Crystal Structure and Geometry-Optimization Study of N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrme

N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrine has been synthesized. The structure is determined by X-ray diffraction method and elemental analysis. The crystal system belongs to orthorhombic space group P(2)2(1)2(1). The geometry has been ob-tained from the density functional theory (DFT) method and the B3LYP method employing the 6-31G* basis sets. The calculated results propose that the latter is close to the experimental data. The structural parameters from the theory are close to those of the crystal and the calculated total energy of coordination is -31677.172 eV. The energy of HOMO and LUMO and the energy gap are 5.179 eV, -1.603 eV and 3.577 eV, respectively.     

Microsatellite Variation in the Oyster Crassostreaplicatula Along the Coast of China

Genetic diversity and differentiation of the oyster Crassostreaplicatula populations from China's coast were studied basedon seven microsatellite loci.All loci showed high polymorphism for all five C.plicatula populations,with an average number of alleleper locus of 19.3-27.9 and an average expected heterozygosity of 0.889-0.952.Significant departures from Hardy-Weinberg equilib-rium and deficits of heterozygotes were observed over most populations at each locus,which were fully explained by null alleles.Microsatellite analysis revealed significant subdivision in the C.plicatula populations.According to the neighbor-joining tree con-structed on the basis of the D,A distance,the five populations fell into three regional groups,showing a relatively homogeneous geneticstructure in geographically close populations.Assignation tests correctly assigned high percentages of individuals to their originalpopulations and groups,and also confirmed the existence of genetic differentiation among C.plicatula populations.The results ob-tained in this study will facilitate the formulation of appropriate fisheries management programs,stock identification and conservationof biodiversity for the species.     

The difference of economic function and the trends of industrial development in central cities along the Xijiang River

TheXijiangRiveristhemainwaterwayacrosseastandwestinSouthernChina.ItsmaincoursebacksontothewestofGuangdongandthesouthwestofChina,withitsexitthroughHongKong,MacaoandSoutheasternAsia.Ithasawidehinterlandandconvenientwatertransportation.AlongtheXijiangRiver,thecentralcitiesarethecities,whichspreadalongtheXijiangRiver'smaincourse,theZhujiangRiver'sdeltaandoutlet,andBosehasbeenselectedasarepresentativecityintheupperreachesoftheXijiangRiver.Theytotal12cities,includingGuangzhou,Shenzhen,Zhuh…     

秭归龙会观5.1级震区及其邻区新生代以来的地壳应力场特征

为了研究三峡坝库区的地壳稳定性,根据奥陶－侏罗纪地层中构造变形的实际观测资料,计算了秭归龙会观５．１级震区及其邻区新生代以来区域应力场的主应力方向。结果表明：主压应力为北东东向,主张应力为北北西向;现代构造应力场与新生代以来应力场基本一致;晚第三纪以来,该区构造应力场相对稳定和统一。     

广西若干重大基础地质特征

文章根据华南地区物探、化探、遥感编图广西综合解译成果,研究广西若干重大基础地质特征,着重讨论地壳结构、深部构造、主要隐伏深断裂带、基底性质等,以板块观点划分大地构造单元,提出广西地壳属陆壳型性质和扬子板块在广西的边界划在三江-大新一线的新认识.     

Spatial distribution characteristics of national protected areas in China

Journal of Geographical Sciences - This paper investigated spatial structures of 3418 national protected areas (NPAs) grouped into 13 types using GIS and quantitative analysis, including point...     

基于全球分布的地震观测数据估计0S0模态的特征频率及品质因子

选取2011-03-11日本MW9.3地震后全球地震台站记录的约220 h波形数据,基于一定的判断准则,筛选出质量较高的448个垂向观测数据,采用频域AR方法对0S0模态的特征频率和品质因子进行估值,并以信噪比为权重进行加权平均,得到特征频率f=0.814 658 4±5.3×10-7,品质因子Q=5 586±12。该结果与已有研究成果相比精度更高,有助于约束现有地球介质密度和衰减模型,使其更接近真实地球。     

Spatial Distribution Assessment and Source Apportionment of Land-Based Pollutant Yield from Qingdao,China

The spatial distribution of chemical oxygen demand(COD) and total nitrogen(TN) yield from Qingdao are studied by comparing pollutant yield amount, densities and spatial aggregation(Getis-Ord indexes) among the land-based pollutant source regions(PSRs) entering the three sub-seas(i.e. the Jiaozhou Bay(JZB), other coastal area in the Yellow Sea(OCAYS) and Laizhou Bay(LZB), respectively). Industrial composition of the loads are also studied by comparing pollutant yield among the sources of agriculture, rural domesticity, industry, urban domesticity and service, and calculation of Gini coefficient. Results show that spatial distribution of COD and TN yield from Qingdao are extremely unbalanced. The JZB, with less than 3% of the total coastal sea area of Qingdao, received 62% COD load and 65% TN yield from Qingdao, while the OCAYS, with more than 97% area, only received 23% COD and 20% TN, which consist with the much worsen water quality of JZB than that of OCAYS. On the other hand, the source apportionment of COD and TN loads in the PSRs entering JZB and the OCAYS was similar. The agricultural and domestic sources with high pollution intensity account for more than 80%, while the industrial and service sources with low pollution intensity account for less than 20%. While Gini coefficients, COD 0.81 and TN 0.84 which are much higher than the ‘imbalance' threshold of 0.4, show the uneven industrial structure of Qingdao. These results may be useful in the determination of land-based pollution total amount control at the PSR level.     

金品位分形结构特征及其地质意义——以胶东乳山蓝家庄金矿床为例

胶东乳山蓝家庄金矿床为近年来胶东东部牟平-乳山金成矿带探明的一处大型金矿床。该文通过系统收集该矿床Ⅰ号矿体金品位数据,综合运用特征参数统计和分形理论,分析了金品位特征参数垂向变化规律及垂向分形结构特征。研究结果表明,金品位具有显著的多重分形结构特征,矿化较好地段一般具有3～4个分维值,而矿化较差地段一般仅具有1个分维值。金品位特征参数和分形结构的规律性变化指示蓝家庄金矿床Ⅰ号矿体向-500m标高以深仍有一定程度地延伸,预测深部具有良好的找矿前景。     

1992-2015年中亚五国土地覆盖与蒸散发变化

1991年苏联解体,中亚五国独立使得土地覆盖与蒸散发格局发生深刻变化。以中亚五国为研究区,采用欧空局气候变化项目（CCI）土地覆盖和全球陆地数据同化系统（GLDAS）蒸散发数据,分析1992-2015年土地覆盖与蒸散发时空变化特征,进一步研究耕地蒸散耗水特征。结果表明：① 中亚五国土地覆盖变化具有阶段性特征,耕地扩张引起土地覆盖格局变化。1992-2003年耕地快速增加（1.1万km ²/a）,林地和草地大幅减少。2003-2015年耕地增速趋缓（0.3万km ²/a）,林地和草地有一定恢复,裸地和水体持续减少,城镇用地持续增长。耕地共增加12.3万km ²,林地和草地分别减少4.0万km ²和2.3万km ²,且集中于哈萨克斯坦中北部。裸地减少3.5万km ²,集中于哈萨克斯坦西南部,水体减少3.1万km ²,集中在咸海湖泊。乌兹别克斯坦耕地减少、裸地增加,吉尔吉斯斯坦、塔吉克斯坦和土库曼斯坦土地覆盖变化幅度较小;② 中亚五国蒸散发变化与土地覆盖格局基本一致。蒸散发总体呈增加态势（6 mm/a）,1992-2003年快速增加（11.3 mm/a）,2003-2015年缓慢上升（2.4 mm/a）。中亚五国年蒸散发达到276.8 mm,东南部的吉尔吉斯斯坦（347.3 mm）和塔吉克斯坦（302.9 mm）最高,中北部的哈萨克斯坦（297.9 mm）次之,西南部的乌兹别克斯坦（211.0 mm）和土库曼斯坦（150.0 mm）最低;③ 中亚五国蒸散耗水结构受耕地面积大小的影响。中亚五国耕地蒸散耗水的贡献由24.7%增至27.9%,土库曼斯坦耕地蒸散耗水仅占本国的11%,其他国家均超过25%。草地、林地和裸地的蒸散耗水贡献降低,但哈萨克斯坦、吉尔吉斯斯坦和塔吉克斯坦仍以草地和林地蒸散耗水为主（≥ 50%）,土库曼斯坦（61.3%）和乌兹别克斯坦（46.4%）的裸地蒸散耗水占绝对优势。本文明确了中亚五国土地覆盖连续动态变化过程,细化各国土地覆盖与蒸散发特征及差异,增强对土地覆盖与蒸散发现状的认识,可为水土资源管理和生态环境保护提供数据参考。