Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.     

Structural stability of gravity dams: a progressive assessment considering uncertainties in shear strength parameters

Structural sliding stability of gravity dams is generally quantified using deterministic factor of safety, FS_det. Large FS_det (e.g. 3 in normal condition), are used in existing guidelines to guard against material and load uncertainties. Some guidelines allow an arbitrary reduction in FS_det (e.g. 2) when the knowledge in strength parameters increases from material test data. Yet, those reduced FS_det are not based on a rational consideration of uncertainties. Propagation of uncertainties could be done using probabilistic analyses, such as Monte-Carlo simulations (MC) which are complex and challenging for practical use. There is thus a need to develop simplified reliability based safety assessment procedures that could rationalise the adjustment of FS_det. This paper presents a progressive analysis methodology using four safety evaluation formats of increasing complexity: (i) deterministic, (ii) semi-probabilistic (partial coefficient), (iii) reliability based Adjustable Factor of Safety (AFS), and (iv) probabilistic. Comprehensive comparisons are made for the sliding safety evaluation of a 80 m gravity dam. Results are presented in terms of sliding factors of safety, allowable water levels, and demand/capacity ratios. It is shown that the AFS formulation, using direct integration, is simple and practical to use in complement to existing dam safety guidelines before undertaking MC simulations.     

基于GIPL2模型的青藏高原活动层土壤热状况模拟研究

青藏高原活动层土壤热状况,对深入了解高原活动层的厚度变化特征、下垫面的热力作用以及对气候变化预测均有重要意义。利用GIPL2模型模拟青藏高原多年冻土区不同植被状况下活动层土壤热状况。模拟结果表明：模型在高寒草原（QT06）试验点模拟效果较好,高寒沼泽草甸（QT03）试验点的模拟效果较差,高寒草甸（QT01）、高寒荒漠草原（QT05）和高寒草原化草甸（QT04）试验点的模拟效果介于高寒草原试验点和高寒沼泽草甸试验点之间。QT01、QT03、QT04、QT05和QT06的土壤温度模拟值与观测值相比,均方根误差分别为0.67、1.29、0.73、0.7和0.56℃;相关系数分别为0.99、0.87、0.98、0.98和0.96;平均误差分别为0.37、0.61、0.31、0.45和0.16℃。QT06模拟结果较好,原因在于此点土壤质地变化不大,模型的分层与所取的参数更加接近此点的实际状况。QT03模拟结果较差,可能由于此地区土壤中存在砾石,在导热率参数化方案中没有考虑砾石含量,导致模拟结果偏差较大。总体而言,GIPL2模型对青藏高原活动层土壤热状况的模拟具有一定的优势,是一种模拟多年冻土区活动层土壤热状况较为理想的模型。     

Visual MODFLOW在煤矿建设地下水环境影响评价中的应用 ——以甘肃省灵台县安家庄煤矿为例

结合甘肃省灵台县安家庄煤矿地下水环境影响评价实例,建立了评价区水文地质概念模型,并基于Visual MODFLOW对评价区地下水进行了数值模拟计算和验证;预报了设计开采条件下研究区不同含水层的地下水水位。预报结果表明:矿坑排水使得煤层所在含水层出现疏干现象,并且疏干范围随着开采范围的增加而不断扩大;在煤矿开采作用下,随着模拟时间的延续,煤系层上覆白垩系洛河组—宜君组含水层地下水位降落漏斗的范围及地下水位下降幅度不断增大,但降落漏斗的范围基本上不超过采空区范围;煤矿开采对白垩系环河组含水层无影响,至矿区开采期结束,未引起含水层水位下降;对上部孔隙、裂隙潜水含水层也无影响,至矿区开采期结束未引起含水层水位下降。     

黄河口清水沟河道的冲淤过程与模拟

为揭示黄河口清水沟河道长时段的冲淤演变规律并建立其冲淤计算方法,分析了清水沟1976—2015年的时空冲淤演变过程,采用河床演变的滞后响应模型,考虑河口来水来沙及河道延伸与蚀退的影响,建立了清水沟累计冲淤量的计算方法。结果表明:1976—1980年改道初期清水沟改道点上游先冲后淤,改道点下游淤滩塑槽,淤积量随着下游河道展宽而增加,1980年后改道点上、下游河道冲淤过程趋于一致;受水沙条件等因素影响,1980—1986年清水沟主槽冲刷展宽,之后主槽淤积萎缩;1996年清八改汊和2002年小浪底水库"调水调沙"原型试验以来,河道转淤为冲,2002年后河道冲刷速率随时间指数衰减;河床演变的滞后响应模型可计算清水沟长时段的冲淤过程,该方法可为预测未来清水沟冲淤演变趋势提供科学参考。     

处置单元核素135Cs迁移数值模拟研究

根据高放废物地质处置库概念设计,以北山花岗岩为参考岩性,内蒙古高庙子膨润土为参考缓冲材料,使用数值模拟软件tough2对放射性核素¹³⁵Cs在处置单元及其围岩中的迁移行为进行了数值模拟研究,考虑放射性核素衰变释热对核素迁移的影响。研究表明:膨润土对核素具有较强的滞留作用,模拟200000年后核素在花岗岩中迁移了1 m左右,且峰值为10-6个数量级;前10 a模型的温度变化最剧烈且温差最大,10 a后模型整体温度开始降低,2 000 a后整体温度接近于初始温度;温度的变化会引起核素迁移速率的改变,但总体温度对核素迁移的影响不大。     

祁连山区多年冻土空间分布模拟

祁连山区位于青藏高原东北边缘,是亚洲水塔重要的组成部分,多年冻土的变化对生态系统和水资源平衡有着重要影响。基于青藏高原第二次综合科学考察、道路勘察钻孔点以及前人所获得的多年冻土下界资料,回归得出祁连山区多年冻土下界统计模型,借助ArcGIS平台在DEM数据的支持下,模拟出祁连山区多年冻土空间分布图。结果表明：祁连山区多年冻土分布的下界具有良好的地带性规律,表现为随经纬度增加而降低的规律;祁连山区多年冻土在空间分布上呈现出以哈拉湖为中心向四周扩散的分布格局;祁连山区总面积约为16.90×10⁴ km²,其中多年冻土面积约为8.03×10⁴ km²,占总面积约47.51%。多年冻土区与季节冻土区之间存在着有不连续多年冻土分布的过渡区,过渡区面积约1.43×10⁴ km²,占总面积约8.46%。     

中国西部寒区流域冰川水文调节功能研究

冰川作为固体水库以“削峰填谷”的形式显著调节径流丰枯变化,冰川的水文调节功能对于中国西北干旱区至关重要。使用现有VIC-CAS模型模拟得到中国西部寒区2014—2100年径流预估数据,从趋势和波动变化相结合的视角,基于径流变差系数法,构建了冰川水文调节指数（Glacier_R）,分析了9个寒区流域冰川径流变化的稳定性,详细剖析了历史时期（1971—2010年）和未来到21世纪末这些流域冰川水文调节功能的强弱变化。结果表明：历史时期及RCP2.6和RCP4.5情景下,除长江流域外,青藏高原其余流域的冰川径流减小时间节点为2020s,西北内陆河流域则为2010s。历史时期及RCP2.6和RCP4.5情景下至21世纪末,尽管西部寒区大部分流域的冰川径流呈减少趋势,但波动幅度减小或无明显变化,冰川径流稳定性增强或无变化。总体上,西北内陆河流域的冰川水文调节功能较高,青藏高原流域的冰川水文调节功能较低。RCP2.6和RCP4.5情景下,至21世纪末,西部寒区各流域冰川水文调节功能均呈现减弱趋势,西北内陆河流域减弱更加显著,如RCP4.5情景下,木扎提河冰川水文调节功能降幅达25.4%,而青藏高原各流域的冰川水文调节功能一直处于较低水平。从年代际变化来看,1970s—2010s是寒区流域冰川水文调节功能较强的时期,1980s和2000s两个时段冰川水文调节功能尤强;RCP2.6和RCP4.5情景下,未来到21世纪末,冰川调节功能明显减弱。减弱的时间节点不同,最早为1970s,最晚为2020s。     

免共振沉桩过程对地表振动影响的FLAC3D数值模拟

为研究免共振沉桩过程对地表振动影响,采用密度放大法以消除模型桩弹性模量过大对计算效率的影响,在有限差分软件FLAC^3D中建立了相应的连续振动沉桩模型,并和文献中的现场测试结果进行了比较,分析了激振力幅值和振动频率这两个施工参数对地表振动响应的影响。结果表明：密度放大法可有效提高数值模拟的计算效率,模拟沉桩7.0倍桩径（4.9 m）所需计算时间约为12.0 h,数值结果较好地模拟了现场测试中免共振沉桩的地表振动影响;激振力幅值和振动频率均主要对近场（水平距离为5.0倍桩径范围内）的地表振动有明显影响;临界沉桩深度与地表振动影响峰值相对应,该深度随水平距离先增大后趋于稳定;激振力幅值对临界沉桩深度的改变不明显,振动频率对远场临界沉桩深度则有较明显影响。     

Extenuating the parameters using HEC-HMS hydrological model for ungauged catchment in the central Omo-Gibe Basin of Ethiopia

Characteristics of ungauged catchments can be studied from the hydrological model parameters of gauged catchments. In this research, discharge prediction was carried out in ungauged catchments using HEC-HMS in the central Omo-Gibe basin. Linear regression, spatial proximity, area ratio, and sub-basin mean were amalgamated for regionalization. The regional model parameters of the gauged catchment and physical characteristics of ungauged catchments were collated together to develop the equations to predict discharge from ungauged catchments. From the sensitivity analysis, crop coefficient (CC), storage coefficient (R), constant rate (CR), and time of concentration (TC) are found to be more sensitive than others. The model efficiency was evaluated using Nash–Sutcliffe Efficiency (N_SE) which was greater than 0.75, varying between ?10% and +10% and the coefficient of determination (R²) was approximated to be 0.8 during the calibration and validation period. The model parameters in ungauged catchments were determined using the regional model (linear regression), sub-basin mean, area ratio, and spatial proximity methods, and the discharge was simulated using the HEC-HMS model. Linear regression was used in the prediction where p-value ≤ 0.1, determination coefficient (R²) = 0.91 for crop coefficient (CC) and 0.99 for maximum deficit (MD). Constant rate (CR), maximum storage (MS), initial storage (IS), storage coefficient (R), and time of concentration (TC) were obtained. The result is that an average of 30 m³/s and 15 m³/s as the maximum monthly simulated flow for ungauged sub-catchments, i.e. Denchiya and Mansa of the main river basin .