GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

SPATIAL DISTRIBUTION OF NUTRIENTS OF SHALLOW LAKE IN THE ZHALONG WETLAND

1 INTRODUCTIONNitrogen and phosphorus in the water are the nu-trients limited in natural wetlands,which seriously in-fluence on the ecosystem production and the biodiver-sity(Mitsch,Grosselin,2000).Nitrogen and phos-phorus recycles have been interrupted b…     

侵蚀红壤植被恢复后土壤呼吸日动态及日呼吸速率测定方法比较

采用密闭室红外气体分析仪法(IRGA法)观测了中亚热带红壤侵蚀裸地植被恢复后不同季节土壤呼吸速率的日动态变化,并比较了IRGA法与碱吸收法(AA法)测定的土壤呼吸速率.结果表明:侵蚀裸地植被恢复后土壤呼吸速率日动态呈单峰曲线,与土壤温度的昼夜变化基本一致,最高值一般出现在午后13∶00~17∶00,最低值出现在凌晨3∶00~7∶00;植被恢复显著提高了土壤日呼吸速率,但明显降低了土壤呼吸速率日变化幅度;马尾松林对土壤呼吸速率日变化幅度降低程度高于板栗园和百喜草地,且对夏季的降低程度影响最大.而IRGA法和AA法测定的土壤呼吸速率具有显著的幂函数关系,AA法测定的土壤呼吸速率为IRGA法的27.5%~218%,平均为76.2%.当土壤呼吸速率较低时,AA法比IRGA法高估了土壤呼吸速率;反之,AA法则低估了土壤呼吸速率.     

Electrical aerosol spectrometer of Tartu University

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.     

厚层覆盖区综合物化探方法找金试验研究——以广西兴安金石金矿为例

在兴安金石金矿外围 4号分散流异常区 ,通过地电化学提取金测量法 ,查明测区存在 5个走向规模小于 5 0 m的金异常区 ,W( Au) 最大值为 72 .4× 10 - 9,高出背景值十几倍 ,并藉综合土壤吸附汞测量 ,高精度磁测和激发极化法等多种物化探方法来确定这些异常区的地质、地球化学和地球物理特征 ,提出金矿成矿的有利部位在金的地电提取高异常区、高汞量异常区、高磁性异常区、低视电阻率异常区和中等视极化率异常区的“三高一低一中”的找矿模式。确定测区的北北东角 (右下角 )一带具备有利的金矿成矿条件     

电磁波CT技术在探测堤坝工程中的应用

应用电磁波CT探测技术对流溪何竹料段大堤和丰顺县虎局水库大坝渗水通道进行了探测研究，由于电磁波的吸收系数和地层结构有密切关系，因此，电磁波CT是通过能量的变化观测反演吸收系数的分布，进而推测地下构造的分布，利用电磁波的吸收系数为层析物理量，在钻孔中进行透射观测，以优于0.5m的分辨率清楚地揭示了测区内渗水层位的分布情况。     

南向行星际磁场事件与磁暴关系的研究

利用172-182年IMP-8飞船的太阳风观测资料和相应地磁活动性指数Dst和AE,研究了43个南向行星际磁场事件期间太阳风和磁层的耦合问题. 与这43个事件对应的地磁暴是中等的和强的磁暴(Dst＜-50nT). 结果表明:(1) 在43个事件中有11个(约占25.6髎)紧随激波之后,18个处于激波下游流场中(占42髎),其余14个(占33髎)和激波没有关连. 绝大多数事件都伴有太阳风动压和总磁场强度的增加;(2) 当行星际晨昏向电场强度EI＞-4mV/m时,只引起磁亚暴,对Dst指数没有明显影响. 仅当EI＜-5mV/m时,磁亚暴和磁暴才会同时出现;(3) 太阳风动压的增加会增强能量向环电流的输入,但不是密度和速度单独起作用,而是以PK=ρV2的组合形式影响能量的输入;(4) 虽然行星际磁场(IMF)南向分量BZ对太阳风和磁层的耦合起着关键作用,但IMF的BX和BY分量相对于BZ的大小对太阳风向磁层的能量传输也有一定影响. 当BX、BY相对BZ较大时能量耦合加强.     

复杂介质结构中折射界面的哈格多恩原理波前成像

在城市活断层探测中 ,浅层结构常常表现为强烈的非均匀性 ,界面横向强烈起伏 ,层内速度变化较大 ,传统的基于平界面均匀层模型的折射资料处理方法不能适用。研究开发能应用于复杂介质结构中折射资料处理的方法就显得十分必要。文中基于惠更斯原理 ,用波前扩张法对波场作正演计算 ,根据哈格多恩折射波前成像原理 ,在lecomte算法和Hole有限差分计算程序的基础上 ,开发出 1种复杂介质结构中折射资料的处理方法与软件 ,并用此方法处理了福州城市活断层折射探测试验中在义序完成的 2条折射剖面资料。结果表明 :探测区浅层为 3层结构 ,分别为盖层、强风化层和基岩。基岩顶界面的埋深约为 5 8～ 5 2m ,盖层P波速度变化较大