湖泊沉积物中磷酸盐氧同位素前处理方法对比

磷酸盐氧同位素(δ~(18)OP)是一种有效的磷源示踪方式.由于湖泊沉积物的组成十分复杂,必须对样品进行除碳处理和纯化处理.本文对目前应用较为广泛的几种前处理方法进行比较,包括NaClO处理和H_2O_2处理等除有机碳方法,以及Blake法和Mc Laughlin法等纯化方法,以期获得适用于湖泊沉积物磷酸盐氧同位素的前处理方法.结果表明:(1)NaClO处理可以保证较高的无机磷提取效率,同时能有效地减少无机磷提取液中有机质含量,且对不同形态磷的破坏较小;H2O2对有机质的去除效果不稳定,且处理后样品磷形态之间发生转化,显著增加了提取的无机磷浓度.(2)Blake法和Mc Laughlin法分别采用磷钼酸铵(APM)+磷酸铵镁(MAP)沉淀和Ce PO4沉淀对样品进行纯化.在纯化处理湖泊沉积物过程中,Blake法优于Mc Laughlin法,主要体现为有机质去除率高,并且磷的回收率较为稳定.(3)经Blake法纯化丹麦Nordborg湖沉积物样品得到的Ag_3PO_4中C、N含量低于Mc Laughlin法且重现性好.本文结合NaClO法与Blake法的优点,建立了一种适合湖泊沉积物的磷酸盐氧同位素前处理方法:首先用2.5%NaClO对沉积物样品进行除碳预处理,然后对磷酸盐提取液依次通过氢氧化镁共沉淀(MAGIC)、APM+MAP沉淀、阳离子交换树脂处理,最后生成Ag3PO4沉淀.     

The role of antecedent groundwater heads in controlling transient aquifer storage and flood peak attenuation in karst watersheds

Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.     

Equilibrium thallium isotope fractionation and its constraint on Earth’s late veneer

Equilibrium isotope fractionation of thallium(Tl) includes the traditional mass-dependent isotope fractionation effect and the nuclear volume effect(NVE). The NVE dominates the overall isotope fractionation, especially at high temperatures. Heavy Tl isotopes tend to be enriched in oxidized Tl^3+-bearing species. Our NVE fractionation results of oxidizing Tl^+ to Tl^3+ can explain the positive enrichments observed in ferromanganese sediments. Experimental results indicate that there could be0.2–0.3 e-unit fractionation between sulfides and silicates at 1650 ℃. It is consistent with our calculation results,which are in the range of 0.17–0.38 e-unit. Importantly,Tl’s concentration in the bulk silicate Earth(BSE) can be used to constrain the amount of materials delivered to Earth during the late veneer accretion stage. Because the Tl concentration in BSE is very low and its Tl isotope composition is similar with that of chondrites, suggesting either no Tl isotope fractionation occurred during numerous evaporation events, or the Tl in current BSE was totally delivered by late veneer. If it is the latter, the Tl-contentbased estimation could challenge the magnitude of late veneer which had been constrained by the amount of highly siderophile elements in BSE. Our results show that the lateaccreted mass is at least five-times larger than the previously suggested magnitude, i.e., 0.5 wt% of current Earth’s mass. The slightly lighter 205 Tl composition of BSE relative to chondrites is probable a sign of occurrence of Tlbearing sulfides, which probably were removed from the mantle in the last accretion stage of the Earth.     

Palaeoclimate indicators (clay minerals,calcareous nannofossils,stable isotopes) compared from two successions in the late Jurassic of the Volga Basin (SE Russia)

A study of clay mineral and calcareous nannofossil abundances in late Jurassic–early Cretaceous sediments from the Volga Basin, SE Russia, is presented. From these results, we are able to compare some general patterns of mineralogical and palaeontological change for the Volga Basin to the palaeoclimate models developed for northern Europe and beyond. The two successions examined comprise calcareous mudstones with black organic‐rich shale horizons, overlain by a series of phosphatic silty sands. Clay mineralogical results show a progressive decrease in kaolinite and the concomitant increase of smectite and illite through the middle Volgian, followed by an abrupt increase in kaolinite in the late Volgian. The clay mineral evidence suggests increasing aridity at the end of the Jurassic, similar, in part, to many western European successions. Because of differential settling of clay minerals, superimposed upon this possible climatic signature is likely to be the effect of relative sea‐level change. Calcareous nannofossil analysis from a single section reveals a shift through the middle Volgian from low nutrient, warm water assemblages dominated by Watznaueria to cooler surface water and high nutrient assemblages dominated by Biscutum constans. These observations suggest that increased aridity is also associated with climatic cooling. Black shales are associated with increased productivity, higher sea levels and increases in smectite content. Hence, periods of low (chemical) hinterland weathering during semi‐arid conditions are paradoxically associated with relatively nutrient‐rich waters, and organic‐rich shales. Comparison of published carbon and oxygen stable isotope results from this and other sections to the clay mineral and nannofossil data confirms the palaeoclimatic interpretation. This study significantly improves the published biostratigraphically constrained clay mineral database for this time period, because other European and North American successions are either non‐marine (and thus poorly dated), absent (through penecontemporaneous erosion) or condensed. Copyright © 2002 John Wiley & Sons, Ltd.     

鳙、鲢鱼鳞作为稳定同位素研究非致命采样替代物的有效性

稳定同位素分析技术已成为食物网研究中的关键技术,通用方法是取鱼类背部白色肌肉,在实际应用过程会导致鱼类的死亡,因而有所局限.使用非致命组织作为稳定同位素研究中的替代组织越来越得到关注,但是目前国内尚未开展相关研究.比较鳙(Aristichthy nobilis)、鲢(Hypophthalmichthys molitrix)鱼鳞与肌肉组织中δ13C和δ15N比值,发现鳙、鲢的鱼鳞与肌肉组织中δ13C和δ15N比值均有显著差异.鱼鳞δ13C比值比肌肉更富集,平均高2.54‰,而δ15N比值比肌肉平均低0.7‰.对鳙、鲢的鱼鳞与肌肉组织δ15N比值含量进行相关分析发现,通过构建线性模型,可用校正后的鱼鳞δ15N比值替代肌肉组织δ15N比值.鲢的鱼鳞与肌肉组织δ13C比值存在显著线性相关,而鳙的鱼鳞与肌肉组织δ13C比值无显著相关关系.     

台风过境期间辽河口滨海湿地水动力特征的数值模拟研究

本研究基于FVCOM环流模型,耦合ECMWF背景风场和Jelesnianski台风经验模型形成合成风场,对9711台风“温妮”过境辽河口区域的水动力进行模拟研究。模型通过在动量方程、湍流方程中加入附加源项来表达盐沼植被对水动力的阻碍作用。使用研究区域实测的潮位、流速、流向等数据对水动力模型进行验证,模拟结果与实测数据吻合较好。结果表明：潮滩盐沼植被对台风过境期间的潮位变化无明显影响,但对流速具有显著的衰减作用,且芦苇对潮流的衰减作用大于盐地碱蓬植被,芦苇区的速度最大衰减率达81.43%。此外,台风路径变化对辽河口湿地海域的增减水及流速影响较大,台风强度越强,局部区域造成的风暴潮增水和流速也相应越大。     

黄河和长江碎屑物质扩散研究——来自江苏沙脊物源示踪的约束

研究源-汇系统对于理解岩石风化、河流输砂、泥砂沉积以及陆地和海洋沉积过程具有重要意义。我国江苏省东海岸具有丰富的沉积物供应,在某些沿海地段形成了一系列沙脊,是进行沉积物源-汇过程研究的理想沉积记录之一。但目前对其物源区来自哪里还未达成共识。我们利用已发表的碎屑锆石U-Pb年龄和钾长石Pb同位素数据,结合江苏沙脊及其周缘区域的数据结果,详细厘定江苏沙脊的物源区,并运用蒙特卡罗反演模型定量评估江苏沙脊潜在物源区对其物质贡献率。结果表明江苏沙脊北部的碎屑物质主要受大别山(45%)和鲁中山区(24%)的共同影响;黄河(29%)、古黄河(27%)和长江(25%)的碎屑物质对江苏沙脊中部的物质组成起重要影响。江苏沙脊南部的物源主要来自长江(68%)。江苏沙脊的出现得益于黄河和长江这样的大陆尺度的大河搬运了丰富的碎屑物质到下游,南黄海西海岸的平坦地貌有利于保存这些碎屑物质,末次冰期后东亚陆架海动力过程(潮汐、海浪和沿岸流等)持续对其改造,这体现了河流-海洋在塑造河口-海岸地貌中的交互作用。     

Spatially distributed hydrotope‐based modelling of evapotranspiration and runoff in mountainous basins

River basins in mountainous regions are characterized by strong variations in topography, vegetation, soils, climatic conditions and snow cover conditions, and all are strongly related to altitude. The high spatial variation needs to be considered when modelling hydrological processes in such catchments. A complex hydrological model, with a great potential to account for spatial variability, was developed and applied for the hourly simulation of evapotranspiration, soil moisture, water balance and the runoff components for the period 1993 and 1994 in 12 subcatchments of the alpine/pre‐alpine basin of the River Thur (area 1703 km²). The basin is located in the north‐east of the Swiss part of the Rhine Basin and has an elevation range from 350 to 2500 m a.s.l. A considerable part of the Thur Basin is high mountain area, some of it above the tree‐line and a great part of the basin is snow covered during the winter season. In the distributed hydrological model, the 12 sub‐basins of the Thur catchment were spatially subdivided into sub‐areas (hydrologically similar response units—HRUs or hydrotopes) using a GIS. Within the HRUs a hydrologically similar behaviour was assumed. Spatial interpolations of the meteorological input variables wereemployed for each altitudinal zone. The structure of the model components for snow accumulation and melt, interception, soil water storage and uptake by evapotranspiration, runoff generation and flow routing are briefly outlined. The results of the simulated potential evapotranspiration reflect the dominant role of altitudinal change in radiation and albedo of exposure, followed by the influence of slope. The actual evapotranspiration shows, in comparison with the potential evapotranspiration, a greater variability in the lower and medium altitudinal zones and a smaller variability in the upper elevation zones, which was associated with limitations of available moisture in soil and surface depression storages as well as with the evaporative demand of the local vegetation. The higher altitudinal dependency and variability of runoff results from the strong increase in precipitation and the decrease in evaporation with increased altitude. An increasing influence of snow cover on runoff as well as evapotranspiration with altitude is obvious. The computed actual evapotranspiration and runoff were evaluated against the observed values of a weighting lysimeter and against runoff hydrographs. Copyright © 1999 John Wiley & Sons, Ltd.     

基于稳定性同位素的普里兹湾南极大磷虾不同发育阶段食性转变分析

As one of the most common and dominant species in the Southern Ocean, Antarctic krill(Euphausia superba)play a significant role in food web structure and the process of energy flow. The diet of Antarctic krill in the Prydz Bay during austral summer of 2012/2013 was investigated and the ontogenetic shift in krill diet was evaluated using the stable isotope method. The nitrogen stable isotope values(δ~(15) N) of adults((2.78±0.58)‰) were much higher than those of juveniles((1.69±0.70)‰), whereas the carbon stable isotope values(δ~(13) C) of adults(–(28.26±1.08)‰) were slightly lower than those of juveniles(–(27.48±1.35)‰). Particulate organic matter(POM)from 0, 25, and 50 m depth combined(0/25/50 m) represented phytoplankton food items. The results showed that phytoplankton food items in surface water and mesozooplankton were two essential food items for Antarctic krill in the Prydz Bay during summer. POM(0/25/50 m) contributes 56%–69% and 26%–34% to the diet of juvenile and adult krill, respectively, whereas mesozooplankton composes 13%–34% and 58%–71% of the diet of juvenile and adult krill, respectively. Thus, an ontogenetic diet shift from POM(0/25/50 m), which consists mainly of phytoplankton, to a higher trophic level diet containing mesozooplankton, was detected. The capacity for adults to consume more zooplankton food items may minimize their food competition with juveniles, which rely mostly on phytoplankton food items. This suggests "diet shift with ontogeny" which may somehow help krill keep their dietary energy budget balanced and well adapted to the Antarctic marine ecosystem as a dominant species.     

夏季大亚湾悬浮颗粒有机物碳、氮同位素组成及其物源指示

2015年夏季开展了大亚湾悬浮颗粒有机物碳（POC）、氮含量（PN）及其同位素组成的研究,结果表明,δ13C_POC和δ15N_PN的变化范围分别为-25.7‰~-17.4‰和-6.3‰~10.4‰,平均值分别为-20.2‰和8.2‰。大亚湾悬浮颗粒有机物含量及其碳氮同位素组成的空间变化反映了不同有机质来源的影响:喜洲岛附近海域表现出高POC、PN、δ13C_POC和δ15N_PN的特征,指征着浮游植物水华的主导贡献;东北部范和港附近海域具有高POC、PN、低δ13C_POC和高δ15N_PN的特征,反映了河流/河口水生有机物的影响;湾顶白寿湾附近海域的δ13C_POC和δ15N_PN出现低值,体现了陆源有机质和人类污水排放的影响。借助δ13C_POC和δ15N_PN的三端元混合模型,定量出海洋自生有机质、陆源有机质、河流/河口水生有机质等3个来源的贡献平均分别为70%、13%和17%,其中海洋自生有机质是夏季大亚湾悬浮颗粒有机物的最主要来源。从这3种来源颗粒有机物含量的空间变化看,海洋自生有机质含量由湾内向湾外减少,与初级生产力的空间变化相对应;河流/河口水生有机质含量在大亚湾东北部出现高值;陆源有机质含量在表、底层出现不同态势,表层陆源有机物含量在湾中部海域最低,而底层则呈现出自湾内向湾口增加的趋势,主要受控于离岸距离和珠江冲淡水、粤东沿岸上升流输送的影响。