火山沉积岩及其矿床研究中伽马测井曲线解释的误区

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。     

Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。     

三峡水库区兴山后坝滑坡成因分析

文章通过对三峡水库区兴山后坝滑坡的地质、结构及变形特征研究以及稳定性分析,阐明了该滑坡成因和影响因素。研究发现,滑坡活动主要受地形地貌、地层岩性、人类工程活动以及降雨等因素的影响。运用剩余推力法对比分析天然及暴雨条件下不同层位的滑坡稳定性系数,得出在暴雨作用下滑坡表层滑带稳定性系数最小,不同滑带的稳定性受降雨的影响也各不相同,呈表层〉浅层〉深层的规律;这主要受滑带土的粘土矿物组分的影响。     

地下矿产开采对天然气管道工程的安全影响评价

西气东输天然气管道工程途经兖州市,穿越杨庄、杨村、兴隆庄等煤矿矿区,压覆煤层埋深变化较大。该文采用预测法对各煤矿在不同开采条件下分煤层对管道运营安全的危害程度进行了评价分析。通过计算表明,煤矿开采埋深越浅,煤层越厚,对管道危害越严重。兴隆庄煤矿3煤层、杨村煤矿煤16t、煤17开采对管道影响强烈,杨庄煤矿煤16t、煤17开采对管道影响中等,兴隆庄煤矿煤16t、煤17开采对管道运营影响小。     

矿山固体废弃物对地质环境的影响分析

在山西省重点地区固体废弃物现状调查研究的基础上,通过试样试验,分析研究了固体废弃物对土壤、大气、水环境的污染,探讨了对固体废弃物的治理及利用,为研究矿山生态环境地质研究提供参考,同时积累工作经验。     

U-Pb Age Determination for Seven Standard Zircons using Inductively Coupled Plasma–Mass Spectrometry Coupled with Frequency Quintupled Nd-YAG (λ = 213 nm) Laser Ablation System: Comparison with LA-ICP-MS Zircon Analyses with a NIST Glass Reference Material

This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For ²⁰⁷Pb/²⁰⁶Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the ²⁰⁶Pb/²³⁸U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the ²⁰⁶Pb/²³⁸U (= 0.2302) newly defined in the present study is used, the measured ²⁰⁶Pb/²³⁸U and ²⁰⁷Pb/²³⁵U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for ²⁰⁶Pb/²³⁸U by measuring several zircon standards in individual laboratories.     

Mechanism for the rapid motion of the Qianjiangping landslide during reactivation by the first impoundment of the Three Gorges Dam reservoir, China

The first impoundment of the Three Gorges Dam reservoir in China started from a water surface elevation of 95 m on June 1, 2003 and reached 135 m on June 15, 2003. Shortly after the water level reached 135 m, many slopes began to deform and some landslides occurred. The Qianjiangping landslide is the largest one; it occurred on the early morning of July 14, 2003 and caused great loss of lives and property. Field investigation revealed that, although failure occurred after the reservoir reached 135 m, the stability of the slope was already reduced by preexisting sheared bedding planes. To study the mechanism of the rapid motion of this reactivated landslide, two soil samples were taken from a yellow clay layer and a black silt layer in the sliding zone, respectively, and a series of ring shear tests were conducted on the samples. One series of ring shear tests simulates the creep deformation behavior, while the other series simulates different shear rates. Conclusions drawn from analysis of the ring shear tests indicate that the mechanism of the rapid motion of the reactivated landslide was caused by the rate effect of the black silt layer during the motion phase after the creep failure. The yellow clay layer did not play any important role in the rapid motion in the 2003 event.     

Composition-Induced Variations in SIMS Instrumental Mass Fractionation during Boron Isotope Ratio Measurements of Silicate Glasses

An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated.     

煤炭采空区处理的新方法与实例分析

位于乌鲁木齐市南湖路以西的煤炭采空区面积达67 100.5m^2,区内构造从南到北主要由八道湾向斜和七道湾背斜组成,地层产状变化不大。该矿区开采较深,且采空区塌陷区有明显的地下水活动迹象。在对深孔大体积采空区注浆时,比较各种常见注浆治理方法,均存在不同的制约因素,故决定采用灌浆爆破压密法对采空区进行压实加固。经现场爆破试验,该区重复爆破次数在3～5次左右。灌浆爆破压密处理后,对不同土层进行取样对比分析,得到其相应密度（增加）及空隙比（减少）的变化分别为：杂填土14.1%,-7.9%;素填土5.9%,-3.3%;塌落煤层7.8%,-7.7%。根据压缩数据及现场测量,处理后的土体沉降2～4m,部分空体地段的沉降量达10～20m,治理效果明显。