沸石在水环境治理中的应用现状与前景

文章叙述了沸石的基本结构以及吸附、离子交换特性，总结了近年来国内外有关沸石在水环境保护方面的研究与应用成果，提出了沸石在今后的水环境保护和改善方面将具有广泛的应用前景。     

冬小麦遥感冠层温度监测土壤含水量的试验研究

在冬小麦主要生育期(2002年4月初到5月底),对不灌溉的冬小麦测定了冠层温度、地温、气温以及土壤含水量,计算了冠气温差且分析了冠层温度和冠气温差与不同土层厚度的土壤含水量相关关系。结果表明:14:00的冠层温度能较好地反映20cm土层的土壤含水量变化,但与其它各土层相关性有较大的波动性;14:00的冠气温差能较好地反映40cm以上土层的土壤含水量变化,二者的相关性很高,在20cm、40cm土层,两者相关系数R2分别为0.98866、0.99389,这为用区域遥感数据反演主要生育期冬小麦的冠气温差进而监测区域40cm土壤含水量提供了实验性的依据;拔节期和灌浆期,用14:00冠气温差来拟合各土壤层的土壤含水量有较高的精度,从而为用区域遥感数据监测区域土壤含水量提供了经验性的模型。     

青藏高原的水塔功能

青藏高原是维持我国乃至东亚地区生态系统的重要水塔。高原平均海拔在4000m以上,与周边地区形成了巨大的地势差。高原东南部不仅具有丰富的降水,而且在3500m以上以冰川雪被形态储存了巨大的水资源,因此,高原具有重要的水塔功能。基于高原潜在输出总水量和不同海拔区域水体所具有的势能两个方面,建立了高原水塔功能的模型,从而利用GIS方法,通过对我国1∶400万系列图和相关资料的统计分析,计算出高原不同高度带贮存的大气降水、冰川储水量、湖泊水量以及工农业用水量。计算结果表明,青藏高原冰川湖泊的淡水储量达39921×108m3,其中冰川储水量为39228×108m3,可利用湖泊储水量为693×108m3,平均每年由降水获得的水资源量为8495×108m3,高原工农业用水量为129×108m3。因此,高原的输出水量即出境河川径流量为6870×108m3。高原储水主要分布在海拔3000～5000m间,与高原周围相比,平均势差在2000～4000m间,最大的势差达5500m。水体具有巨大的势能,在势能的作用下,自然向周边区域输送汇集,维持着周边地区的生态过程和社会经济活动,因此,青藏高原的水塔功能对于周边地区的生态系统和社会经济系统是极其重要的。     

RIVER SYSTEM AND DISTURBANCE FACTORS IN THE LAKE TOBA

Situated at an elevation of 905 m above sea level in the Province of North Sumatra, Lake Toba and its surrounding landscapes are regarded as a natural heritage in a certain extent, as a quoted national treasure. Unfortunately degradation of the land and water resources in the watershed along Lake Toba is taking place at an alarming and totally unacceptable rate. The quality of the lake is partly depended on input the quality of the rivers. When compared to the control area the water quality that influenced by the piggeries are highly polluted. It can be concluded that the Salbe River at the downstream of the piggeries has been polluted and apparently it is a serious problem to the catchment area management. It should be noted that the polluted river would influence the water quality of the Lake Toba. Based on calculation, the permissible BOD5 according to B- river standard is 238 mg/L, it means the river still in B standard but the condition and quality are decreasing continuously. Following the Indonesian health standard the permissible BOD is - 461 mg/L. It means BOD in the river should be reduced 461 mg/L or clean program is needed.     

Water Quality Impacts of Climate and Land Use Changes in Southeastern Pennsylvania*

This study investigates potential changes in nitrogen and phosphorus loads under a warmer and wetter climate, urban growth, and combined changes in the Conestoga River Basin and its five subbasins in southeastern Pennsylvania. A GIS‐based hydrochemical model was employed for assessing the sensitivity of the basins to the projected changes in 2030. Under the HadCM2 climate change scenario, mean annual nitrogen and phosphorus loads are expected to increase, with great increases in spring but slight decreases in fall primarily because of changes in monthly precipitation. When climate change and urbanization occur concurrently, mean annual nitrogen loads further increase by 50% in the most urbanizing subbasin. Point source nitrogen control could mitigate negative effects of climate and land use changes, reducing mean annual nitrogen loads to the contemporary baseline level.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

极端洪水导致的湖泊水位抬升和氮磷输入增加对苦草(Vallisneria natans)的复合影响

据全球气候变化模型预测,未来极端洪水事件将呈现增多和加剧态势。极端洪水对沉水植物功能性状、生长发育状况及整个生态系统均有深远的影响,研究极端洪水对沉水植物生长发育的影响对理解和预测气候变化过程中水生态系统的变化具有重要意义。本文针对极端洪水事件引起的水位急剧上升和营养负荷量增加双重效应,在实验周期90 d内设置对照(水位保持75 cm)、2种极端洪水条件(水位在第1天从75 cm快速上升至150 cm + NP输入、水位从75 cm逐步上升至150 cm + NP输入)以及水位保持75 cm + NP输入4项处理(后3项处理中营养输入总量相同),研究了极端洪水对沉水植物苦草(Vallisneria natans)生长、繁殖对策及生物量分配的影响,实验过程中还同步监测了浮游植物、附着藻类和水体营养状况(TN和TP)。在苦草的17个测定指标中,只有根生物量分配和有性繁殖分配在4个处理下无明显变化。从水位的单独作用看,相对于营养增加且水位恒定的处理,两种洪水条件(水位急剧上升和逐步上升)均降低了苦草的分株数、叶片数、间隔子数、间隔子总长、最大根长、花果数以及各器官生物量和总生物量,促进了人工基质表面附着藻类的生长。水位急剧上升时,植株对间隔子的生物量投资倾向于最小,而株高和植株对叶的生物量投资倾向于最大。从营养负荷的单独作用来看,相对于对照组,营养增加且水位恒定的处理中水体N浓度显著增加,促进浮游植物和苦草表面附着藻类的生长,但是从二者的Chl.a浓度来看,浮游植物遮光作用相对较大,抑制了苦草叶、根和间隔子的生长,但有性繁殖生物量无明显变化。从水位和营养负荷联合作用的模式来看,水位上升和营养负荷两个环境因素的联合作用会使入湖营养负荷加强水位上升对沉水植物生长的影响效应,二者的联合作用使叶、根、间隔子和有性繁殖生物量均大大降低。因此,极端洪水对沉水植物的不利影响较大,一方面水位抬升会直接影响沉水植物,另一方面会通过浮游植物间接影响沉水植物生长发育。     

Softs of Fildes Peninsula, King George Island, the maritime Antarctic: Part I. Formation processes and pedogenetic particularities

Based on the data obtained from tens of the investigated soil profiles scattered over the Fildes Peninsula, King George Island, the maritime Antarctic, the soil-forming processes were discussed. It was concluded that on the weathering crusts resulted from various physical courses, the strong freeze-thaw action within regolith, significant organic matter accumulation, evident leaching and illuviation, as well as initial argillification dominated the formation and development of the soils on the Fildes Peninsula. Furthermore, this study indicated that the juvenility of genesis, poor profile-expression, variation in column thickness, etc. characterized the pedogenetic features of the soils of the Fildes Peninsula.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

煤矸石释放重金属环境效应研究--淮南煤矿塌陷区水体试验场实例调查

概要分析了淮南新孜5号井煤矸石所含的重金属元素对塌陷区鱼塘水质的影响,指出除个别水样中Zn、Cu超标外,其他均不超标,该鱼塘水质适宜养鱼要求。矸石样与华北及整个地壳泥岩中元素的丰度比,矸石中Cr、Pb、Zn与泥岩丰度基本持平,而Cd、Cu均超过其他泥岩中丰度值。因此,煤矸石在地面遭受风化,其所含有害物质可能会释放到环境,在煤矸石堆放处适当进行监测还是必要的。