Synthesis of soil‐hydraulic properties and infiltration timescales in wildfire‐affected soils

We collected soil‐hydraulic property data from the literature for wildfire‐affected soils, ash, and unburned soils. These data were used to calculate metrics and timescales of hydrologic response related to infiltration and surface runoff generation. Sorptivity (S) and wetting front potential (Ψ_f) were significantly different (lower) in burned soils compared with unburned soils, whereas field‐saturated hydraulic conductivity (K_fs) was not significantly different. The magnitude and duration of the influence of capillarity during infiltration was greatly reduced in burned soils, causing faster ponding times in response to rainfall. Ash had large values of S and K_fs but moderate values of Ψ_f, compared with unburned and burned soils, indicating ash has long ponding times in response to rainfall. The ratio of S²/K_fs was nearly constant (~100 mm) for unburned soils but more variable in burned soils, suggesting that unburned soils have a balance between gravity and capillarity contributions to infiltration that may depend on soil organic matter, whereas in burned soils the gravity contribution to infiltration is greater. Changes in S and K_fs in burned soils act synergistically to reduce infiltration and accelerate and amplify surface runoff generation. Synthesis of these findings identifies three key areas for future research. First, short timescales of capillary influences on infiltration indicate the need for better measurements of infiltration at times less than 1 min to accurately characterize S in burned soils. Second, using parameter values, such as Ψ_f, from unburned areas could produce substantial errors in hydrologic modeling when used without adjustment for wildfire effects, causing parameter compensation and resulting underestimation of K_fs. Third, more thorough measurement campaigns that capture soil‐structural changes, organic matter impacts, quantitative water repellency trends, and soil‐water content along with soil‐hydraulic properties could drive the development of better techniques for numerically simulating infiltration in burned areas.     

Numerical simulation of agricultural sediment and pesticide runoff: RZWQM and PRZM comparison

Agricultural sediment and pesticide runoff is a widespread ecological and human health concern. Numerical simulation models, such as Root Zone Water Quality Model (RZWQM) and Pesticide Root Zone Model (PRZM), have been increasingly used to quantify off‐site agricultural pollutant movement. However, RZWQM has been criticized for its inability to simulate sedimentation processes. The recent incorporation of the sedimentation module of Groundwater Loading Effects of Agricultural Management Systems has enabled RZWQM to simulate sediment and sediment‐associated pesticides. This study compares the sediment and pesticide transport simulation performance of the newly released RZWQM and PRZM using runoff data from 2 alfalfa fields in Davis, California. A composite metric (based on coefficient of determination, Nash–Sutcliffe efficiency, index of agreement, and percent bias) was developed and employed to ensure robust, comprehensive assessment of model performance. Results showed that surface water runoff was predicted reasonably well (absolute percent bias <31%) by RZWQM and PRZM after adjusting important hydrologic parameters. Even after calibration, underestimation bias (?89% ≤ PBIAS  ≤ ?36%) for sediment yield was observed in both models. This might be attributed to PRZM's incorrect distribution of input water and uncertainty in RZWQM's runoff erosivity coefficient. Moreover, the underestimation of sediment might be less if the origin of measured sediment was considered. Chlorpyrifos losses were simulated with reasonable accuracy especially for Field A (absolute PBIAS  ≤ 22%), whereas diuron losses were underestimated to a great extent (?98% ≤ PBIAS  ≤ ?65%) in both models. This could be attributed to the underprediction of herbicide concentration in the top soil due to the limitations of the instantaneous equilibrium sorption model as well as the high runoff potential of herbicide formulated as water‐dispersible granules. RZWQM and PRZM partitioned pesticides into the water and sediment phases similarly. According to model predictions, the majority of pesticide loads were carried via the water phase. On the basis of this study, both RZWQM and PRZM performed well in predicting runoff that carried highly adsorptive pesticides on an event basis, although the more physically based RZWQM is recommended when field‐measured soil hydraulic properties are available.     

Hydrologic response of engineered media in living roofs and bioretention to large rainfalls: experiments and modeling

The hydrologic response of engineered media plays an important role in determining a stormwater control measure's ability to reduce runoff volume, flow rate, timing, and pollutant loads. Five engineered media, typical of living roof and bioretention stormwater control measures, were investigated in laboratory column experiments for their hydrologic responses to steady, large inflow rates. The inflow, medium water content response, and outflow were all measured. The water flow mechanism (uniform flow vs. preferential flow) was investigated by analyzing medium water content response in terms of timing, magnitude, and sequence with depth. Modeling the hydrologic process was conducted in the HYDRUS‐1D software, applying the Richards equation for uniform flow modeling, and a mobile–immobile model for preferential flow modeling. Uniform flow existed in most cases, including all initially dry living roof media with bimodal pore size distributions and one bioretention medium with unimodal pore size distribution. The Richards equation can predict the outflow hydrograph reasonably well for uniform flow conditions when medium hydraulic properties are adequately represented by appropriate functions. Preferential flow was found in two media with bimodal pore size distributions. The occurrence of preferential flow is more likely due to the interaction between the bimodal pore structure and the initial water content rather than the large inflow rate.     

Experimental study on the hydrological performance of green roofs in the application of novel biochar

Biochar has the potential to be a soil amendment in green roofs owing to its water retention, nutrient supply, and carbon sequestration application. The combined effects of biochar and vegetated soil on hydraulic performance (e.g., saturated hydraulic conductivity, retention and detention, and runoff delay) are the crucial factor for the application of the novel biochar in green roofs. Recent studies investigated soil water potential (i.e., suction) either on vegetated soil or on biochar-amended soil but rarely focused on their integrated application. With the purpose of investigating the hydraulic performance of green roofs in the application of biochar, the combined effect of biochar and vegetated soil on hydrological processes was explored. Artificial rainfall experiments were conducted on the four types of experimental soil columns, including natural soil, biochar-amended soil, vegetated natural soil, and vegetated biochar-amended soil. The surface ponding, bottom drainage and the volumetric water content were measured during the rainfall test. Simulation method by using HYDRUS-1D was adopted for estimating hydraulic parameters and developing modelling analysis. The results indicated that the saturated hydraulic conductivity of vegetated soil columns were higher than bare soil columns. The addition of biochar decreased the saturated hydraulic conductivity, and the magnitude of decrease was much significant in the case of vegetated soil. The influence of vegetation on permeability is more prominent than biochar. The vegetated biochar-amended soil has the highest retention and detention capacity, and shows a preferable runoff delay effect under heavy rain among the four soil columns. The results from the present study help to understand the hydrological processes in the green roof in the application of biochar, and imply that biochar can be an alternative soil amendment to improve the hydraulic performance.     

Assessing the effects of catchment‐scale urban green infrastructure retrofits on hydrograph characteristics

Run‐off from impervious surfaces has pervasive and serious consequences for urban streams, but the detrimental effects of urban stormwater can be lessened by disconnecting impervious surfaces and redirecting run‐off to decentralized green infrastructure. This study used a before–after‐control‐impact design, in which streets served as subcatchments, to quantify hydrologic effectiveness of street‐scale investments in green infrastructure, such as street‐connected bioretention cells, rain gardens and rain barrels. On the two residential treatment streets, voluntary participation resulted in 32.2% and 13.5% of parcels having green infrastructure installed over a 2‐year period. Storm sewer discharge was measured before and after green infrastructure implementation, and peak discharge, total run‐off volume and hydrograph lags were analysed. On the street with smaller lots and lower participation, green infrastructure installation succeeded in reducing peak discharge by up to 33% and total storm run‐off by up to 40%. On the street with larger lots and higher participation, there was no significant reduction in peak or total stormflows, but on this street, contemporaneous street repairs may have offset improvements. On the street with smaller lots, lag times increased following the first phase of green infrastructure construction, in which streetside bioretention cells were built with underdrains. In the second phase, lag times did not change further, because bioretention cells were built without underdrains and water was removed from the system, rather than just delayed. We conclude that voluntary green infrastructure retrofits that include treatment of street run‐off can be effective for substantially reducing stormwater but that small differences in design and construction can be important for determining the level of the benefit. Copyright © 2015 John Wiley & Sons, Ltd.     

Trend and extreme occurrence of precipitation in a mid‐latitude Eurasian steppe watershed at various time scales

The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann–Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large precipitation anomalies. The objectives of this study were to (1) formulate a trend analysis approach that considers nonstationarity due to step changes, (2) use this approach to detect trends and extreme occurrences of precipitation in a mid‐latitude Eurasian steppe watershed in North China, and (3) examine how runoff responds to precipitation trends in the study watershed. Our results indicate that annual precipitation underwent a marginal step jump around 1995. The significant annual downward trend after 1994 was primarily due to a decrease in summer rainfall; other seasons exhibited no significant precipitation trends. At a monthly scale, July rainfall after 1994 exhibited a significant downward trend, whereas precipitation in other months had no trend. The percentage of wet days also underwent a step jump around 1994 following a significant decreasing trend, although the precipitation intensity exhibited neither a step change nor any significant trend. However, both low‐frequency and high‐frequency precipitation events in the study watershed occurred more often after than before 1994; probably as either a result or an indicator of climate change. In response to these precipitation changes, the study watershed had distinctly different precipitation‐runoff relationships for observed annual precipitations of less than 300 mm, between 300 and 400 mm, and greater than 400 mm. Copyright © 2013 John Wiley & Sons, Ltd.     

Effect of rainfall uncertainty on the performance of physically based rainfall–runoff models

This paper analyses the effect of rain data uncertainty on the performance of two hydrological models with different spatial structures: a semidistributed and a fully distributed model. The study is performed on a small catchment of 19.6 km² located in the north‐west of Spain, where the arrival of low pressure fronts from the Atlantic Ocean causes highly variable rainfall events. The rainfall fields in this catchment during a series of storm events are estimated using rainfall point measurements. The uncertainty of the estimated fields is quantified using a conditional simulation technique. Discharge and rain data, including the uncertainty of the estimated rainfall fields, are then used to calibrate and validate both hydrological models following the generalized likelihood uncertainty estimation (GLUE) methodology. In the storm events analysed, the two models show similar performance. In all cases, results show that the calibrated distribution of the input parameters narrows when the rain uncertainty is included in the analysis. Otherwise, when rain uncertainty is not considered, the calibration of the input parameters must account for all uncertainty in the rainfall–runoff transformation process. Also, in both models, the uncertainty of the predicted discharges increase in similar magnitude when the uncertainty of rainfall input increase.     

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.     

Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.