万家寨引黄工程泥灰岩段隧洞岩石掘进机(TBM)卡机事故工程地质分析和事故处理

隧道全断面岩石掘进机 (TBM )的施工对地质条件适应性是一个不断认识和深化的过程 ,其中很多认识是来自已发生的各种各样事故和对事故原因的理性认识。本文是在对某隧洞TBM卡机地段的岩性 (包括工程性质 )、构造、地应力及其在TBM施工条件下的变化等方面进行工程地质力学研究的基础上 ,指出层间剪切带的存在及由此而产生的较大变形速率是导致事故发生的工程地质原因 ,并提出了相应的处理意见和建议。TBM卡机问题的顺利解决和它重新开始快速掘进证明了作者分析和工程处理措施的合理性。本文的分析有助于加深TBM施工对复杂地质条件适应性的认识 ,并可望为避免类似事故的再次发生提供参考和借鉴。     

胶莱盆地含金建造地球化学特征

胶莱盆地蓬家夼金矿床及宋家沟金矿床均赋存于下白垩统莱阳群一段含金建造中,该含金建造由砾岩、含砾砂岩、碳质泥岩及碳酸盐岩等组成,Au100.2～241.0ng/g,Ag1.50～3.73μg/g,Zn560～1021μg/g,Pb356～364μg/g,Cu60～394μg/g,As11.0～25.4μg/g,同时富硫及有机碳。含金建造K-Rb、K-Ba呈正相关,K-Sr、K-Ca不相关,Sr/Ba<1,B、V关系均显示了陆相淡水沉积特征。La/Y-REE组成显示了沉积特征。围岩、矿石及矿石中黄铁矿及磁铁矿的稀土元素分布模式相似,该含金建造是矿源层也是容矿层,是区内重要的成矿地质条件及找矿标志。     

A mathematical hysteretic model for elastomeric isolation bearings

An analytical model for high damping elastomeric isolation bearings is presented in this paper. The model is used to describe mathematically the damping force and restoring force of the rubber material and bearing. Ten parameters to be identified from cyclic loading tests are included in the model. The sensitivity of the ten parameters in affecting the model is examined. These ten parameters are functions of a number of influence factors on the elastomer such as the rubber compound, Mullins effect, scragging effect, frequency, temperature and axial load. In this study, however, only the Mullins effect, scragging effect, frequency and temperature are investigated. Both material tests and shaking table tests were performed to validate the proposed model. Based on the comparison between the experimental and the analytical results, it is found that the proposed analytical model is capable of predicting the shear force–displacement hysteresis very accurately for both rubber material and bearing under cyclic loading reversals. The seismic response time histories of the bearing can also be captured, using the proposed analytical model, with a practically acceptable precision. Copyright © 2002 John Wiley & Sons, Ltd.     

含水矿物在真空下的释Ar机制:Ar-Ar热年代学面临的新问题

地质体的实际情况、激光显微探针束研究、XRD和SEM观测以及真空加热下Ar的释放特征都表明体积扩散不是含水矿物在真空加热中释放Ar的唯一机制。在低温下 ,Ar的释放主要受由缺陷引起的短程扩散和体积扩散共同作用的多途径扩散机制制约 ;而在高温下 ,由于含水矿物在真空中不够稳定 ,Ar的释放受到脱羟基、脱氢、氧化反应、分层作用等造成的晶体结构改变的强烈影响。含水矿物在高温下的氧化分解会导致矿物中原始Ar浓度梯度的均一化 ,因而无法得到真实的Ar分布剖面 ,也无法据此计算矿物的封闭温度 ,并进而可能影响到ArAr年龄坪的地质意义。     

海拉尔盆地含油气系统

海拉尔盆地为中－新生代的断陷－坳陷型盆地，其发育演化主要经历了地壳隆起、断陷、坳陷、萎缩四个阶段。根据对成藏要素分析，确定出以凹陷为单元的三类含油气系统，各含油气系统都有各自的形成和分布规律。按其空间展布，又可划分为同期并列式、同期交叉式、异期叠合式三种组合形式。这些形式的有效组合，构成了海拉尔盆地内有利的油气聚集带。     

Pseudotachylytes in the southern border fault of the Cenozoic intracontinental Teletsk basin (Altai, Russia)

The Cenozoic intracontinental Teletsk basin in the Central Asian Altai Mountains is composed of a complexly structured northern and a more simple southern sub-basin. These sub-basins formed in two distinct kinematic stages when first the NNW-striking Teletsk- and then the NE-striking West-Sayan shear zones became reactivated in the Cenozoic under dominant NS-oriented horizontal compression. Although the entire Teletsk basin strikes roughly NS, the southern sub-basin is parallel to the NNW-trending, amphibolite facies Teletsk ductile shear zone, while the northern sub-basin is NS-striking and flanked by differently structured, greenschist facies basement. Basement reactivation closely controlled the southern sub-basin formation, but this is less clear for the northern sub-basin. Contrasts between northern and southern basement and the exclusive occurrence of pseudotachylytes along the margins of the southern basin are explored for their contribution to the formation of the Teletsk basin with two distinct sub-basins.In the ductile shear fabric of the basement flanking the southern sub-basin, concordantly interleaved pseudotachylytes and isolated breccia lenses reflect local brittle deformation along the ductile fabric. The genetic link between breccia lenses and pseudotachylyte occurrences was defined by microstructural investigation. It allows to explore their possible development in a dextral strike–slip zone. These rocks occur in a large fault-bounded segment of the basement. The geometry of the structures in the segment is comparable with a dextral strike–slip sidewall-ripout structure along the Teletsk shear zone. Seismic slip related to pseudotachylytes is attributed to the sudden stress release on the NNW-striking Teletsk shear zone, when the latter became unconstrained by reactivation of the NE-trending West-Sayan fault zone at its northern boundary. The boundary of the sidewall-ripout structure was reactivated as a large listric fault in a later stage. The northern sub-basins roughly develop along an NS strike and are assumed to reflect reactivation of the ductile shear zone underneath the variably structured greenschist facies basement outcropping along the flanks of the sub-basin.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001     

Sm-Nd ISOTOPIC AGE OF LAMPROPHYRES IN THE GEZHEN GOLD-BEARING SHEAR ZONE ON HAINAN ISLAND AND ITS GEOLOGICAL IMPLICATIONS

Sm-Nd isotopic compositions of eight lamprophyre samples, which come from the Gezhen gold-bearing shear zone on western Hainan Island, are measured. The Sm-Nd isochron age is 495.98&#177;13.14 Ma, (143Nd/144Nd) 0=0.512094, εNd(t) ranges from +1.80 to +2.00 and TDM from 982 Ma to 1196 Ma (average: 1060 Ma). The authors point out that the whole-rock Sm-Nd isochron age (495.98 &#177; 13.14 Ma) really represents the petrogenetic age of lamprophyre and the time of magmatism during subsequent subduction.     

Cu–Fe Bearing Zinc Sulfide from Laloki Stratabound Massive Sulfide Deposit, Papua New Guinea: Chemical Characterization

Abstract: A strange, unidentified, Cu-Fe bearing zinc sulfide occurs in the Laloki massive sulfide deposit, Papua New Guinea. The mineral is optically uniform in texture but is chemically variable and zoned even within a single grain. Copper contents vary from 0.1 up to 8.85 wt%. Iron reaches 18.31 wt% at maximum and decreases as Cu increases. It is remarkable, however, that the total Fe+Cu remains essentially unchanged between roughly 18 and 20 wt%. Zn and S are least variable, giving 45.85–47.84 wt% and 33.48–34.58 wt%, respectively. Other trace elements such as Cd and Mn are in general less than 0.2 wt%. It is strongly suggested that the mineral in question constitutes a unique Fe-Cu substitutional solid solution series belonging essentially to the Zn–Fe–Cu–S system.
The ideal chemical formula of the solid solution series can well be presented as Zn₁₀(Fe, Cu)₅S₁₅ or Zn₂(Fe, Cu)S₃, where Fe is always greater than Cu. It is intriguing that chalcopyrite blebs are recognizable restrictively only in nearby portions of the Cu-rich end member with the ideal composition close to Zn₁₀Fe₃Cu₂S_15. It has been confirmed by vacuum-sealed heating experiments that this mineral is decomposed to produce chalcopyrite and Fe-bearing normal sphalerite at temperatures below 200C. This would provide another evidence for the existence of such distinct phase as suggested here.     

A comparison of tectonic ambient shear stress value in China with that in western USA

Introduction The stress status of the earths crust is closely related to global structure, the direction of plate movement, the drive mechanism of plate, earthquake cause, etc. Therefore the researches of the stress status of the earths crust and the process of dynamic evolution are paid a great attention to by many people around the world (Zoback, Zoback, 1980; Zoback, et al, 1989; Zoback, 1989; Spence, 1997; Fuchs, 1997; Plenefish, Bonjer, 1997; Muller, et al, 1997; XU, et al, 1989; WAN…