高岭石表面酸碱反应的电位滴定实验研究

采用表面酸碱电位滴定法探讨高岭石表面酸碱性质,基于多位模式(即假定高岭石表面存在3种基团Al2 OH 、AlOH 和SiOH ) ,根据实验所得数据对高岭石表面的质子化和去质子化过程的相关参数进行拟合,讨论各个位点所发生的反应,并探讨了支持电解质浓度、高岭石溶解过程对表面酸碱电位滴定结果的影响。高岭石的表面零净质子电荷点(pHPZNPC,5 .2 )不等同于零电荷点,当pH <5 .2时,高岭石表面荷正电荷,主要由于表面富硅贫铝层的形成和Al位的质子化所致;当pH >5 .2时,高岭石表面荷负电荷,以Si位和Al的去质子化反应为主。     

中国重要古生物化石及其产地保护浅论

中国古生物化石资源丰富且分布较广,目前在化石的保护与利用上还存在着诸多问题,主要体现在以下几个方面:古生物化石流失严重;古生物化石管理机构不健全;保护法规宣传力度不够;对外交流工作不够;其科普教育价值没有充分发挥;公众保护意识较差等。据此提出如下保护策略及措施:加大相关法律宣传力度;正确处理化石产地、旅游与地方经济的关系;科学规划保护区;积极开展科研工作,大力推广地质科普游;建立健全稳定的资金投入保障机制;加强生态环境的保护;有机整合地质资源,增加吸引力。     

Structural Characterisation of Organic Matter in Fine Tropospheric Aerosol by Pyrolysis-Gas Chromatography-Mass Spectrometry

The organic matter in tropospheric aerosol plays animportant, yet undetermined role in atmosphericprocesses. The bulk of organic carbon representing asignificant part of the fine aerosol mass is bound toa polymeric matter whose structure and properties areto date largely unknown. Here we use thefingerprinting technique of derivatization pyrolysis-gas chromatography-massspectrometry tosubstantiate that in terms of chemical structure partof this polymer in rural aerosol in summer can beregarded as natural humic matter. We suggest thatthese compounds are likely to be directly emitted bybiogenic sources.     

Site effects at Euroseistest—II. Results from 2D numerical modeling and comparison with observations

This paper presents results of numerical modeling of site response for Euroseistest. Ground motion across a very detailed model of the subsoil of this valley has been simulated for vertically incident SH waves. The predominance of locally generated surface waves is very clear in the synthetic seismograms. These results are then compared with published studies of observed site effects at this basin and with a detailed analysis of two events in the time domain. It is discussed in which sense it is possible to obtain a good fit between observations and 1D models, even though the real behavior involves locally generated Love waves. For this reason, it can be misleading to rely on an incomplete observation such as empirical transfer functions. Finally, it is stressed that in order to predict ground motion in alluvial valleys the information contained in the phase cannot be neglected.     

Supervised Mineral Classification with Semiautomatic Training and Validation Set Generation in Scanning Electron Microscope Energy Dispersive Spectroscopy Images of Thin Sections

This paper addresses the problem of classifying minerals common in siliciclastic and carbonate rocks. Twelve chemical elements are mapped from thin sections by energy dispersive spectroscopy in a scanning electron microscope (SEM). Extensions to traditional multivariate statistical methods are applied to perform the classification. First, training and validation sets are grown from one or a few seed points by a method that ensures spatial and spectral closeness of observations. Spectral closeness is obtained by excluding observations that have high Mahalanobis distances to the training class mean. Spatial closeness is obtained by requesting connectivity. Second, class consistency is controlled by forcing each class into 5–10 subclasses and checking the separability of these subclasses by means of canonical discriminant analysis. Third, class separability is checked by means of the Jeffreys–Matusita distance and the posterior probability of a class mean being classified as another class. Fourth, the actual classification is carried out based on four supervised classifiers all assuming multinormal distributions: simple quadratic, a contextual quadratic, and two hierarchical quadratic classifiers. Overall weighted misclassification rates for all quadratic classifiers are very low for both the training (0.25–0.33%) and validation sets (0.65–1.13%). Finally, the number of rejected observations in routine runs is checked to control the performance of the SEM image acquisition and the classification. Although the contextual classifier performs marginally best on the validation set, the simple quadratic classifier is chosen in routine classifications because of the lower processing time required. The method is presently used as a routine petrographical analysis method at Norsk Hydro Research Centre. The data can be approximated by a Poisson distribution. Accordingly, the square root of the data has constant variance and a linear classifier can be used. Near orthogonal input data, enable the use of a minimum distance classifier. Results from both linear and quadratic minimum distance classifications are described briefly.     

Environmental geological investigations at the Van open dump site, southeastern Turkey

 This study evaluates the geological, hydrogeological and hydrological conditions at the open waste dump site of the Van municipality in eastern Anatolia, Turkey. A geological map and a three-dimensional view of the project site have been prepared. All lithological units exposed at and near the dump site have been determined and their boundary relationships identified. Drainage basin characteristics of the dump site along with the water bearing properties of different lithological units have been assessed. For the rehabilitation of the existing dump site, material availability (clay as a liner, cap, and daily cover material; granular soil as a filter material) has been researched. Based on the geological, hydrogeological, morphological and hydrological conditions of the existing waste dump site, recommendations to minimize its environmental impact are presented. Received: 8 March 1999 · Accepted: 3 May 1999     

1998年8月27日伽师6.6级地震宏观烈度与震害

１９９８年８月２７日伽师６．６级地震的宏观考究结果为：极震区烈度为Ⅷ度,宏观震中位于乌堂村和艾孜尼库木一带,震前无明显的宏观异常;在烈度区内,不同地点的房屋破坏存在差异,这除了与场地土、地下水埋深有关外,与灾区房屋的重建率有关;包括岳胡和疏勒县２个烈度异常区,受灾人口共计１７万余人,其中死亡３人,重伤５人,轻伤１３人。     

Large amplification of ground motion at rock sites within a fault zone in Nocera Umbra (central Italy)

During the two mainshocks of September 26, 1997 inthe Umbria-Marche border a strong-motion accelerographrecorded peak ground accelerations as large as 0.6 g,approximately, in the town of Nocera Umbra, atdistances of 10 to 15 km from the epicentres. Thisvalue is significantly larger than expected on thebasis of the usual regressions with magnitude anddistance. A broad-band amplification up to a factor of10 was consistently estimated in previous papers,using both weak and strong motion data recorded at theaccelerograph site during local moderate earthquakes.To study the cause of this amplification we deployedsix seismologic stations across the tectonic contactbetween the Ceno-Mesozoic limestone and the Mesozoicmarly sandstone where the accelerograph is installed.Seismograms of 21 shallow aftershocks in the magnituderange from 2.2 to 4.0 and a subcrustal M_w = 5.3event are analysed. Regardless of epicentre location,waveforms show a large complexity in an approximately200 m wide band adjacent to the tectonic contact. Thisis interpreted as the effect of trapped waves in thehighly fractured, lower velocity materials within thefault zone.     

砂土液化判定评价与对策

砂土液化的评定、评价及对策虽然要概念不同,但有着必然的联系,本文通过工程实例分析,对液化判定、评价及对策进行较为详细的阐述。     

土体动非线性黏弹性模型及其ABAQUS软件的实现

基于土的动应力-应变关系--Davidenkov骨架曲线,采用破坏剪应变幅上限值作为分界点,对Davidenkov骨架曲线进行了修正,即当剪应力值大于破坏剪应力值时,土体产生破坏,土体的动剪切模量采用破坏后的动剪切模量;参考Mashing法则,构造了修正后的Davidenkov骨架曲线土体加卸载对应的应力-应变滞回圈曲线。基于ABAQUS软件的操作平台,开发了土体动弹塑性本构模型的子程序。选择南京某个典型软弱场地为研究对象,首先输入余弦加速度时程曲线,然后选取一条强震加速度记录作为基岩输入地震动,对不同峰值加速度水平下该场地的地震反应进行了二维有限元非线性分析,计算结果验证了所建模型的准确性和可用性。