Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy

Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample).     

长岛县海洋产业结构优化研究

21世纪是海洋的世纪,科学利用海洋资源、发展海洋经济是实现人类社会可持续发展的重要途径。海岛地区,要在新一轮竞争中抢占发展先机、实现新的跨越,必须加快产业结构调整,推动产业转型提质增效。对此,以长岛为例,对海洋产业结构优化进行了专题研究。     

20世纪40年代初以来中国大陆沿海主要海湾形态变化

受气候变化和人类活动的影响,中国海岸带正在经历各种剧烈的变化,海湾形态变化是其中的一个重要方面.基于地形图资料与遥感影像提取20世纪40年代初至2014年7个时相的中国大陆沿海主要海湾的空间信息,进而分析海湾岸线类型结构,开发利用程度和空间位置的变化特征,以及海湾面积,形状和重心分布的变化特征.结果表明,20世纪40年代初以来,中国大陆沿海主要海湾的形态变化显著且复杂,主要体现为:海湾岸线的结构变化显著,自然岸线的长度和比例急剧减少;海湾岸线的开发利用程度持续增强;海湾岸线普遍背陆向海运动;海湾面积普遍大幅萎缩;海湾形状总体趋向复杂但个体间的差异在缩小;海湾重心分布位置普遍背陆向海迁移;海湾变化具有显著的时空差异性等.总的来说,以围填海为主的人类活动是导致海湾发生上述变化特征的主要原因.通过研究,指出应该对中国的海湾进行功能定位划分和分类管理,通过强化以海湾为基本单元的管理,促进中国海岸带综合管理能力的提高和管理目标的实现.     

二维地震勘探在新疆准东煤田梧桐窝子煤矿区煤层对比中的应用

通过人工合成地震记录,了解煤层反射波形成机理,在常规地震时间剖面中确定标准反射波,根据标准反射波连续性、时间间距、动力学特征,在新疆准东煤田梧桐窝子煤矿区煤层对比中取得了较好的应用效果,通过实践证明利用地震资料进行煤层对比方法是可行的,可以在复杂地区提高煤层对比的可靠性。     

地震勘探技术在煤炭勘查中的应用与展望

地震勘探作技术为一种重要的勘探方法,可以经济、有效的发现资源和解决资源开采过程中遇到的构造、地层、岩性等问题。煤炭地震勘探发展过程中地震野外数据采集、地震数据处理和地震解释都取得了重大成就,目前煤炭地震勘探正进一步向高信噪比、高分辨率、高保真度、高清晰度、高精度、定量分析的方向发展,未来也必将在煤炭资源发现和矿井隐蔽致灾因素的探测中发挥重要作用。     

土地集约利用数据库实时更新系统的研制

针对PDA产品信息采集不全、屏幕小不易图形编辑、维护保管难及数据库更新不及时等问题,文章将更新数据的编辑、审核和更新入库功能移至服务器端。在系统结构设计、数据库设计以及功能设计等基础上,利用组件式GIS开发、空间数据拓扑分析、软件系统集成、地理建模等先进技术,对土地集约利用数据库实时更新系统进行开发,实现了土地集约利用评价数据库采集和更新内外业一体化,进而实现与"土地集约利用终端系统"的完美对接,为土地集约利用评价系统提供了实时、准确的数据源。     

胶东金翅岭金矿构造控矿规律及找矿预测

金翅岭金矿是胶东招远北部的一个典型石英脉型金矿,构造是金矿最为重要的控矿因素。在前人资料的基础上,综合分析了矿区构造控矿特征,总结了构造控矿规律:矿脉分支复合,表现为NE向矿脉产生SN,NNE向次级矿脉,NNE向矿脉产生NE向次级矿脉;矿体厚度与金品位呈负相关,深部次级矿脉群在P4脉下盘出现;矿脉侧伏角和倾伏向变化处矿体富集,表现为SW向侧伏的P4矿脉,矿体富集于-240 m,侧伏角变大,同时倾伏向由SW向转变为NW向的部位。最后建立了平面和剖面P4矿脉的波形函数,并对深部进行了预测。     

三角洲前缘厚层砂岩孔隙结构及微观渗流特征——以吴仓堡地区长6储层为例

依据薄片、压汞、扫描电镜、物性分析及油水驱替实验资料,对吴仓堡地区三角洲前缘亚相长6厚层砂岩储层的岩石学特征、孔渗特征、孔隙结构特征、成岩作用、微观渗流特征等进行深入研究,分析影响储层储集性能的主控因素。结果表明,受东北物源控制的长6厚层砂岩储层具有成分成熟度中等、结构成熟度较好的特点,储集空间主要为残余粒间孔和粒间溶孔、粒内溶孔,为典型中低孔、特低渗储集层;储层储集性能主要受沉积微相和成岩作用控制。对储层发育影响最大的成岩期位于中成岩A期,中等压实－粘土膜胶结残余粒间孔发育成岩相和弱压实-残余粒间孔+溶蚀孔隙发育成岩相是最有利储层发育的成岩相带。根据微观渗流特征,可划分出4种驱油类型,微观孔隙结构比宏观物性更能反映储层的本质特征。     

内蒙古中部红格尔图地区花岗岩的成因及构造背景——LA-ICP-MS锆石U-Pb年龄、地球化学的制约

内蒙古察右后旗红格尔图花岗岩岩体位于索伦缝合带以南,主要为正长花岗岩和二长花岗岩,富硅(70.44%~78.80%),富碱(7.46%~10.74%),贫镁、铁、钛等,A/CNK值在0.95~1.41之间,碱铝指数AKI值在0.68~0.97之间,碱度率AR值在3.30~6.68之间,为弱过铝质-过铝质类碱性系列花岗岩;稀土元素总量变化范围大,轻稀土元素富集,重稀土元素亏损,Eu呈负异常(δEu=0.03~0.89);富集高场强元素Th、U、Hf、Ta、Y等,亏损大离子亲石元素Sr、Ba、Eu等;高场强元素和值((Zr+Nb+Ce+Y)350×10~(-6))明显偏低,该岩体属于高分异I型花岗岩,形成于后造山(后碰撞)伸展构造环境。LA-ICP-MS锆石同位素测年,获得锆石~(206)Pb/~(238)U年龄加权平均值分别为267.2±1.4Ma、269.2±1.6Ma和272.1±1.2Ma,表明该岩体形成于中二叠世,因此研究区内两大板块碰撞缝合的时间应该至少早于该岩体的形成时代,即应该至少早于267.2~272.1Ma。     

Phylogeography of the pelagic fish Seriola lalandi at different scales: confirmation of inter-ocean population structure and evaluation of southern African genetic diversity

The study investigated the global and regional phylogeography of the yellowtail kingfish Seriola lalandi by examining genetic diversity and population genetic structure of this species at inter-and intra-ocean level and on a regional scale. DNA fragments of two mitochondrial genes, cytochrome b (Cytb) and cytochrome c oxidase subunit I (COI) and one nuclear gene, recombination activating gene 1 (RAG1), were sequenced to investigate the global-scale phylogeography of this species. The population genetic structure within the South Pacific, as well as along the South African coastline, was examined further using six microsatellite markers. Three distinct clades were identified for S. lalandi, which correspond with previously described subspecies of the North-East Pacific, North-West Pacific and the Southern Hemisphere. Within the latter, additional divergence was observed between the South Pacific and the South-East Atlantic regions. Divergence estimates were indicative of a Pacific origin for S. lalandi populations, because of Pleistocene vicariant events. Microsatellite analyses revealed overall significant genetic differentiation between South African and South Pacific samples. This corroborates recent findings on the global phylogeography of the species. No population differentiation was observed within South Africa, indicating high levels of gene flow.