ICP—AES法分析辉锑矿

本文针对辉锑矿成分复杂、主元素Sb易水解、部分元素易挥发,酸不溶元素的存在以及元素之间的干扰等问题,拟定了酸溶和碱熔分解试样的分析流程。在酸溶系统中结合TBP萃淋树脂和巯基棉分离富集分组,ICP-AES法测定Fe、Ca、Mg、Cu、Mn、Pb、Zn、Co、Ni、Au、Ag、In、Tl、Cd、Bi、Ga、Mo、Se、Te、As等20个元素。碱熔系统不分离主元素,用校正因素校正元素间光谱干扰并采用内标法ICP-AES测定Al、Ti、V、Ba、Sr、Sn、Sc、Cr、Be、Si和Sb等11个元素。试样验证表明,方法可行。     

Radon in soil anomaly observed at Los Azufres geothermal field,Michoacan: a possible precursor of the 1985 Mexico earthquake (Ms = 8.1)

A radon anomaly in a nuclear track detector placed on a fault was detected prior to the destructive (Ms = 8.1) Mexican earthquake of 19 September 1985. The fault is a structural feature of the geothermal field Los Azufres, 260 km NE of the epicentral area. Since no other phenomenon can be found as a possible cause for the radon anomaly, it is proposed that preseismic regional stress perturbations may produce changes in the fluid transport patterns at the fault, suggesting that radon measurements in similar conditions could provide a good precursor in high seismic risk areas.     

川西南干热河谷赤按人工林生物量和营养元素含量

用林木生物量回归方程，求得川西南干热河谷五年生赤桉纯林中乔木层生物量１３１３３．９ｋｇ／ｈａ（年平均生长量８０７９．７ｋｇ／ｈａ），草本层生物量５５２．０ｋｇ／ｈａ（枯落物现存量５９１．６ｋｇ／ｈａ）；赤桉与山毛豆混交林林分生物量２７１８６．９ｋｇ／ｈａ，其中赤桉生物量１６４９４．３ｋｇ／ｈａ（年平均生长量６６２０．２ｋｇ／ｈａ），灌木层生物量１０３６３．６ｋｇ／ｈａ，草本层生物量３２９．０ｋｇ／ｈａ（枯落物现存量１２６４．３ｋｇ／ｈａ）．混交林中赤桉生长好于纯林中赤桉的生长。林分营养元素含量不同植物差别很大，同种植物各器官也有所差别．各器官中营养元素含量顺序一般为：ｃａ＞Ｎ＞Ｍｇ＞Ｋ＞Ｐ，Ｐ是林地土壤缺乏的元素。     

THE NUMERICAL SIMULATION OF THE ICE AGE CLIMATE

Using the lAP two-level general circulation model,the ice age July climate was simulated through the surface conditions of 18 000 years before present assembled by the CLIMAP Project.Comparing with the present July simulation results,the ice age atmosphere is found to have a substantially lower temperature,precipitation,and cloudiness,higher sea-level pressure,especially in the high latitude land region of the Northern Hemisphere and Antarctica.When the CO₂ content is set as the modern value the climatic response is very small,which shows that the problems of CO₂ sensitivity should be studied by means of coupled models.It is also pointed out that there are some common characteristics between CO2-induced climatic changes and the ice age surface condition-induced climatic changes,which may give us some insight into how climate responds to external forcings.     

岩石颗粒解离试验研究

试验确定，在用HCI和NaOH试剂解离硅质胶结的沉积岩时，浓度5％的试剂即可达到解离度95％以上，且颗粒表面特征、重矿物数量和重矿物标型特征较浓度10％的试剂处理的样品保存得更好。     

Some engineering characteristics of a compacted lateritic residual soil

Summary In many parts of the world, particularly in humid tropical regions, residual soils are abundant. In this paper the suitability of a residual lateritic soil as a construction material is investigated, with respect to its strength and compaction characteristics. In comparison with other typical construction fills available in Southeast Asia, compacted lateritic soils produce excellent shear strengths and CBR values. However, the brittleness and tensile cracking of this compacted material become enhanced on the dry side of the optimum moisture content, or if excessive compaction is imparted. Nevertheless, at a moisture content of 2% wetter than the optimum, the tensile mode of failure is suppressed and the lateritic fills become ideally suited for the construction of high embankments and impervious dam cores.     

黄原酯棉富集分离—全差示光度法测定痕量银

在5—35％HClO_4介质中,0.1g黄原酯棉可定量吸附500μg Ag,灰化解脱后Ag回收率在99％以上。Ag-金试剂-OP络合物的显色条件是:pH为4.5—6.5,最大吸收波长505nm,摩尔吸光系数1.0×10~5,络合物组成是Ag:金试剂=1:4,Ag量在0—10μg/25ml范围内符合比尔定律。采用全差示分光光度法测定地质样品中的Ag,操作简单快速、灵敏度高、选择性好、测定范围宽.     

高岭石的结晶有序度及其对纸张涂布粘浓度的影响

粘浓度是纸张涂布的一项重要指标,测定的变化范围从46.4—72％。用Hinckley方法测定了高岭石的结晶度指数,从0.57变化至1.40。当粘浓度>67％时,结晶度指数>1。粘浓度<67％,结晶度指数<1,有序高岭石有利于粘浓度提高。随着结构无序化,晶粒变小,晶片变薄,比表面增加,晶体边缘和角易破损,使粘浓度降低。结构无序化破坏了颗粒的均匀性,使颗粒长/厚比增加,粘浓度降低。高岭石八面体中Fe~(3+)的存在一定程度上影响了有序度。     

熔融包裹体中水含量的测定方法

本文在对Ｎａｕｍｏｖ（１９７９）计算熔融包裹体中水含量计算模式作原则性修正的基础上建立了新的计算模式，其特点是充分考虑了熔体被捕获后在漫长地质时期内经历的各种变化对其中水含量计算精度的影响。通过加热使熔融包裹体均一，并在均一化过程中的每一个相变发生前后分别测量各相的相对体积百分比，可从本质上消除Ｎａｕｍｏｖ计算模式未曾考虑过的对水含量计算精度发生影响的因素，因此可较为准确地获得熔融包裹体中的水含量。计算实例表明，烙融包裹体中的水含量与其均一温度负相关，随均一温度的降低含水量增高。