Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.     

Multiple episodes of tectonothermal processes in the Eastern Ghats granulite belt

A suite of rocks from Borra Carbonate Granulite Complex (BCGC) in the Eastern Ghats granulite belt displays superposed structures and overprinted mineral assemblages that reveal multiple episodes of tectonothermal reworking of the complex under granulite facies condition. Five distinct episodes of deformation (D₁, D₂, D₃, D₄ and D₅) and four phases of metamorphism (M₁, M₂, M₃ and M₄) are recorded. The signature of the earliest tectonothermal event, D₁ is a gneissic foliation (S₁) denned by segregation of peak granulite facies mineral assemblages corresponding to prograde M₁ metamorphism. M₂ metamorphic overprint represents an episode of near-isobaric cooling of the complex under a static condition. D₂ represents an episode of ductile deformation manifested by isoclinal folding (F₂) and associated extensional structures, within a broad framework of coaxial bulk deformation. The present study reveals that D₂ took place subsequent to M₂ - Subsequent deformation, D₃, produced F₃ folds and also deformations of boudins formed during D₂. M₃, which is synchronous with F₃, represents a near isothermal decompression of the BCGC. This was followed by a weak structural readjustment (D₄), producing E-W cross folds. The latter was not, however, associated with any recognizable petrological reworking. In the terminal events, deformation (D₅) and mineral reactions (M₄) were localized along narrow intersecting shear zones. The latter acted as channelways for carbonic and still later hydrous fluid infiltration. The available thermobarometric data from BCGC and other areas of the Eastern Ghats belt reveal that reworking during M₂ and M₃ ensued in a thermally perturbed regime. The high thermal regime might also have persisted during carbonic fluid infiltration related to terminal reworking (M₄).     

Regionalization of unit hydrograph parameters: 1. Comparison of regression analysis techniques

Hydrologic regionalization is a useful tool that allows for the transfer of hydrological information from gaged sites to ungaged sites. This study developed regional regression equations that relate the two parameters in Nash's IUH model to the basin characteristics for 42 major watersheds in Taiwan. In the process of developing the regional equations, different regression procedures including the conventional univariate regression, multivariate regression, and seemingly unrelated regression were used. Multivariate regression and seeming unrelated regression were applied because there exists a rather strong correlation between the Nash's IUH parameters. Furthermore, a validation study was conducted to examine the predictability of regional equations derived by different regression procedures. The study indicates that hydrologic regionalization involving several dependent variables should consider their correlations in the process of establishing the regional equations. The consideration of such correlation will enhance the predictability of resulting regional equations as compared with the ones from the conventional univariate regression procedure.     

The separation of the influence of nutrients and climate on the varve time-series of baldeggersee, Switzerland

The varve data-set from a freeze-core taken in the deepest part of Baldeggersee was subjected to different multivariate statistical analyses in order to estimate the amount of variance in the varve thickness measures explicable by past climate and by the trophic state of the lake. A comparison of two different time-periods (1902 to1992 versus 1920 to 1980) revealed that the lake restoration programme since 1982 has had a significant impact on the formation of the seasonal layers. Results of the partitioning of the variance in the varve thickness measures showed that about two thirds of the variance are unexplained by a climate and trophic state model and that trophic state explains 6%, whereas climate accounts for about 28% of the variance before the effect of lake restoration had a strong impact on the varves. Among the climate parameters the amount of annual precipitation is a strong predictor for explaining the thickness of both dark layer and total couplet thickness, whereas summer precipitation is important for the thickness of the light layer.     

Regionalization of unit hydrograph Parameters: 2. Uncertainty analysis

Hydrologic model parameters obtained from regional regression equations are subject to uncertainty. Consequently, hydrologic model outputs based on the stochastic parameters are random. This paper presents a systematic analysis of uncertainty associated with the two parameters, N and K, in Nash's IUH model from different regional regression equations. The uncertainty features associated with N and K are further incorporated to assess the uncertainty of the resulting IUH. Numerical results indicate that uncertainty of N and K from the regional regression equations are too significant to be ignored.     

Regionalization of unit hydrograph Parameters: 2. Uncertainty analysis

Hydrologic model parameters obtained from regional regression equations are subject to uncertainty. Consequently, hydrologic model outputs based on the stochastic parameters are random. This paper presents a systematic analysis of uncertainty associated with the two parameters, N and K, in Nash's IUH model from different regional regression equations. The uncertainty features associated with N and K are further incorporated to assess the uncertainty of the resulting IUH. Numerical results indicate that uncertainty of N and K from the regional regression equations are too significant to be ignored.     

地球脉动——表现、级别及与古地磁的联系

地球脉动的概念是指地球在其历史中曾发生膨胀和收缩的周期性变化。其根据是构造变动、岩浆活动、地磁极倒转以及海平面升降等方面，在地球的膨胀和收缩期，均有各种表现。构造 海平面升降在地球收缩期形成海退，在膨胀期形成海侵。在一个地球脉动旋回的不同时期，地表、海平面和洋底之间的相互关系均有变化，因而形成“层序”的沉积记录。地磁场的强度和地磁极倒转频率在显生宙有明显变化，有高峰期和平静期。这种频率变化与构造变动和岩浆活动都有对应关系，特别是４Ｍａ为准周期的地磁极倒转频率与海底扩张、洋壳形成速率之间具有良好的对应关系。地球脉动旋回可以分为不同的级次，构成级别体系：超级旋回约１Ｇａ，巨旋回２５０～３００Ｍａ，一级旋回５０～１５０Ｍａ，二级旋回５～５０Ｍａ，三级旋回１～５Ｍａ，均可与构造旋回相对应，更高的级次对构造不形成影响。三级及更长的脉动旋回可能受深部过程的控制。中、新生代以来，地球脉动是在地球适度膨胀的背景下进行的。     

地球演化中最大的两级节律

地球演化中表现出的最大两级节律为１０×１０８ａ和２×１０８ａ。每２个相邻节律可合并为一个周期，因而地球演化的最大两级周期为２０×１０８ａ和４×１０８ａ。岩石学、地层学和构造地质学方面诸多证据都说明这种划分的合理性。对于地球演化中的这类大型节律及周期性的成因机制，用笔者已提出的“地球多级驻波脉动理论模型”可以得到较合理的解释。     

基于复模态的有限元模型修正算法

针对地下结构地震响应分析中无限地基辐射阻尼问题，引入复模态情况下的具有非简化的堆积阻尼矩阵的阻尼模型，并针对具有集中质量阵的阻尼模型提出了合并与质量有关的阻尼和堆积阻尼的思想，并据此提出了一种修正此类有限元模型的两步法，首先从复模态参数中提取实模态参数，采用基于模态残余力的识别算法修正刚度矩阵，然后根据复模态参数和已得的刚度矩阵来识别阻尼模型中的刚度参与系数和质量阻尼堆积阻尼联合矩阵。     

数据分析法确定嶂山闸闸基渗透压力

闸基渗透压力是影响水闸闸室稳定的关键性因素。当水闸同时受到上下游水位差、基底承压水头、粘性土地基扬压力滞后等多重因素作用时 ,闸基渗透压力的估算就变得比较困难。通过对嶂山闸闸基历年实测渗透压力数据进行统计分析 ,初步揭示其基底渗透压力的变化规律 ,为该闸闸室稳定性分析提供依据。