Spatial patterns of groundwater‐lake exchange – implications for acid neutralization processes in an acid mine lake

Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m^‐2 d^‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m^‐2 d^‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g^‐1 d^‐1) compared to alternating sites (<220 nmol g^‐1 d^‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.     

冀中拗陷古潜山油田水化学研究

冀中拗陷油气田87%的储量产于海相碳酸盐岩古潜山中,在油气生成、运移、集聚和散失的过程中地下水起了重要作用。本文根据50个试样的水化学分析资料,运用对应分析方法对冀中拗陷古潜山油田水进行了分类并初步探讨了水化学成分演化与油气藏形成的关系。     

Rayleigh 阻尼作用下斜拉桥扭转振动

在侧向风力或侧向水平地源力作用下,斜拉桥容易发生扭转振动。本文采用非线性Rayleigh阴尼,它能反映在低速振动时有激发而加速振动,至一定高速后又衰减的完整振动过程。对非线性的统辖方程及定解条件,先使之无量纲化,再按非线性项的系数这个小参数展开未知函数,得到线性化的各级近似方程。把待求函数展成梁轴坐标的Fourier级数,其系数为待定的时间函数,应用Fourier级数的正交性,得到求解未知时间函数的二阶常微分方程,完全类似单自由度质点在线性粘滞性阻尼作用下的统辖方程,其解为已知。     

Coastal Massachusetts pond development: edaphic,climatic, and sea level impacts since deglaciation

Kettle ponds in the Cape Cod National Seashore in southeastern Massachusetts differ in their evolution due to depth of the original ice block, the clay content of outwash in their drainage basins, and their siting in relation to geomorphic changes caused by sea-level rise, barrier beach formation, and saltmarsh development. Stratigraphic records of microfossil, carbon isotope, and sediment changes also document late-glacial and Holocene climatic changes.The ponds are separated into 3 groups, each of which follow different development scenarios. Group I ponds date from the late-glacial. They formed in clay-rich outwash, have perched aquifers and continuous lake sediment deposition. The earliest pollen and macrofossil assemblages in Group I pond sediments suggest tundra and spruce-willow parklands before 12 000 yr B.P., boreal forest between 12 000 and 10 500 yr B.P., bog/heath initiation and expansion during the Younger Dryas between 11 000 and 10 000 yr B.P., northern conifer forest between 10 500 and 9500 yr B.P., and establishment of the Cape oak and pitch pine barrens vegetation after 9500 yr B.P. Sedimentation rate changes suggest lowered freshwater levels between 9000 and 5000 yr B.P. caused by decreased precipitation on the Atlantic Coastal Plain. Lake sediment deposition began in the middle Holocene in Group II ponds which formed in clay-poor outwash. These ponds date from about 6000-5000 yr B.P. In these ponds sediment deposition began as sea level rose and the freshwater lens intersected the dry basins. The basal radiocarbon dates of these ponds and stable carbon isotope analyses of the pond sediments suggest a sea-level curve for Cape Cod Bay. Holocene topographic changes in upland and the landscape surrounding the ponds is reconstructed for this coastal area.Group III ponds in the late Holocene landscape of the Provincelands dunes originated as interdunal bogs about 1000 yr B.P. and became ponds more recently as water-levels increased. Peat formation in the Provincelands reflects climatic changes evident on both sides of the Atlantic region.This is the 8th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

烃类微渗漏的地物波谱探测原理与方法研究

通过对新疆塔里木盆地北缘油气谱的实测和分析，结合烃类微渗漏理论，讨论油气信息的波谱特征和遥感直接探测的机理。运用遥感技术探测油气信息，一是探测烃类微渗漏产生的地表理化异常，二是直接探测渗漏运移到地表的烃类物质或土壤吸烃信息。在塔北试验区，烃类组分异常是最直接，最有意义的标志，２．３２－２．３６μｍ的烃类吸收双谷位置，被确定为塔北地区油气遥感探测波段。     

台风成因与地壳运动关系初探

本文从台风和世界上大多数热带气旋的密集生成区与板块相互作用的地壳剧烈活动区相吻合这一现象出发,认为当今台风成因的研究之所以遇到困难的原因之一,就是忽略了剧烈的地壳运动所产生的热流通过海洋这一特殊水解质对其上方大气所产生的影响。     

对饱和粘性土渗透规律的新认识及其应用

通过实验，对饱和粘性土的渗透规律进行研究，得到几点新认识。利用此认识建立了饱和粘性土越流补给量的计算公式，并在实际应用中得到验证。     

A new theoretical solution of the effect of atmospheric pressure on water level

Based on the partial differential equation governing the effect of atmospheric pressure on water level of confined well, deriving the boundary condition and considering the seepage water between well and aquifer, the author obtained the analytical solution of water level change in time domain under the action of an atmospheric pressure history with the Laplace transform method. This solution is composed of two terms:stable and retarded terms. The stable term is the multiplication of barometric efficiency and simultaneous atmospheric pressure, and it implies the value of water level after infinite time when the atmospheric pressure is a constant from the time in question. The retarded term is the transient process due to the time lag of water exchange between well and aquifer. From the solution, it is obtained that the interference of atmospheric pressure on water level is the integral superimposition of the contribution of all atmospheric pressure changes before the time in question. So that, we further found out the response function of pulsive atmospheric pressure history. Calculation shows: (1) The pulsive response function starts from zero and tends to a steady value, which is proportional to the barometric efficiency, when the time tends to infinity; (2) The retarded time depends on the mechanical property of aquifer and the radius of well. The larger the seepage coefficient, the smaller the radius of well and the thicker the aquifer, then the shorter the retarded time gets. This solution can be used as the theoretical basis for further analysis of the atmospheric effect and practical correcting method in the future.     

Conservation laws of wave action and potential enstrophy for rossby waves in a stratified atmosphere

The purpose of this article is to discuss the evolution of wave energy, enstrophy and action for atmospheric Rossby waves in a variable mean flow. The presentation is theoretical, but does not represent original research; rather, it is pedagogic in nature. The work of a number of people has been drawn together into a unified account, with much of the algebra implicit in previous work made explicit here. The central results are that wave energy is conserved only when there are no spatial variations in the mean flow, and wave action is conserved even in the presence of such variations as long as they are not in the longitudinal direction. Finally, wave enstrophy is conserved in the presence of arbitrary (slow) mean flow variations.