冷冻牡蛎贮存过程中脂溶性有毒物质的变化研究

牡蛎是我国出口量较大的水产品之一,由于产品本身的特殊性,在生长过程中易产生腹泻性贝毒(DSP).本实验中原料牡蛎DSP生物法检测结果为阴性,冷冻贮存4个月后检测结果即为阳性.本研究以分析这一变化原因为目的,采用LC-MS法对DSP生物检测的阳性样品进行确认,结果表明,生物法DSP检测的结果为假阳性,造成生物法DSP检测中小白鼠死亡的是牡蛎在贮藏过程中产生的脂溶性有毒物质.进一步分析确定该有毒物质为牡蛎脂肪水解物--游离脂肪酸.同时本研究对牡蛎在不同贮存温度和贮存时间下产生的游离脂肪酸含量进行了测定,在-10 ℃贮存温度下,贮存0,2,4,6,8,10个月,游离脂肪酸的变化范围为5.2～788.6 mg/kg;在-10 ℃,-18 ℃,-25 ℃贮存温度下,贮存4个月,游离脂肪酸的变化范围为92.5～389 mg/kg.     

Effect of connecting rain barrels on the storage size reduction

In this article, the possibility of sharing rain barrels and the potential benefit of reducing storage size through physical and non‐physical connections of rain barrels in a community are investigated. Using the concepts of homogeneous/heterogeneous users in rainwater harvesting systems (RWHS), two simple cases of a community composed of four prospective users are examined. The first is performed with the users who have the same mean and variance in water demands (homogeneous users), and the second is with the users with different means and variances (heterogeneous users). To take account for the rainfall characteristics in different places, historical records from six cities in the USA are used for storage–reliability–yield analysis. The result indicates that required total storage can be reduced by connecting multiple rain barrels. In addition, a significant difference is found between homogeneous and heterogeneous user groups. Homogeneous users do not achieve a substantial benefit from connecting their rain barrels; these users may even be disadvantaged by sharing. In contrast, heterogeneous users receive benefit by reducing the total required storage. Most benefit is expected between users with maximum difference in mean water demands. The reduction in storage size was as considerable as 37% in this study. The quantity of storage reduction depends on locations and target reliabilities. Knowledge of the benefits and limitations of rain barrel connections can improve RWHS performance through ability to customize a network plan for individual users. Copyright © 2011 John Wiley & Sons, Ltd.     

Enhancement of the channel routing module in SWAT

The objective of this study is to demonstrate that the channel flow routing techniques used in the Soil and Water Assessment Tool (SWAT) can be sometimes inappropriate for runoff simulation in small basins. Simulated hydrographs have a tendency to underestimate peak flows or may send a false signal during the recession periods when SWAT is applied to the Mihocheon Basin in South Korea. This was particularly evident for sub‐basins that had a short travel time of much less than a day. In order to enhance the channel routing module in SWAT, an alternative routing technique in which Manning relationship is combined with a simple channel reach continuity equation is proposed in the present study. The advantage of the proposed routing technique is that parameters are readily available from channel morphological data and that it is applicable to small basins. Through simulations of specific events, this routing module that is incorporated into SWAT is almost free from instability errors and produces realistic flow depths and velocities unlike the original version of SWAT with Muskingum method. Copyright © 2009 John Wiley & Sons, Ltd.     

Preliminary 3–D geological model of the Kalgoorlie region,Yilgarn Craton,Western Australia,based on deep seismic‐reflection and potential‐field data

The granite‐greenstone terranes of the Eastern Goldfields Province, Yilgarn Craton, Western Australia, are a major Australian and world gold and nickel source. The Kalgoorlie region, in particular, hosts several world‐class gold deposits. To attempt to understand why these deposits occur where they do, it is important to understand the crustal architecture in the region and how the major mineral systems operate in this architecture. One way to understand these relationships is to develop a detailed 3–D geological model for the region. The best method to map the 3–D geometry of major geological structures is by acquisition and interpretation of seismic‐reflection profiles. To contribute to this aim, a grid of deep seismic‐reflection traverses was acquired in 1999 to examine the 3–D geometry of the region in an area including the Kalgoorlie mineral region and mineral fields to the north and west. This grid was tied to the 1991 regional deep seismic traverse and 1997 high‐resolution seismic profiles in the same region. The grid covers an area measuring approximately 50 km wide by 50 km long and extended to a depth of approximately 50 km (below the base of the crust in this region). The resulting 3–D geological model was further constrained by both surface geological data and geophysical interpretations, with the seismic interpretations themselves also constrained by gravity and magnetic modelling. The 3–D model was used to investigate the geometric relationships between the major faults and shear zones in the area, the relationship between the granite‐greenstone succession and the basement, and the spatial relationships between the greenstones and the granites. Interpretation of the grid of seismic lines and construction of the 3–D geological model confirmed the existence of the detachment surface and led to the recognition that the granite‐greenstone contact usually occurs at a much shallower level than the detachment. Also, west‐dipping faults in the vicinity of the Golden Mile, including the Abattoir Shear through to Boulder‐Lefroy Fault, appear to be more important than previously thought in controlling the structure of that area. An antiformal thrust stack occurs beneath a triangle zone centred on the Golden Mile. The Black Flag Group was deposited in a probable extensional setting, and late extension was also probably more important than previously thought. The granite‐gneiss domes were uplifted by the formation of antiformal thrust stacks at depth beneath them.     

Potential Influence of a Developing La Niña on the Sea-Ice Reduction in the Barents–Kara Seas

Abstract

The potential influence of a developing La Niña on Arctic sea-ice annual variability is investigated using both observational data and an atmospheric general circulation model. It is found that during the developing phase of an eastern Pacific (EP) La Niña event in June, July, and August (JJA) and September, October, and November (SON), the sea-ice concentration (SIC) over the Barents–Kara Seas declines more than 15%. The local atmospheric circulation pattern associated with the EP La Niña is characterized as a weak decrease in geopotential height over the Barents–Kara Seas, combined with an anticyclone in the North Atlantic. The corresponding southerly winds push warm waters northward into the key sea-ice reduction region and directly accelerate sea-ice melt. Meanwhile, the abundant moisture contained in the lower troposphere is transported into the Arctic region by winds resulting from the local barotropic structure. The humid atmosphere contributes to both net shortwave and longwave radiation and thus indirectly accelerates the decline in sea ice. Simulations by the European Centre Hamburg Model, version 5.4, are forced by observed sea surface temperature anomalies associated with EP La Niña events. The results of the simulations capture the North Atlantic anticyclone and reproduce the moisture transport, which supports the premise that an EP La Niña plays a crucial role in sea-ice reduction over the Barents–Kara sector from the perspective of atmospheric circulation and net surface heat flux.     

Constraining sequence stratigraphy in north Australian basins: SHRIMP U–Pb zircon geochronology between Mt Isa and McArthur River

Fifty‐five new SHRIMP U–Pb zircon ages from samples of northern Australian ‘basement’ and its overlying Proterozoic successions are used to refine and, in places, significantly change previous lithostratigraphic correlations. In conjunction with sequence‐stratigraphic studies, the 1800–1580 Ma rock record between Mt Isa and the Roper River is now classified into three superbasin phases—the Leichhardt, Calvert and Isa. These three major depositional episodes are separated by ～20 million years gaps. The Isa Superbasin can be further subdivided into seven supersequences each 10–15 million years in duration. Gaps in the geological record between these supersequences are variable; they approach several million years in basin‐margin positions, but are much smaller in the depocentres. Arguments based on field setting, petrography, zircon morphology, and U–Pb systematics are used to interpret these U–Pb zircon ages and in most cases to demonstrate that the ages obtained are depositional. In some instances, zircon crystals are reworked and give maximum depositional ages. These give useful provenance information as they fingerprint the source(s) of basin fill. Six new ‘Barramundi’ basement ages (around 1850 Ma) were obtained from crystalline units in the Murphy Inlier (Nicholson Granite and Cliffdale Volcanics), the Urapunga Tectonic Ridge (‘Mt Reid Volcanics’ and ‘Urapunga Granite’), and the central McArthur Basin (Scrutton Volcanics). New ages were also obtained from units assigned to the Calvert Superbasin (ca 1740–1690 Ma). SHRIMP results show that the Wollogorang Formation is not one continuous unit, but two different sequences, one deposited around 1730 Ma and a younger unit deposited around 1722 Ma. Further documentation is given of a regional 1725 Ma felsic event adjacent to the Murphy Inlier (Peters Creek Volcanics and Packsaddle Microgranite) and in the Carrara Range. A younger ca 1710 Ma felsic event is indicated in the southwestern McArthur Basin (Tanumbirini Rhyolite and overlying Nyanantu Formation). Four of the seven supersequences in the Isa Superbasin (ca 1670–1580 Ma) are reasonably well‐constrained by the new SHRIMP results: the Gun Supersequence (ca 1670–1655 Ma) by Paradise Creek Formation, Moondarra Siltstone, Breakaway Shale and Urquhart Shale ages grouped between 1668 and 1652 Ma; the Loretta Supersequence (ca 1655–1645 Ma) by results from the Lady Loretta Formation, Walford Dolomite, the upper part of the Mallapunyah Formation and the Tatoola Sandstone between ca 1653 and 1647 Ma; the River Supersequence (ca 1645–1630 Ma) by ages from the Teena Dolomite, Mt Les and Riversleigh Siltstones, and Barney Creek, Lynott, St Vidgeon and Nagi Formations clustering around 1640 Ma; and the Term Supersequence (ca 1630–1615 Ma) by ages from the Stretton Sandstone, lower Doomadgee Formation and lower part of the Lawn Hill Formation, mostly around 1630–1620 Ma. The next two younger supersequences are less well‐constrained geochronologically, but comprise the Lawn Supersequence (ca 1615–1600 Ma) with ages from the lower Balbirini Dolomite, and lower Doomadgee, Amos and middle Lawn Hill Formations, clustered around 1615–1610 Ma; and the Wide Supersequence (ca 1600–1585 Ma) with only two ages around 1590 Ma, one from the upper Balbirini Dolomite and the other from the upper Lawn Hill Formation. The Doom Supersequence (<1585 Ma) at the top of the Isa Superbasin is essentially unconstrained. The integration of high‐precision SHRIMP dating from continuously analysed stratigraphic sections, within a sequence stratigraphic context, provides an enhanced chronostratigraphic framework leading to more reliable interpretations of basin architecture and evolution.     

On the magnetic field diffusion in mhd modeling of the inner coma of comet halley

Abstract

Some approaches of one-dimensional time-dependent magneto-hydrodynamic modeling of the structure of the inner coma of comet Halley are considered. The influence of the magnetic field diffusion on this structure is studied. The solution of Cravens (1989) approach containing classic magnetic diffusion is compared with an approach containing a specific diffusion, caused by non-instantaneous mass-loading of new ions. A case with no magnetic field is also considered. Common features of all the solutions are obtained. Special attention is paid to the sharp velocity jump, synchronized with a local density pick. Some differences between two types of magnetic field diffusion are discussed. A possible connection is supposed between this consideration and the large-scale shock fitting modeling of the solar plasma-comet interaction.     

Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.     

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.     

Response of detrital zircon and monazite,and their U–Pb isotopic systems,to regional metamorphism and host‐rock partial melting,Cooma Complex,southeastern Australia

Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ～12°C/10⁶y from ～730 to ～170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton.