An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

Research relevance, 'knowledge transfer' and the geographies of CASE studentship collaboration

The Co-operative Awards in Science and Engineering (CASE) studentship programme of the UK Research Councils provide one example of wider efforts internationally to encourage so-called 'knowledge transfer' and thereby harness publicly supported university research more closely to the goals of national competitiveness, regional economic development and local regeneration. In this paper we describe the implications of how the various UK research councils have interpreted the objectives and beneficiaries of 'knowledge transfer', both for the relative opportunities available to human and physical geographers for collaboration through CASE and for the sorts of values that their research must serve. Then, we draw on unpublished data from the Economic and Social Research Council (ESRC) to explore the geographies of CASE studentship allocation and participation. The broad regional and institutional patterns of participation we describe have important implications for ongoing debates in the UK about research selectivity and the role of the university as an engine of local development, while the striking disciplinary patterns of CASE participation, and in particular the overwhelming success of geographers in this competitive programme, provide an opportunity to reassess claims about whether and for whom geographical research is relevant.     

A new view of Italian seismicity using 20 years of instrumental recordings

In this paper, we show the seismicity of the past 20 years that occurred in Italy and surrounding regions. Hypocentral locations have been obtained by using P- and S-wave arrival times from the INGV national and several regional permanent seismic networks. More than 48,000 events, selected from an original data set of about 99,780, are used to reconstruct the most complete seismic picture of the Italian region so far. The seismicity distribution allows inference on seismotectonics of this complex region of subduction versus continental collision. Our results clearly reveal the geometry of the Adria and the Ionian subduction and a continuous normal fault belt in the upper crust, following the Apennines mountain range. The depth of the seismogenic layer is computed from the cut-off of seismicity at depth and shows large variations along and across the seismic active regions. Earthquakes are generated by the different velocity of slab retreat and the subsequent asthenospheric upwelling.     

Morphological and microtectonic analysis of Quaternary deformation from Puná and Santa Clara Islands, Gulf of Guayaquil, Ecuador (South America)

This paper presents the neotectonic study of Santa Clara and Puná Islands sited in the Gulf of Guayaquil eastern part. Both islands are located on the south-western segment of the fault zone bounding to the east the North Andean Block. Fault motion and morphostructural analysis were carried out from Pleistocene age terrain. A two step deformation characterises the South Puná tectonics. The first step involves the Zambapala Cordillera uplift that post-dates Pleistocene sediments and pre-dates a marine terrace correlated with the M.I.S. 11 or 13 (440–550 ka). The second step is the formation of a pull-apart that shows evidence of 2.9 km dextral offset since the M.I.S. 11 or 13, giving an offset mean rate of 5.3 to 6.6 mm/yr. This rate is higher than the one calculated on the Pallatanga Fault northeast of the study area, in the Western Andean Cordillera, suggesting that deformation is split in different fault segments from the Gulf of Guayaquil to the continent. The Zambapala Cordillera uplift and transpression deformation requires a compressive event that may have been induced by the subduction process during the early Pleistocene.     

Deep structure of the northeastern Japan arc and its implications for crustal deformation and shallow seismic activity

Seismic tomography studies in the northeastern Japan arc have revealed the existence of an inclined sheet-like seismic low-velocity and high-attenuation zone in the mantle wedge at depths shallower than about 150 km. This sheet-like low-velocity, high-attenuation zone is oriented sub-parallel to the subducted slab, and is considered to correspond to the upwelling flow portion of the subduction-induced convection. The low-velocity, high-attenuation zone reaches the Moho immediately beneath the volcanic front (or the Ou Backbone Range) running through the middle of the arc nearly parallel to the trench axis, which suggests that the volcanic front is formed by this hot upwelling flow. Aqueous fluids supplied by the subducted slab are probably transported upward through this upwelling flow to reach shallow levels beneath the Backbone Range where they are expelled from solidified magma and migrate further upward. The existence of aqueous fluids may weaken the surrounding crustal rocks, resulting in local contractive deformation and uplift along the Backbone Range under the compressional stress field of the volcanic arc. A strain-rate distribution map generated from GPS data reveals a notable concentration of east–west contraction along the Backbone Range, consistent with this interpretation. Shallow inland earthquakes are also concentrated in the upper crust of this locally large contraction deformation zone. Based on these observations, a simple model is proposed to explain the deformation pattern of the crust and the characteristic shallow seismic activity beneath the northeastern Japan arc.     

Quantum-thermodynamic treatment of intrinsic anharmonicity; Wallace’s theorem revisited

Wallace (in Thermodynamics of crystals, 1972) developed a theorem, rooted in rigid lattice dynamics, which incorporates intrinsic anharmonic effects in solids. The practical application of this theorem in mineral physics is computationally involved and this is the main reason for the theorem not getting the attention it deserves. Because intrinsic anharmonicity is an important issue at the extreme conditions in planetary mantles, we derived a method which removes the computational obstacles in applying this theorem. We extended the theorem to incorporate details of the phonon spectrum and tested our algorithm on forsterite (Mg₂SiO₄). Using a least squares inversion technique applied to all available experimental data, we show that it results in an accurate representation of thermodynamic properties and sound wave velocities of Mg₂SiO₄ in its complete pressure–temperature stability range. We also show that the accuracy of our results is not significantly affected by the use of a different equation of state.