基于SPE与SPATT的水体中麻痹性贝类毒素检测方法构建与应用

为实现麻痹性贝类毒素(paralytic shellfish poisoning,PSP)的实时监控与提前预警,本研究构建了基于固相萃取技术(solid phase extraction,SPE)与固相吸附毒素跟踪技术(solid phase adsorption toxin tracking,SPATT)的水体中PSP检测方法,重点优化了吸附材料及前处理方法,评价了回收率、检出限等指标,并将方法应用于2019年春季秦皇岛山海关海域PSP消长过程的监测中,比较评估了两种方法的监控预警效果。结果表明:SPE方法选用ENVI-Carb 500mg/6mL固相萃取柱,过样体积为50mL,13种PSP组分的平均回收率为82.2%±10.0%、检出限为4.0-20.0ng/L;SPATT方法选用SP207大孔吸附树脂,洗脱时间为静置Id最佳,整体回收率约为9.2%;在实际应用中,结合产毒藻密度及贻贝富集毒素含量的变化,发现SPE方法的检测结果可实时表征海域PSP风险状况,对于贻贝中PSP的预警效果也显著优于SAPTT方法,后者不仅因监控方式相对滞后一个监测周期,且灵敏度及准确性均较差。对于秦皇岛...     

The general solution of the HENON–HEILES problem

The general solution of the Henon–Heiles system is approximated inside a domain of the (x, C) of initial conditions (C is the energy constant). The method applied is that described by Poincaré as ‘the only “crack” permitting penetration into the non-integrable problems’ and involves calculation of a dense set of families of periodic solutions that covers the solution space of the problem. In the case of the Henon–Heiles potential we calculated the families of periodic solutions that re-enter after 1–108 oscillations. The density of the set of such families is defined by a pre-assigned parameter ε (Poincaré parameter), which ascertains that at least one periodic solution is computed and available within a distance ε from any point of the domain (x, C) for which the approximate general solution computed. The approximate general solution presented here corresponds to ε = 0.07. The same solution is further improved by “zooming” into four square sub-domain of (x, C), i.e. by computing sufficient number of families that reduce the density parameter to ε = 0.003. Further zooming to reduce the density parameter, say to ε = 10⁻⁶, or even smaller, although easily performable in both areas occupied by stable as well as unstable solutions, was found unnecessary. The stability of all members of each and all families computed was calculated and presented in this paper for both the large solution domain and for the sub-domains. The correspondence between areas of the approximate general solution occupied by stable periodic solutions and Poincaré sections with well-aligned section points and also correspondence between areas occupied by unstable solutions and Poincaré sections with randomly scattered section points is shown by calculating such sections. All calculations were performed using the Runge-Kutta (R-K) 8th order direct integration method and the large output received, consisting of many thousands of families is saved as “Atlas of the General Solution of the Henon–Heiles Problem,” including their stability and is available at request. It is concluded that approximation of the general solution of this system is straightforward and that the chaotic character of its Poincaré sections imposes no limitations or difficulties.     

Cosmological Scalar in the Jordan-Brans-Dicke Theory. I

A variant of the Jordan-Brans-Dicke (JBD) theory is examined which contains a cosmological scalar that is written so that on going to the Einstein representation it becomes the ordinary cosmological constant of general relativity theory. This paper is divided into two parts. In Part I we examine the cosmological solutions for the Einstein representation of the JBD theory, i.e., in the presence of a minimally coupled scalar field. In Part II we shall study the cosmological solutions in the proper representation of the JBD theory with a self consistent scalar field. The analysis of these solutions is of interest in connection with modern concepts of the evolution of the universe, in particular, with the observed acceleration of cosmological expansion and estimates of the density of dark matter and dark energy.__________Translated from Astrofizika, Vol. 48, No. 3, pp. 455–462 (August 2005).     

Focal Mechanism Solutions of the 2008 Wenchuan earthquake sequence from P-wave polarities and SH/P amplitude ratios: new results and implications

The 2008 Wenchuan earthquake, a major intraplate earthquake with M _w 7.9, occurred on the slowly deforming Longmenshan fault. To better understand the causes of this devastating earthquake, we need knowledge of the regional stress field and the underlying geodynamic processes. Here, we determine focal mechanism solutions (FMSs) of the 2008 Wenchuan earthquake sequence (WES) using both P-wave first-motion polarity data and SH/P amplitude ratio (AR) data. As P-wave polarities are more reliable information, they are given priority over SH/P AR, the latter of which are used only when the former has loose constraint on the FMSs. We collect data from three categories: (1) permanent stations deployed by the China Earthquake Administration (CEA); (2) the Western Sichuan Passive Seismic Array (WSPSA) deployed by Institute of Geology, CEA; (3) global stations from Incorporated Research Institutions for Seismology. Finally, 129 events with magnitude over M _s 4.0 in the 2008 WES are identified to have well-constrained FMSs. Among them, 83 are well constrained by P-wave polarities only as shown by Cai et al. (Earthq Sci 24(1):115–125, 2011), and the rest of which are newly constrained by incorporating SH/P AR. Based on the spatial distribution and FMSs of the WES, we draw following conclusions: (1) the principle compressional directions of most FMSs of the WES are subhorizontal, generally in agreement with the conclusion given by Cai et al. (2011) but with a few modifications that the compressional directions are WNW–ESE around Wenchuan and ENE–WSW around Qingchuan, respectively. The subhorizontal compressional direction along the Longmenshan fault from SW to NE seems to have a left-lateral rotation, which agrees well with regional stress field inverted by former researchers (e.g., Xu et al., Acta Seismol Sin 30(5), 1987; Acta Geophys Sin 32(6), 1989; Cui et al., Seismol Geol 27(2):234–242, 2005); (2) the FMSs of the events not only reflected the regional stress state of the Longmenshan region, but also were obviously controlled by the faults to some extent, which was pointed out by Cai et al. (2011) and Yi et al. (Chin J Geophys 55(4):1213–1227, 2012); (3) while the 2008 Wenchuan earthquake and some of its strong aftershocks released most of the elastic energy accumulated on the Longmenshan fault, some other aftershocks seem to occur just for releasing the elastic energy promptly created by the 2008 Wenchuan earthquake and some of its strong aftershocks. (4) Our results further suggest that the Longmenshan fault from Wenchuan to Beichuan was nearly fully destroyed by the 2008 Wenchuan earthquake and accordingly propose that there is less probability for great earthquakes in the middle part of the Longmenshan fault in the near future, although there might be a barrier to the southwest of Wenchuan and it is needed to pay some attention on it in the near future.     

低固相冲洗液在赣南再里地区的应用研究

钻进过程中,孔壁的稳定性和冲洗液的渗漏是影响钻进效率和钻孔质量的重要因素。孔内情况越复杂,施工周期越长,对冲洗液性能的要求也越高。赣南再里地区施工区构造发育复杂,地层中存在大量的松散、胶结性差的砂岩以及高岭土、绿泥石等水敏性地层,钻探施工钻孔容易缩径,孔壁稳定性差,极易出现剥落、掉块、坍塌等现象,试验采用了低固相不分散冲洗液,取得了良好的钻进效果。     

法国Echassieres地区石英网脉中黑钨矿及其共生矿物的固溶体研究

Echassiares石英网脉中的黑钨矿主要系钨锰矿一钨铁矿系列中的铁端员矿物一钨铁 矿，富泥但贫担，当其与妮铁矿共生时，钨铁矿可含8.91% Nb205。在该矿物中常见的元素置换 有:(1)Fe2+→Mn2+;(2)Wg6+Fe2+→Nb5+ +Fe+3 (3) 3W6+ +Fe2+ →4Nb5+。 妮铁矿呈它形，富含Ta. W,Ti。钨铁捉矿以枝状形态位于钨铁矿和妮铁矿之间，形成完整的矿物组合。Beauvoir花岗岩的侵位带入的热液交代钨铁矿是形成这种矿物组合的主要原因。同时,铅钨铁矿中的裂隙带或其边部还局部发生钨锰矿化。     

变荷载下双层地基一维非线性固结近似解析解

目前考虑土体非线性压缩及渗透特性的双层地基非线性固结解均假定土体固结系数保持不变,能反映固结系数变化的双层地基非线性固结解还很鲜见。引入经典的e- 和e- 非线性关系描述土体的非线性压缩、渗透特性,在假定双层地基上、下土层压缩指数与渗透指数比值 相等且不等于1的基础上,得到变荷载下考虑土体固结系数变化的双层地基一维非线性固结近似解。该解答在 1条件下可退化为已有的 1时双层地基一维非线性固结解。基于此解探讨了双层地基上、下土层参数的相对比值对非线性固结性状的影响。结果表明：单面排水条件下 越小,下层土与上层土的相对压缩性越低、相对渗透性越高,则双层地基非线性固结速率越快;减小 值,增加双层地基中压缩性小、渗透性高的土层的厚度,会加快地基的固结速率。     

高频表面波对定常Ekman流解的影响

基于Jenkins(1989)建立的包含Stokes漂流、风输入和波耗散影响的修正Ekman模型,采用Paskyabi等(2012)使用的推广的Donelan等(1987)中的谱和波耗散函数,并利用Paskyabi等(2012)中修正方法给出的包含高频波的风输入函数,在粘性不依赖于水深及粘性随深度线性变化的条件下,研究了包含高频毛细重力波的随机表面波对Stokes漂流和Song(2009)导出的波浪修正定常Ekman流解的影响。结果表明高频表面波使Stokes漂流在海表面剪切加强,对定常Ekamn流解的影响通常不能忽略,但对Ekman流场的角度偏转影响很小。最后,将考虑高频表面波尾谱影响所估算的定常Ekman流解与已有观测结果以及经典Ekman解进行了比对分析。     

中国若干固体矿床He、Ar同位素研究

本文以成矿阶段放物中的汉体包裹体为测定对象，研究了哀牢山金矿带内3个金矿床、马厂箐斑岩铜矿床、金顶铅-锌矿床和白云鄂博稀土-铌-铁矿床的He、Ar同位素组成。结果表明，He、Ar同位素对揭示成矿古流体的成因，具有灵敏感的示踪作用。     

滇池农村固体废物和化肥流失治理试验研究

怎样合理处置农村固体废物和减少农田化肥流失一直是农村面源污染控制的难题之一。该研究将农村固体废物的处理与减少化肥施用措施有机结合，利用微生物复合发酵剂和农村固体废物生产活性肥料，开展了一系列农业种植试验和数据监测，在此基础上，提出了一套实用性强、效果好的控制农业固体废物和化肥流失污染的对策措施。