海底玄武岩中次生组分HCl溶解实验研究

次生组分沉淀是海底岩石中普遍存在的现象,次生组分去除是减少次生组分干扰、获取海底岩石高质量数据的关键。选择西太平洋麦哲伦海山区MK海山相对新鲜的玄武岩作为研究对象,经研磨、均一化后将粉末样品分为49份,其中48份分别以0.25,0.50,1.00,1.50,2.00,2.50 mol/L六种浓度的足量HCl溶解0.5,1,2,4,8,16,32和64 h后,选取溶解残渣测定主要氧化物和特征微量元素质量分数,确定HCl溶解法在去除次生组分的同时不会对海底新鲜玄武岩中原生组分造成影响的HCl浓度-时间组合。结果表明,在HCl浓度为1.00～2.50 mol/L,溶解时间为0.5～2 h的12种HCl浓度-时间组合均可保证海底玄武岩中原生组分的安全,并可有效去除次生组分。综合海底蚀变玄武岩次生组分去除实验研究,推荐使用1.00～2.00 mol/L HCl,溶解时间在0.5～1 h的实验方案。     

下扬子地区幕府山组陆缘海-台地黑色细粒沉积岩系沉积学和孔隙结构特征

黑色细粒沉积岩系沉积学和孔隙结构研究对于沉积环境恢复、页岩气储层评价和有利储层预测具有重要意义.利用下扬子地区最新完钻的XYZ-1钻井资料,综合钻井岩心、岩石薄片、XRD分析、氩离子-场扫描电镜等手段,开展幕府山组细粒沉积岩系的沉积学和孔隙结构研究.结果表明,幕府山组岩性组成以块状、纹层状深色(碳质)泥岩、浅灰色纹层状...     

复合体系有机气体氧化生成二次有机气溶胶研究进展

生物源与人为源有机气体氧化形成的二次有机气溶胶(SOA)对气候变化和人类健康具有重要影响。SOA的产生与其前体物研究已取得了一些进展,但由于有机气体之间存在复合相互作用以及SOA形成机制复杂,目前对不同有机气体混合体系中SOA的形成认知还比较匮乏。因此,深入了解有机气体多源、复杂的相互作用,摸清有机气体的大气氧化机制、SOA的形成及影响等对深入理解真实大气有机气体化学演变具有指导意义。本文旨在了解复合体系有机气体氧化生成SOA的相关研究进展。一方面总结了复合体系有机气体产生SOA质量浓度、产率、成分、挥发性、光学性质等的变化,侧重于实验室复合体系有机气体氧化对SOA形成的多重影响以及SOA组成元素、分子构成的变化特征,并总结了目前实验室基于模型对复合体系SOA生成的模拟研究和拟合情况;另一方面探究了环境因素,如相对湿度(RH)、温度(T)以及无机气体,如氮氧化物(NO_x)、二氧化硫(SO₂)、氨气(NH₃)等对复合体系有机气体形成SOA的影响。     

三峡库首区重点断裂围限区蓄水的加卸载效应

通过对蓄水前后三峡库首区构造应力场进行三维数值模拟发现,相对于蓄水前,蓄水至135 m水位时,官渡口断裂-马鹿池断裂-牛口断裂围限区、秭归地理中心和九湾溪断裂带,出现了4个主应力下降区和共轭的主应力增长区,形成了差应力场;175 m水位与135 m水位相比,局部差应力场呈现逆向变化,即形成了加载效应与卸载效应的交替过程。这一过程,可能是水库诱发地震的诱震(或触震)因素。     

不同水沙条件下黄河下游二级悬河的发展过程

以大量实测横断面资料为基础,研究了1973~1997年不同水沙过程对黄河下游二级悬河形成过程的影响。发现花园口至高村河段二级悬河集中形成于1985~1997年的枯水阶段。高村以下河段二级悬河的形成可分两个阶段,1973~1985年大水条件下是冲刷主槽和淤积滩地的时期,但是由于泥沙主要堆积在靠近滩唇的部位,造成河床横比降增大;1985~1997年枯水条件下泥沙在主槽中大量淤积,导致二级悬河的形势更加严重。生产堤限制了泥沙的堆积范围,导致生产堤内滩地平均高程增长速度明显快于生产堤外滩地平均高程增长速度,生产堤距较窄的河段生产堤内滩地平均高程增长速度较快,显示了生产堤对二级悬河的发展有促进作用。     

电缆地层测试最小测试时间的确定

电缆地层测试器是重要的地层评价仪器,可以测量地层压力和渗透率、识别流体类型、确定油水界面.然而在低孔低渗地层中,由于泥饼的封闭性差而造成的地层增压现象,致使无法测量到地层真实压力.同时由于长时间的测试,容易将仪器卡在地层中而造成事故.本文提出一种确定电缆地层测试最小测试时间的方法.利用有限元方法计算泥饼和原状地层中的压力分布情况,求取泥浆柱静压力的影响半径,继而确定储层的最小测试时间,并且针对渗透性不同的储层给出了最小测试时间的范围.电缆地层测试最小测试时间的确定,可以确保电缆地层测试器在低孔低渗储层中测量到地层的真实信息,减小由于测量时间过长而引起工程事故发生率.     

白云岩成因相关问题及主要形成模式

在综述白云岩成因研究历程和最新成果的基础上,总结阐述了与之相关的4个方面的问题:①尽管白云岩原生沉淀与次生交代成因分歧依旧,但越来越多的证据表明白云岩的形成以次生交代为主;②白云石难以直接沉淀的原因是受结晶动力学条件制约,而非热力学因素;③控制次生交代强度和规模的关键条件是富Mg流体的来源及其量的大小;④微生物活动很可能有助于白云岩的形成。关于白云岩化模式,其核心是构建富Mg流体与先成钙质碳酸盐岩相互作用的条件与场所,其中浓缩正常海水模式、萨布哈模式、混合水模式和埋藏白云岩化模式等具有一定的普遍性。理清白云岩成因问题,对于认识以白云岩及其相关的碳酸盐岩为储层的油气勘探工作尤为重要。     

中国地震次生地质灾害危险性评价

地震次生地质灾害主要指地震引起的崩塌、滑坡、塌陷、地裂缝、砂土液化。震级大于5级、烈度超过Ⅵ度的地震可能引发不同程度的地质灾害,震级和烈度越高,次生地质灾害越严重。本文根据中国历史地震次生地质灾害活动程度及发生条件,以地(市、区、盟)为单元,进行了危险性评价:高度和中度危险区主要分布在中国中部的陕甘宁川渝滇藏地区,形成一个大致NE向高危险带,其余大部分地区为轻度危险区。      

渤海大型底栖动物次级生产力的初步研究

1998年 9月和 1999年 4月分别对渤海 2 0个站进行了大型底栖动物两个航次的调查取样。整个研究海域大型底栖动物年次级生产力平均值为 6 .4 9g(AFDW) /(m2 · a) ,其中渤海海峡以东海域较高 ,为 12 .5 9g(AFDW) /(m2· a) ;渤海中部为 4 .4 6 g(AFDW) /(m2· a) ,渤海大型底栖动物年平均 P/B为 0 .82     

Theoretical aspects of cap-rock and fault seals for single- and two-phase hydrocarbon columns

Cap-rock seals can be divided genetically into those that fail by capillary leakage (membrane seals) and those whose capillary entry pressures are so high that seal failure preferentially occurs by fracturing and/or wedging open of faults (hydraulic seals). A given membrane seal can trap a larger oil column than gas column at shallow depths, but below a critical depth (interval), gas is more easily sealed than oil. This critical depth increases with lower API gravity, lower oil GOR and overpressured conditions (for the gas phase). These observations arise from a series of modelling studies of membrane sealing and can be conveniently represented using pressure/ depth (P/D) profiles through sealed hydrocarbon columns. P/D diagrams have been applied to the more complex situation of the membrane sealing of a gas cap underlain by an oil rim; at seal capacity, such a two-phase column will be always greater than if only oil or gas occurs below the seal.These conclusions contrast with those for hydraulic seals where the seal capacity to oil always exceeds that for gas. Moreover, a trapped two-phase column, at hydraulic seal capacity will be less than the maximum-allowed oil-only column, but more than the maximum gas-only column. Unlike membrane seals, hydraulic seal capacity should be directly related to cap-rock thickness, in addition to the magnitude of the minimum effective stress in the sealing layer and the degree of overpressure development in the sequence as a whole.Fault-related seals are effectively analogous to membrane cap-rocks which have been tilted to the angle of the fault plane. Consequently, all of the above conclusions derived for membrane cap-rocks apply to both sealing faults sensu stricto (fault plane itself seals) and juxtaposition faults (hydrocarbon trapped laterally against a juxtaposed sealing unit). The maximum-allowed two-phase column trapped by a sealing fault is greater than for equivalent oil-only and gas-only columns, but less than that predicted for a horizontal membrane cap-rock under similar conditions. Where a two-phase column is present on both sides of a sealing fault (which is at two-phase seal capacity), a deeper oil/water contact (OWC) in one fault block is associated with a deeper gas/oil contact (GOC) compared with the adjacent fault block. If the fault seal is discontinuous in the gas leg, however, the deeper OWC is accompanied by a shallower GOC, whereas a break in the fault seal in the oil leg results in a common OWC in both fault blocks, even though separate GOC's exist. Schematic P/D profiles are provided for each of the above situations from which a series of fundamental equations governing single- and two-phase cap-rock and fault seal capacities can be derived. These relationships may have significant implications for exploration prospect appraisal exercises where more meaningful estimates of differential seal capacities can be made.The membrane sealing theory developed herein assumes that all reservoirs and seals are water-wet and no hydrodynamic flow exists. The conclusions on membrane seal capacity place constraints on the migration efficiency of gas along low-permeabiligy paths at depth where fracturing, wedging open of faults and/or diffusion process may be more important. Contrary to previous assertions, it is speculated that leakage of hydrocarbons through membrane seals occurs in distinct pulses such that the seal is at or near the theoretically calculated seal capacity, once this has been initially attained.Finally, the developed seal theory and P/D profile concepts are applied to a series of development geological problems including the effects of differential depletion, and degree of aquifer support, on sealing fault leakage, and the evaluation of barriers to vertical cross-flow using RFT profiles through depleted reservoirs. It is shown that imbibition processes and dynamic effects related to active cross-flow across such barriers often preclude quantitative analysis and solution of these problems for which simulation studies are usually required.