吉林海沟金矿矿山地质环境及其恢复治理方法

在对海沟金矿矿山地质环境调查基础上，针对矿区存在着的问题，提出了治理与防范措施，对同类矿山有借鉴作用。     

Hydrologic and water isotope characterization of a regulated Canadian Shield river basin

Stable water isotope surveys have increasingly been integrated into river basins studies, but fewer have used them to evaluate impact of hydropower regulation. This study applies hydrologic and water isotope survey approaches to a Canadian Shield river basin with both regulated and natural flows. Historical streamflow records were used to evaluate the influence of three hydroelectric reservoirs and unregulated portions of the basin on downstream flows and changes in water level management implemented after an extreme flood year (1979). In 2013, water isotope surveys of surface and source waters (e.g., rainfall, groundwater, snowmelt) were conducted to examine spatial and temporal variation in contributions to river flow. Seasonal changes in relative groundwater contribution were assessed using a water‐isotope mass balance approach. Within the basin, two regulated reservoirs exhibited inverted hydrographs with augmented winter flows, whereas a third exhibited a hydrograph dominated by spring snowmelt. In 2013, spatial variation in rain‐on‐snow and air temperatures resulted in a critical lag in snowmelt initiation in the southern and northern portions of the basin resulting in a dispersed, double peak spring hydrograph, contrasting with 1979 when a combination of rain‐on‐snow and coincident snowmelt led to the highest flood on record. Although eastern basin reservoirs become seasonally enriched in δ¹⁸O and δ²H values, unregulated western basin flows remain less variable due to groundwater driven baseflow with increasing influence downstream. Combined analysis of historical streamflow (e.g., flood of 1979, drought of 2010) and the 2013 water isotope surveys illustrate extreme meteorological conditions that current management activities are unable to prevent. In this study, the influence of evaporative fractionation on large surface water reservoirs provides important evidence of streamflow partitioning, illustrating the value of stable water isotope tracers for study of larger catchments.     

Geochemical and isotopic characterization of trace fossil infillings: New insights on tracemaker activity after the K/Pg impact event

Geochemical and isotopic analyses of the Cretaceous–Paleogene (K/Pg) boundary deposits were conducted at the Caravaca section (External Subbetic, southeast of Spain) in order to evaluate the recovery of the macrobenthic tracemaker community and the bioturbational disturbance. Samples from the infilling material of several lower Danian dark-colored trace fossils (Chondrites, Planolites, Thalassinoides and Zoophycos) located in the uppermost 8-cm of the light upper Maastrichtian strata, as well as samples from the host sedimentary rock of these trace fossils, were analyzed and compared with data from the lower Danian deposits. The values of element ratios indicative of extraterrestrial contamination (Cr/Al, Co/Al and Ni/Al) are higher in the infilling trace fossil material than in the upper Maastrichtian and lower Danian deposits, which suggests a contribution of the ejecta layer. Regarding the isotope composition, the δ¹³C values are lower in the infilling material than in the Maastrichtian host sedimentary rocks surrounding the traces, while the δ¹⁸O are higher in the infilling material. The geochemical and isotopic compositions of the infilling material evidence the unconsolidated character of the sediment, including the red boundary layer. Softground conditions confirm a relatively rapid recovery by the macrobenthic tracemaker community, starting a few millimeters above the K/Pg boundary layer. The mixture of the infilling material of the trace fossils moreover reveals a significant macrobenthic tracemaker activity affecting K–Pg boundary transition sediments that may have significantly altered original signatures.     

DEM simulations of methane hydrate exploitation by thermal recovery and depressurization methods

Methane hydrate (MH, also called fiery ice) exists in forms of pore filling, cementing and load-bearing skeleton in the methane hydrate bearing sediment (MHBS) and affects its mechanical behavior greatly. To study the changes of macro-scale and micro-scale mechanical behaviors of MHBS during exploitation by thermal recovery and depressurization methods, a novel 2D thermo-hydro-mechanical bonded contact model was proposed and implemented into a platform of distinct element method (DEM), PFC2D. MHBS samples were first biaxially compressed to different deviator stress levels to model different in-situ stress conditions. With the deviator stress maintained at constant, the temperature was then raised to simulate the thermal recovery process or the pore water pressure (i.e. confining pressure for MH bond) was decreased to simulate the depressurization process. DEM simulation results showed that: during exploitation, the axial strain increased with the increase of temperature (in the thermal recovery method) or decrease of pore water pressure (in the depressurization method); sample collapsed during MH dissociation if the deviator stress applied was larger than the compression strength of a pure host sand sample; sample experienced volume contraction but its void ratio was slightly larger than the pure host sand sample at the same axial strain throughout the test. By comparison with the laboratory test results, the new model was validated to be capable of reproducing the exploitation process by thermal recovery and depressurization methods. In addition, some micro-scale parameters, such as contact distribution, bond distribution, and averaged pure rotation rate, were also analyzed to investigate their relationships with the macroscopic responses.     

Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.     

反渗透海水淡化技术现状和展望

反渗透膜技术于20世纪60年代取得突破性进展,促使反渗透海水淡化在近50年间高速发展,淡化产能自20世纪90年代起激增.海水反渗透(SWRO)淡化已成为目前投资最省、成本最低的利用海水制备饮用水的过程.文中主要对海水反渗透淡化的发展状况进行了介绍,如膜和组件的改进,关键设备高压泵和能量回收装置效率的提高,多种工艺过程的不断发展,包括预处理和后处理的新工艺,以及对环境的影响和相应对策等.反渗透技术的发展也推动了其他膜分离技术的进步,并扩展其应用领域.预计在不久的将来,膜技术在海水淡化和水再利用、扩大和保护水资源、循环经济、清洁生产、改造传统产业、节能减排及提高人民生活水平等方面发挥的作用会越来越显著.     

Possibilities of land use change analysis in a mountainous rural area: a methodological approach

Decreasing population density is a current trend in the European Union, and causes a lower environmental impact on the landscape. However, besides the desirable effect on the regeneration processes of semi-natural forest ecosystems, the lack of traditional management techniques can also lead to detrimental ecological processes. In this study we investigated the land use pattern changes in a micro-region (in North-Eastern Hungary) between 1952 and 2005, based on vectorised land use data from archive aerial photos. We also evaluated the methodology of comparisons using GIS methods, fuzzy sets and landscape metrics. We found that both GIS methods and statistical analysis of landscape metrics resulted in more or less the same findings. Differences were not as relevant as was expected considering the general tendencies of the past 60 years in Hungary. The change in the annual rate of forest recovery was 0.12%; settlements extended their area by an annual rate of 3.04%, while grasslands and arable lands had a net loss in their area within the studied period (0.60% and 0.89%, respectively). The kappa index showed a smaller similarity (~60%) between these dates but the fuzzy kappa and the aggregation index, taking into account both spatial and thematic errors, gave a more reliable result (~70–80% similarity). Landscape metrics on patch and class level ensured the possibility of a detailed analysis. We arrived at a similar outcome but were able to verify all the calculations through statistical tests. With this approach we were able to reveal significant (p < 0.05) changes; however, effect sizes did not show large magnitudes. Comparing the methods of revealing landscape change, the approach of landscape metrics was the most effective approach, as it was independent of spatial errors and ensuring a multiple way of interpretation.     

苏里格大型致密砂岩气田储层结构与水平井提高采收率对策

在分析苏里格气田辫状河体系及储层结构特征的基础上,提出了剖面储量集中度的概念,建立了厚层块状型、垂向叠置泛连通型、分散局部连通型、分散孤立型4种砂体分布模式,探讨了不同储层结构下的水平井采出程度,提出了水平井提高采收率技术对策。研究结果表明,辫状河沉积体系复合有效砂体由于“阻流带”的存在,直井动用不完善,水平井能克服“阻流带”的影响,提高层内储量动用程度;但由于砂体多层状分散分布,水平井开发会导致纵向含气层系储量动用不充分,影响层间采出程度。对于剖面储量集中度高的厚层块状型、垂向叠置泛连通型储层,采用水平井整体开发,Ⅰ+Ⅱ类井比例达70%以上,可显著提高储量动用程度和采收率。对于剖面储量集中度低的分散局部连通型储层,采用直井井网开发后进行甜点式优选水平井井位加密部署,可提高采收率10%以上。     

融雪洪水跳跃变异对其参数估计不确定性影响分析

利用Pettitt非参数检验法和Mann-Kendall非参数趋势检验法,分析年最大洪峰流量序列的非一致性,确定序列的变异形式,采用“分解-合成”理论对其进行一致性修正,得到过去、现状两种条件下年最大洪峰流量序列,根据贝叶斯理论对序列一致性修正前后参数不确定性进行估计,并对其预报区间优良性进行评价。研究结果表明：年最大洪峰流量序列变异点发生在1993年,序列整体上升趋势不显著,在1957-1993年子序列呈显著下降趋势,而1994-2006年子序列变化趋势不显著,跳跃变异为序列主要变异形式;给出了实测、还原及还现序列参数后验分布估计值及95%置信区间,将其结合优化适线法进行P-Ⅲ型频率分析,得到修正前后设计频率年最大洪峰流量预报区间估计值;还原、还现序列与实测序列相比,预报区间覆盖率均提高24%,平均带宽分别减少39.59%、23.17%,平均偏移幅度分别减少28.45%、11.39%。通过对非一致性年最大洪峰流量序列还原/还现计算,可减小参数估计不确定性对其计算产生的影响,从而提高预报区间的可靠性。     

MELTWATER FLUXES AT AN ARCTIC FOREST-TUNDRA SITE

Models of surface energy balance and snow metamorphism are utilized to predict the energy and meltwater fluxes at an Arctic site in the forest–tundra transition zone of north-western Canada. The surface energy balance during the melt period is modelled using an hourly bulk aerodynamic approach. Once a snowcover becomes patchy, advection from the bare patches to the snow-covered areas results in a large spatial variation in basin snowmelt. In order to illustrate the importance of small-scale, horizontal advection, a simple parameterization scheme using sensible heat fluxes from snow free areas was tested. This scheme estimates the maximum horizontal advection of sensible heat from the bare patches to the snow-covered areas. Calculated melt was routed through the measured snowcover in each landscape type using a variable flow path, meltwater percolation model. This allowed the determination of the spatial variability in the timing and magnitude of meltwater release for runoff. Model results indicate that the initial release of meltwater first occurred on the shallow upland tundra sites, but meltwater release did not occur until nearly two weeks later on the deep drift snowcovers. During these early periods of melt, not all meltwater is available for runoff. Instead, there is a period when some snowpacks are only partially contributing to runoff, and the spatial variation of runoff contribution corresponds to landscape type. Comparisons of melt with and without advection suggests that advection is an important process controlling the timing of basin snowmelt.