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91.
石墨炉原子吸收光谱法测定土壤样品中镉 总被引:5,自引:0,他引:5
采用磷酸氢二铵作基体改进剂塞曼扣背景石墨炉原子吸收光谱法测定土壤样品中镉,方法检出限DL=0.012μg/g,精密度RSD在3.55%~7.33%,满足了土壤样品中镉测定的镉质量要求。 相似文献
92.
93.
文章列数了《中国地层典》5个方面的重要失误:不是中国地层名称全览性的工具书,急于采用处于争议中的术语,大量地层单位名称的出处因考证不到位而形成张冠李戴,采用的历史优先律不是国际共识,在编撰过程中建立新名称。文章用选出的泰山杂岩、滹沱系、秦岭片岩和仑山石灰岩4个名称为例说明《中国地层典》对其出处的考证不到位,进而论证《中国地层典》的诸多解释可信度低。文章严肃地指出“历史优先律”给中国地层学造成的不良后果:它破坏了地层命名法的标准性,颠倒了中国地层命名史,干扰了中国地层名称的管理。 相似文献
94.
Microlites (minute spherulitic, dendritic, skeletal, acicular and poikilitic crystals) diagnostic of crystallization in quenched melt or glass in fault rocks have been used to infer fossil earthquakes. High‐P microlites and crystallites are described here in a variably eclogitized gabbro, the wallrock to the coesite‐bearing eclogite breccia at Yangkou in the Chinese Su‐Lu high‐P metamorphic belt. The studied hand specimens are free of discernible shear deformation, although microfractures are not uncommon under the microscope. In the least eclogitized gabbro, the metagabbro, stellate growths of high‐P minerals on the relict igneous minerals are common. Dendritic garnet crystals (<1?5 μm) grew around rutile and/or phengite replacing ilmenite and biotite, respectively. Skeletal garnet also rims broken flakes of igneous biotite and mechanically twinned augite. Radial intergrowths of omphacite and quartz developed around relict igneous orthopyroxene and are rimmed by skeletal or poikilitic garnet where a Ti‐bearing mineral relict is present. Acicular epidote, kyanite and phengite crystallites are randomly distributed in a matrix of Na‐rich plagioclase, forming the pseudomorphs after igneous plagioclase. In the more eclogitized gabbro, the coronitic eclogite located closer to the eclogite breccia, all the igneous minerals broke down into high‐P assemblages. Thick coronas of poikilitic garnet grew between the pseudomorphs after igneous plagioclase and ferromagnesian minerals. The igneous plagioclase is replaced by omphacite crystallites, with minor amounts of phengite and kyanite. Thermodynamic modelling of the plagioclase pseudomorphs shows an increase in P–T in the wallrock from the metagabbro to the coronitic eclogite, and the P–T variation is unrelated to H2O content. The fluid‐poor pressure overstepping scenario is unsupported both by phase diagram modelling and by whole‐rock chemical data, which show that the various types of eclogitized gabbro are all fairly dry. A large pressure difference of >2 GPa between the metagabbro and the coesite‐bearing eclogites ~20 m apart cannot be explained by the subduction hypothesis because this would require a depth difference of >60 km. The microlites and crystallites are evidence for dynamic crystallization due to rapid cooling because constitutional supercooling was unlikely for the plagioclase pseudomorphs. The lack of annealing of the broken biotite and augite overgrown by strain free skeletal garnet is consistent with a transient high‐P–T event at a low ambient temperature (<300 °C), probably in the crust. Therefore, the eclogitization of the wallrock to the eclogite breccia was also coseismic, as proposed earlier for the eclogite facies fault rocks. The outcrop‐scale P–T variation and the transient nature of the high‐P–T event are inconsistent with the other existing tectonic models for high‐P metamorphism. The fact that the less refractory but denser biotite is largely preserved while the more refractory but less dense plagioclase broke down completely into high‐P microlite assemblages in the metagabbro indicates a significant rise in pressure rather than temperature. Given that the metamorphic temperatures are far below the melting temperatures of most of the gabbroic minerals under fluid‐absent conditions, stress‐induced amorphization appears to be the more likely mechanism of the coseismic high‐P metamorphism. 相似文献
95.
A hydraulic invariance‐based methodology for the implementation of storm‐water release restrictions in urban land use master plans 下载免费PDF全文
Viviana Pappalardo Alberto Campisano Francesco Martinico Carlo Modica Luca Barbarossa 《水文研究》2017,31(23):4046-4055
A hydraulic invariance (HI)‐based methodology was developed as a tool to support implementation of storm flow control measures into land use master plans (LUMPs) for urban catchments. The methodology is based on the use of simple hydrologic analysis to compare predevelopment and postdevelopment catchment flow release scenarios. Differently from previous literature examples, for which the parcel scale is usually considered for the analysis, HI was pursued assuming the LUMP areas of transformation as the basic units for assigning storm water control measures in the form of flow release restrictions. The methodology was applied to a case study catchment in the southern part of the City of Catania (Italy), for which the LUMP re‐design has been recently proposed. Simulations were run based on the use of the EPA‐Storm Water Management Model and allowed deriving flow release restrictions in order to achieve HI at the subcatchment level for design events of different return period. 相似文献
96.
深层水平位移监测(即测斜)能直接反映土体或支护结构的变形特征,是高风险建筑基坑工程安全的重要保证。本文对测斜技术原理进行了阐述,并根据工程实践经验对测斜监测的作业要点进行了探讨与总结。 相似文献
97.
城市旅游电子地图是人们出行旅游必备的信息指南。为了设计满足不同性别的旅游用户的需求的城市旅游电子地图,本文分析了基于性别差异用户的认知特点,以及性别差异对旅游电子地图编绘的影响。重点提出了基于性别差异的城市旅游电子地图的内容设计、符号设计和语音功能设计。最后,本文探讨了城市旅游电子地图的编制原则,主要包括内容设计原则、界面设计原则和符号设计原则。基于用户性别进行地图设计的研究思想可以更好地为广大用户提供更加全面翔实的旅游信息和服务。 相似文献
98.
纹理特征向量与最大化熵法相结合的SAR影像非监督变化检测 总被引:1,自引:0,他引:1
合成孔径雷达(SAR)影像具有明显的斑点噪声,在变化检测中,一般需要考虑空间邻域信息。本文结合SAR影像丰富的纹理信息,提出一种考虑空间邻域信息的高分辨率SAR影像非监督变化检测方法,用基于灰度共生矩阵(GLCM)的32维纹理特征向量构造差异影像。通过最大化熵法自动选取阈值,对精度指标随窗口大小的变化进行回归分析,得到适合于变化检测的窗口为11×11。试验表明,本文方法优于马尔科夫随机场法,可以减小斑点噪声的影响,有效提高高分辨率SAR影像变化检测的精度。 相似文献
99.
Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy 下载免费PDF全文
Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample). 相似文献
100.
Jesse D. Ward Mark Bowden C. Tom Resch Steven Smith Bruce K. McNamara Edgar C. Buck Gregory C. Eiden Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148
Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant. 相似文献