Petrophysical characterisation of tight sandstone gas reservoirs using nuclear magnetic resonance: a case study of the upper Paleozoic strata in the Kangning area,eastern margin of the Ordos Basin,China

Residual and movable porosity are significant parameters for characterising petrophysical properties, especially in tight reservoirs. Eight tight sandstone samples from the upper Paleozoic gas-bearing strata in the Kangning area, from the eastern margin of the Ordos Basin, were analysed using nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), petrography, and porosity and permeability tests. The lithology and pore types were identified and classified using petrography and SEM. The residual and movable porosity were obtained with NMR. In addition, NMR was used to visualise pore structure and pore size distribution. The results suggest that the upper Paleozoic sandstones in the study area mainly comprise feldspathic litharenite and litharenite. The sandstone porosity and permeability are low, with means of 5.9% and 0.549 mD, respectively. Four pore types exist in the tight sandstones: residual primary pores, grain dissolution pores, micropores (clay-dominated) and microfractures. The T₂ spectra under water-saturated conditions correlate with pore size and can be used to distinguish small and large pores based on the transverse relaxation time cutoff value of 10 ms, which corresponds to a pore diameter of 0.232 μm. Small pores account for 72% of the pores in the tight sandstones. The continuous bimodal T₂ spectra suggest good connectivity between small and large pores, despite the low porosity and permeability. In this study, the movable porosity of the major tight sandstone gas reservoirs is higher than the residual porosity, which confirms the effective evaluation of movable porosity to tight sandstone reservoirs, based on NMR experiments.     

冻融循环对不同孔隙率页岩相似材料影响的试验研究

基于地质力学模型试验的相似理论,针对寒区岩体工程,分别制作了5种不同孔隙率的页岩相似材料,进行冻融循环试验,探究不同孔隙率的页岩相似材料在冻融前后,其主要物理力学参数的变化规律。试验研究表明：在冻融循环后,页岩相似材料的单轴抗压强度、三轴抗压强度、弹性模量、粘聚力、内摩擦角有不同程度的减小,孔隙率、泊松比有不同程度的增大。页岩相似材料的物理力学参数受冻融循环的影响随孔隙率的增大先增大后减小,孔隙率处于9.4%~13.6%时,受冻融循环影响最大;孔隙率处于5.8%~9.4%时,受冻融循环的影响随孔隙率的增大有增大的趋势;孔隙率处于13.9%~19.1%时,受冻融循环的影响随孔隙率的增大有减小的趋势。研究结果可以为西部寒区的岩土工程建设和减灾提供相关的科学依据。     

长春地区粉质黏土导热系数与其物性参数相关性研究

为研究导热系数与影响因素之间的相关关系,建立导热系数的推算公式,以长春地区粉质黏土为研究对象,对原状土样的导热系数与其物理参数之间的相关性进行回归分析。制作9个重塑土样,测其相关的参数值,以验证回归方程的适用性。结果表明,回归分析建立导热系数与2个物理参数之间的关系式不成立;考虑天然密度、含水率和孔隙度为自变量,其分别对应的相关性系数T检验显著值(Sig)都0. 05,复决定系数为0. 886,建立的回归方程成立,自变量能准确解释因变量的变化,且含水率与导热系数呈负相关,天然密度和孔隙度呈正相关。重塑土样相关参数代入回归方程得到的导热系数值与实验实测值之间相对误差低于4%,验证了该回归方程的普遍性和适用性。     

碳酸盐岩铸体薄片面孔自动提取研究

岩石孔隙是储层储集油气的重要场所,通过铸体薄片进行岩石孔隙结构分析对储层质量评价具有重要意义。碳酸盐岩孔隙结构较为复杂,铸体薄片图像中存在大量噪声和干扰因素,致使常规方法面孔提取效果不佳,因此本文引入一种多阈值铸体薄片面孔自动提取方法（ctsPore方法）进行孔隙区域提取和面孔率估计,方法综合利用HSV色彩空间中不同参数提取孔隙区域。本文针对碳酸盐岩储层的特点确定了一套ctsPore阈值参数,以解决溶蚀孔与噪声易混淆的问题。实验以伊拉克A油田中新统 Asmari组A段碳酸盐储层为例对所使用算法进行了效果检验。算法精度和效率分析实验表明,基于ctsPore方法的碳酸盐岩铸体薄片面孔提取误差小于0.24%。全井段铸体薄片分析结果表明,A段储层面孔率范围主要分布在6%~8%,储层较为致密,从上到下A1~A3小层的储层平均面孔率分别为6. 9%、11.7%、5.4%,与储层物性、沉积微相和岩性等纵向分布规律较为吻合。     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

四川盐源模范村喜马拉雅期斑岩铜矿床地质特征

文章通过野外地质观察,结合岩矿鉴定、化学分析、稳定同位素测定、稀土元素分析、成岩成矿同位素年龄测定、包裹体测温及成分等的研究,表明四川盐源模范村矿床具有典型斑岩铜矿的特征。成岩的多期次构成复式岩体,断裂构造控制的隐爆碎裂岩筒为成矿提供了通道和沉积场所。多期次成矿,特别是次生富集作用形成了中型规模的Ⅰ号矿体,影响次生富集带发育的F7断裂带起了重要作用。模范村矿床确系典型的斑岩铜矿,但又具独自的成矿特征。     

动机、成本、风险：家长视角下研学旅游产品价值感知研究

以中小学生自然教育研学旅游作为具体情境,基于539份家长问卷数据阐释研学旅游动机与价值感知之间的关系,并通过成本感知和风险感知探讨其内在机制和边界条件。结果表明,家长感知的研学旅游动机越强烈,越容易感知到研学旅游产品所传递的价值,验证了研学旅游情境下动机对价值感知的积极影响,也形成了对动机与价值之间关系研究的理论补充。并且,这一动机除了直接作用于价值感知外,还会通过成本感知的部分中介作用影响价值感知,揭示了中国家长对于教育价值的重视会削弱其对“利失”的感知。此外,进一步验证了风险感知的积极影响,即家长感知研学旅游的不确定性水平越高,动机对价值感知的积极影响越明显,且会抑制成本感知对价值感知的负向作用,但风险感知水平达到一定高度时,其对成本感知与价值感知间的抑制作用将不显著。因此,面向需求设计打造产品,突出产品价值、加大宣传营销力度、把控活动安全、合理制定价格,获取家长群体的认同接受,将是研学旅游进一步拓展市场的重要考量。     

横向沙丘背风侧沙粒风蚀起动的风洞模拟

通过风洞实验,探讨了横向沙丘背风侧“二次流”的沉积学和形态-动力学意义。在不同迎风坡坡度的横向沙丘模型背风侧,我们观测了不同位置沙粒的起动风速以及在临界状态下沙粒的运动特征。结果表明,沙丘背风侧的颗粒起动风速不仅与其距沙丘顶部的距离有关,也与沙丘迎风坡坡度有密切关系。根据沙丘背风侧颗粒运动特征,可以将其划分为向后运动区域、晃动或摆动区域以及向前运动区域,产生这一现象的原因是在沙丘背风坡气流分离、反向涡和气流重新辐合共同作用的结果。在所有的观测结果中,迎风坡坡度为15°的沙丘具有最大的沙粒起动风速和最远的气流重新辐合距离,其原因尚需进一步研究。     

论直流激发极化法的视电阻率参数

直流激发极化法,计算视电阻率的一次场采集于供电方波的末端时间,从而包含了被激发形成的二次场。在高极化率地质体上,得到的视电阻率将削弱其低阻特性或放大高阻特性。为此,建议在野外工作中,应对所采集的一次场作适当的处理后,再计算视电阻率,以降低这种影响。     

Ex situ cultivation of Aplysinaaerophoba close to in situ conditions: ecological, biochemical and histological aspects

Sponges provide the largest number of biologically active natural products known from the marine environment and continue to be a very well studied phylum of marine fauna. The Mediterranean sponge Aplysina aerophoba accumulates brominated isoxazoline alkaloids such as Aplysinamisin-1, Aerophobin-2, Isofistularin-3 and the biotransformation product Aeroplysinin-1, which possesses, for example, antibiotic and cytotoxic properties. Until now, it is still being discussed which organisms – the sponge itself or associated microorganisms – are responsible for metabolite production. For cultivating Aplysina individuals under ex situ conditions, we surveyed relevant ecological factors in situ and controlled them in our aquarium system. We maintained A. aerophoba for more than 9 months and analysed changes of metabolite content and composition, microbial association as well as morphology in situ and ex situ under different light exposure. Although sponges showed slight reduction during maintenance, ex situ cultivation similar to in situ conditions provides a promising method to keep sponges and obtain their bioactive metabolites.