要。本文以中国西南天山高压-超高压变质带中碳酸盐化云母片岩为例,探讨俯冲带岩石的碳酸盐化对深部碳循环的影响。西南天山长阿吾子一带的碳酸盐化云母片岩记录了俯冲板片起源的碳质流体对俯冲带云母片岩的交代作用,地球化学特征表明蛇纹岩释放的富水流体溶解俯冲洋壳中的碳酸盐可能是产生COH流体的重要机制。基于碳质流体对多硅白云母(Si(a.p.f.u.)=3.58～3.73)的交代及相对高压的碳酸盐矿物(主要为白云石和菱镁矿)与金红石的共生,结合区域上碳酸盐化云母片岩与高压碳酸盐化蛇纹岩(HP-ophidolomite)的伴生,我们认为云母片岩的碳酸盐化作用可能发生在俯冲板片峰期稍后的高压折返阶段。俯冲带云母片岩的固碳作用表明除了上覆板块,俯冲带岩石本身对于碳质流体也具有很好的吸收能力。初步估算表明俯冲带云母片岩的碳酸盐化每年可固存至少2.46～6.68Mt/yr,约占俯冲板片每年进碳量的4%～17%。     

水基钻井液防塌封堵材料封堵特性实验研究

提高钻井液封堵能力是有效解决硬脆性页岩、煤层等复杂地层井壁失稳的主要技术手段。本文以在一定温度、压力条件下30 min的滤失量为评价标准,对几种封堵材料的封堵特性进行了实验研究。结果表明：除超细碳酸钙外,其他材料随着加量的增加,封堵效果越来越好;乳化沥青、乳化石蜡和油溶性酚醛树脂随着温度的升高,封堵效果变差,而聚乙二醇和聚酯先变差然后又有一定程度的恢复;聚酯和超细碳酸钙能够快速封堵微裂缝;几种封堵剂均对钻井液的流变性能有较明显的影响。对各封堵材料的封堵机理分析表明：不同的封堵材料具有不同的封堵特性,分别适应不同的温度、压力条件。只有根据井下实际情况,有针对性地选择与之相适应的封堵材料,才能有效提高水基钻井液的封堵能力。     

巴音戈壁盆地塔木素铀矿床含矿砂岩成岩作用类型、演化序列及其对铀成矿的约束

勘查和研究发现部分砂岩型铀矿床中不仅有表生氧化流体作用还存在深部流体的参与,这类砂岩型铀矿床蚀变类型多样且成因复杂.塔木素砂岩型铀矿表生流体和深部流体活动都很明显,砂岩普遍固结且后生蚀变类型独特,因此,恢复成岩成矿事件及其演化过程,对揭示铀沉淀富集机理至关重要.本文通过镜下鉴定、电子探针、扫描电镜分析等,系统研究了塔木素矿床含矿砂岩成岩作用特征与后生蚀变矿物生成序列,重塑了成岩成矿事件的演化过程.研究结果显示,塔木素矿床砂岩中压实作用较弱而胶结作用很强,重结晶作用普遍,是造成目的层致密的主要原因,赤铁矿、褐铁矿化、碳酸盐化、石膏化是该地区主要的胶结类型.将该地区的成岩演化划分为沉积-早成岩阶段、早期氧化流体作用阶段、热流体改造阶段和晚期氧化流体弱改造阶段.成岩环境由弱碱性向酸性环境转变的过程中的氧化还原过渡部位是造成铀沉淀的关键,大规模的氧化作用是矿床形成的基础,后期热流体活动对早期形成的低品位铀矿石进行叠加改造,是成矿的关键环节.     

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.     

上地幔超高压流体的金刚石压砧实验研究

地球深部流体主要是NaCl-H2O溶液,越到地球深部,它赋存的温度、压力越高,性质状态也不断变化,反之,亦然。当NaCl-H2O流体进入和脱离(上升过程)超临界状态时,其性质会发生截然不同的变化,影响着各种地质过程。使用金刚石压砧在高温高压下原位观测流体的实验,用谱学方法,结合同步辐射光源技术,成为定量化研究地球深部高温超高压流体的有效方法。作者使用同步辐射光源的红外谱研究了10GPa下的NaCl-H2O溶液;在地球化学动力学实验室研究了3GPa,650℃下的NaCl-H2O溶液红外谱,此测量方法可以提供温度压力和体积等数据,能研究其状态。NaCl-H2O溶液红外谱表明水分子主要振动谱受压力和温度影响是不同的。压力增加促使水分子主要振动谱向低波数变化。但是温度增加的效应相反。常温高压下水被压缩,结晶向紧密堆积变化。高温高压下的水有气、液、固和超临界流体各相。水分子间的氢键在近临界态开始减弱,氢键网络被破坏。     

SH波入射时多个半圆形沉积谷地附近浅埋圆形孔洞的动力分析

本文采用辅助函数的思想,利用复变函数和多级坐标的方法给出了SH波入射条件下多个半圆形沉积谷地附近浅埋圆形孔洞动力分析问题的解答。将整个求解区域分割成两部分来处理,区域I为多个半圆形沉积谷地,区域II为浅埋圆形孔洞附近带半圆形凹陷的半无限弹性空间。在区域I和II中分别构造位移解,并在二个区域的“公共边界”上实施位移应力的连续条件,建立求解该问题的无穷代数方程组。最后,本文给出了算例和数值结果,并对其进行了讨论。     

Reduced Hamiltonian formalism for general-relativistic adiabatic fluids and applications

For the dynamics of general-relativistic adiabatic fluids a reduced Hamiltonian formalism is presented. For slowly moving fluids an approximation scheme is defined. The first steps of the scheme are worked out explicitly. Radiation damping and emission, and backscattering are discussed. The usefulness of the formalism for numerical relativity is pointed out.     

基于HYCOM再分析数据研究琉球海流的形成与起源

The origin of the Ryukyu Current(RC) and the formation of its subsurface velocity core were investigated using a 23-year(1993–2015) global Hybrid Coordinate Ocean Model(HYCOM) dataset. The volume transport of the RC comes from the Kuroshio eastward branch(KEB) east of Taiwan and part of the North Pacific Subtropical Gyre(pNPSG). From the surface to 2 000 m depth, the KEB(p-NPSG) transport contributes 41.5%(58.5%) to the mean total RC transport. The KEB originally forms the subsurface velocity core of the RC east of Taiwan due to blockage of the subsurface Kuroshio by the Ilan Ridge(sill depth: 700 m). Above 700 m, the Kuroshio can enter the East China Sea(ECS) over the Ilan Ridge, meanwhile, the blocked Kuroshio below 700 m turns to the right and flows along the Ryukyu Islands. With the RC flowing northeastward, the p-NPSG contribution strengthens the subsurface maximum structure of the RC owing to the blockage of the Ryukyu Ridge. In the surface layer, the pNPSG cannot form a stable northeastward current due to frequent disturbance by mesoscale eddies and water exchange through the gaps(with net volume transport into ECS) between the Ryukyu Islands.     

UHV/VHF波段SAR对次地表层土壤湿度探测与反演

首先采用一层非球形粒子植被模型,计算各波段矢量辐射传输方程Mueller矩阵一阶散射解,对比微扰法所得各波段地表粗糙面直接后向散射解,结果证明L波段植被层的散射对观测结果仍有影响,与下垫土壤粗糙表面的散射不易分离.因此,宜采用更低频率的UHF和VHF波段,对地表和次地表层能有较大的渗透深度,并可忽略植被层影响.接着,运用矢量辐射传输的3层土壤全极化Mueller矩阵解,计算UHF/VHF波段分层土壤的散射与传输,分析该两波段探测深度的差异,证实UHF波段可探测大致10-60cm深处的土壤湿度,而VHF波段探测深度能更大一些.根据第3层中土壤体湿度变化0.1时能否引起土壤表面观测的后向散射系数变化0.1dB这一判据,分析VHF波段反演第3层土壤体湿度的必要条件,证实当第2层的体湿度较小时(<0.25)才能反演层3的体温度.基于UHF/VHF两波段探测深度的差异,耗散土壤层的贡献有不同的权重,先后采用UHF和VHF,迭代法实现3层土壤湿度廓线反演.误差分析表明,该方法是有意义的.