An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.     

未定名矿物(Bi38CrO60)的矿物学研究

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.     

川西北倒三角形断块东部区域强震带形成机制与地震活动特征

川西北倒三角形断块东部区域地处青藏高原东部边缘地带,地跨川西北高原及其与四川盆地过渡带的高山峡谷区,属我国著名的南北向地震带的中段,因其特定的大地构造环境和强烈的现代地壳构造运动,导致其在强大的近东西向构造应力场的驱动和平卧“A”字型控震构造体系的控制下,沿两侧边界断裂向东强力楔入,于“构造急剧收口带”之西侧形成了一个近SN向地跨三大构造单元的强震带,强震沿该带有规律的往返迁移和重复发生,且地震活动强弱具有较明显的分形特征。     

Earthquake Disaster Management and Insurance

As one of the most powerful tools to reduce the earthquake loss, the Earthquake Disaster Management [EDM] and Insurance [EI] have been highlighted and have had a great progress in many countries in recent years. Earthquake disaster management includes a series of contents, such as earthquake hazard and risk analysis, vulnerability analysis of building and infrastructure, earthquake aware training, and building the emergency response system. EI, which has been included in EDM after this practice has been done for many years, include these contents: insurance model, financing. This paper presents the development of china in EDM and EI. The main contents include: (1) the statue and trend of earthquake disaster management and insurance in china; (2) the progresses and new methods about the seismic risk zonation and vulnerability analysis, and the future developing trend, the application of GIS in earthquake disaster assessment is introduced; (3) the way and illustration in building the earthquake disaster e     

数据分析法确定嶂山闸闸基渗透压力

闸基渗透压力是影响水闸闸室稳定的关键性因素。当水闸同时受到上下游水位差、基底承压水头、粘性土地基扬压力滞后等多重因素作用时 ,闸基渗透压力的估算就变得比较困难。通过对嶂山闸闸基历年实测渗透压力数据进行统计分析 ,初步揭示其基底渗透压力的变化规律 ,为该闸闸室稳定性分析提供依据。     

邯郸市西部岩溶地下水的利用与开发

根据区域内岩溶地下水供需水现状，特别是通过对岩溶地下水最新开采动态资料分析，认为邯郸市西部岩溶水区尚具有一定的开发潜力，并提出了解决岩溶山区(革命老区)人畜用水的可行性和拦蓄滞洪、人工补给的有效途径，为地方经济持续发展提供决策依据，也可为北方类似岩溶地区所借鉴。     

颗粒分析用量筒的规格标准和计量标定

文章讨论了国内外用于密度计法颗粒分析用量筒的计量标准的规定，提出了相应的建议和标定方法。     

2004欧洲X射线光谱分析会议

介绍了2004欧洲X射线光谱分析会议的简况和会议所讨论的热点问题。利用聚合毛细管X射线透镜进行微区分析是近期X射线领域最受关注的热点。     

Evolution of sand waves in the Messina Strait, Italy

In the present paper the morphodynamics of sand waves in the Messina Strait, Italy, is analysed by comparing data gathered during two different surveys carried out in 1991 and 2001, respectively. In particular, a morphometric analysis on the most recent data and a qualitative analysis of the differences between bottom bedform patterns, are carried out. At locations characterised by greater depths, only minor changes to the planimetric configuration of the field, i.e. crest orientation (which is seen to be orthogonal to the direction of net gross sand transport) and wave length are observed, while differences in wave length and crest direction are more evident in more shallow areas. On the other hand, wave height has significantly increased in the whole field. A possible explanation of such a change, based on the previsions of a theory which relates sand-wave growth and migration to the main components of the tidal ellipse, is provided.Responsible Editor: Jens Kappenberg     

GOCE Gravity Field Processing Strategy

A processing strategy and the corresponding software architecture for the processing of GOCE (Gravity field and steady-state Ocean Circulation Explorer) observables is presented and described, with the major objective to compute a high-accuracy, high-resolution spherical harmonic model of the Earth's gravity field. The combination of two numerical solution strategies, i.e. the rigorous solution of the corresponding large normal equation systems applying parallel processing (on a PC cluster) as the core solver, and the fast semianalytic approach as a quick-look gravity field analysis (QL-GFA) tool, is proposed. Such a method fusion benefits from the advantages of the individual components: the rigorous inversion of the system providing also the full variance-covariance information, and the quickness enabling the consecutive production of intermediate gravity field solutions, for the purpose to analyse partial and incomplete data sets and to derive a diagnosis of the performance of the GOCE measurement system. The functionality and operability of the individual components are demonstrated in the framework of a closed loop simulation, which is based on a realistic mission scenario both in terms of the orbit configuration and the coloured measuring noise. Special concern is given to the accuracy of the recovered coefficients, the numerical behaviour, the required computing time, and the particular role of the individual modules within the processing chain. In the case of the core solver, it is demonstrated that the assembling and rigorous solution of large normal equation systems can be handled by using Beowulf clusters within a reasonable computing time. The application of the quick-look tool to partial data sets with short-term data gaps is demonstrated on the basis of several case studies. Additionally, the spectral analysis of the residuals of the adjustment is presented as a valuable tool for the verification of the noise characteristics of the GOCE gradiometer.