Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

A new method of estimating the ratio between in situ rock stresses and tectonics based on empirical and probabilistic analyses

This paper describes a new procedure for assessing the ratio between in situ stresses in rock masses by means of K (K = σ_H / σ_v, being σ_H and σ_v principal stress) and tectonics for purposes of engineering geology and rock mechanics. The method combines the use of the logic decision tree and the empirical relationship between the Tectonic Stress Index, TSI, and a series of K in situ values obtained from an extensive database. The decision tree considers geological and geophysical factors affecting stress magnitudes both on the regional and local scale. The TSI index is defined by geological and geomechanical parameters. The method proposed provides an assessment of the magnitude of horizontal stresses of tectonic origin. Results for several regions of Europe are presented and the possible applications of the procedure are discussed.     

Room-temperature equation of state of Li<Subscript>2</Subscript>VOSiO<Subscript>4</Subscript> up to 8.5 GPa

High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li₂VOSiO₄, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V ₀ and K ₀ using the data weighted by the uncertainties in V. The bulk modulus is K ₀ = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K ₀(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K ₀(a) = 195 ± 3 GPa).     

Biaxial test simulations using a packing of polygonal particles

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.     

引水工程秦巴段隧洞地应力模拟及工程地质问题

利用Ansys有限元软件对三峡引水工程秦巴段线路不同深度、不同截面形态隧洞围岩的应力重分布情况进行模拟计算,得到圆形隧洞、城门形隧洞和马蹄形隧洞围岩的应力数值和等值线图.利用库仑一纳维尔强度准则,对花岗岩区及灰岩区隧洞围岩的剪切破坏进行分析;利用三种岩爆应力判别指标,对岩爆进行初步预测;进而对不同深度、不同截面形态的隧洞围岩的稳定性进行分析;最后对引水工程隧洞设计中截面形态的选择给出了初步建议.     

饱和粉砂不稳定性的试验研究

通过对净砂和级配良好粉砂(含10 %粉土)进行一系列三轴固结不排水试验（CU）,研究了粉土、孔隙比和围压对饱和粉砂不稳定性的影响。试验结果表明,净砂与粉砂在不排水剪切条件下均会出现应变软化现象（即不稳定性）。同一围压下脆性指数(IB)随孔隙比增加,但不稳定线的应力比随孔隙比增加而减小。引用等效粒间孔隙比(ege)后,净砂和粉砂在ege-ln p?平面上拥有基本相同的临界状态线。在临界状态理论及等效粒间孔隙比的基础上,提出在同一修正状态参数(?ge)下净砂和级配良好粉砂有相似的不稳定性。     

岩石破坏前后曲线分类及脆-延转换围压研究——蚀变岩常规三轴压缩试验Ⅰ

蚀变岩是工程中少见的软弱岩类,在西南某重大水电工程中,蚀变岩处于工程的重要部位,为保证工程的长期稳定性,对蚀变岩力学特性进行了深入全面的试验研究.通过对孔隙度不同的饱水蚀变岩进行系统的常规三轴压缩试验和总结分析,提出了蚀变岩三轴压缩下破坏前应力.应变曲线可分为3大类,破坏后应力-应变曲线亦可分为3大类的形态模式.并得出结论:蚀变岩的破坏类型受围压与孔隙度的共同影响,在给定的12 MPa围压下蚀变岩以脆性破坏为主,只有孔隙度大于16%且围压大于4 MPa时才有可能进入脆-延转换状态,且脆-延转换围压随孔隙度增加而降低,临界状态应力比随孔隙度增大而增加.     

Predictability of Interannual Variability in the Kuroshio Transport South of Japan Based on Wind Stress Data over the North Pacific

It is expected that a roughly two-year forecast of the Kuroshio transport variation can be made from a past record of wind stress data over the ocean, since it takes nearly ten years for the first-mode baroclinic Rossby wave to traverse the entire basin in the midlatitude North Pacific (∼30°N). We therefore investigated the predictability using an ocean general circulation model driven by the wind stress data from the National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis. Referring to a hindcast experiment as the control run, we carried out fifteen forecast experiments, the initial conditions of which are taken from the hindcast experiment at intervals of two years during the period from the end of 1969 to the end of 1997. Each of the forecast experiments is driven only by wind stress in the year preceding each experiment. The forecasted Kuroshio transport anomaly south of Japan agrees better with the hindcasted one during the first two years of the forecast in most cases. In some cases, however, significant disagreements occur, most of which are likely due to larger unpredictable variations caused by wind stress anomalies near Japan. At the end of forecast year 2, the anomaly correlation coefficient is about 0.7, and rms of the forecast error is smaller than rms of the hindcasted anomaly. These results indicate that the prediction of the interannual variability in the Kuroshio transport could be made two years in advance at a statistically significant level. This revised version was published online in July 2006 with corrections to the Cover Date.     

秦山核电站邻近水域的流况分析

本文分析了秦山核电站邻近水域各测站的实测流、潮流和佘流分布及季节变化。结果表明:测区内潮流为非正规丰日浅海潮流,其运动形式呈往复流。核电站二期工程取水口附近(L_1,18站)为一大流速区,而一期工程出水口周围(L_2,L_2′站)有一相对小的流速区。大流速区落潮流历时大于涨潮流历时,而相对小流速区则相反;大流速区的余流较小,而小流速区的余流大。在四个季节中,涨潮流速秋季最大,春季次之,夏季最小;落潮流速秋季最大,夏季次之,春季最小。余流冬、秋两季较大。在实测流中以潮流为主,径流和季风的作用也相当显著。     

盐胁迫对番茄同工酶基因表达的影响

分析了普通番茄（Lycopersicumesculentum）在NaCl胁迫下酯酶（EST）和过氧化物酶（PRX）同工酶的变化，考察了盐胁迫对10个同工酶位点21个等位基因在特定组织中表达的影响。发现许多EST和PRX等位基因在盐胁迫下表达，产生盐诱导同工酶；另有些等位基因的表达受盐抑制，它们在盐胁迫下的表达活性显著减弱或消失。实验表明，EST和PRX同工酶表达的变化与番茄对盐胁迫的遗传适应性有密切关系。