Inorganic arsenic speciation in the waters of the Penzé estuary (NW France): Seasonal variations and fluxes to the coastal area

Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.     

基于迁移学习方法的山东冷云冰晶特征分布研究

为分析冷云中冰晶的分布特征,揭示冰晶增长演变机制,根据冰晶形状和尺度特征分为8类并进行标注,同时标注1类隔断栏进行数据质量控制,将9类标签图像整合并建立图像集,利用迁移学习VGGNet16方法进行识别训练,经训练模型分类准确率达98%。将模型应用到秋季冷云冰晶特征研究中,选取3次积层混合云和3次层状云降水过程,分析冰晶形状在不同温度区间的占比及冰晶谱变化特征,结果表明,温度通过影响冰晶基面与棱面的比值来决定冰晶初始形状分布,相同温度区间积层混合云内球状冰晶和线型冰晶占比高于层状云,低于-12℃后各类冰晶占比相对固定;积层混合云内线型冰晶直径集中在300~800 μm,冰晶谱呈多峰分布,聚合体直径大于600 μm,冰晶谱首尾两端浓度相当,球状冰晶直径集中在120～300 μm,冰晶谱呈单调下降趋势。     

辽宁省霾天气季节变化特征及其主导因子分析

利用辽宁省51个地面气象观测站的能见度、均一化相对湿度和天气现象资料,采用最优距离法和固定比例法对能见度资料进行一致性处理,重建了1961—2020年的辽宁省逐日霾资料,并利用该资料对辽宁省年和四季霾日时空变化特征和主导因子进行分析。结果表明,1961—2020年辽宁省平均年霾日呈显著增加趋势[2.1 d·(10 a)^-1],但2015年以来霾日显著减少;空间上,年和四季霾日呈现一致的分布特征,均存在1个高值中心(沈阳)和2个副高值中心(北票和锦州),年平均霾日分别为139、52、46 d,辽东和辽西山区为霾日低发区,年平均霾日在20 d以内。风向和风速是霾日形成的重要气象因子,西南偏南风增加带来的暖湿气流对春季、夏季和秋季霾日的形成贡献较大,北风的减少则对冬季霾日的形成贡献较大。霾发生时辽宁省春季、夏季和秋季发生西南偏南风的频率分别由11.4%、12.1%和8.0%增加至15.8%、19.8%和13.5%,冬季则表现为北风发生频率的减少和静风发生频率的增加;霾发生时四季风速均较平均状况偏小,说明小风有利于霾的形成。辽宁省霾长期演变受到污染物排放、风力因子和环境政...     

地磁Z分量低点时间季节性变化研究

通过小波分析和频谱分析,发现Z分量低点时间的小波变换结果曲线(α=6)明显地随节气而变化;对地磁Z分量低点时间季节性变化进行了初步的比较分析.     

季节性冻结滞水促滑效应——滑坡发育的一种新因素

在综合分析西北季节性冻土地区滑坡发生时间规律和危险斜坡变形动态规律的基础上，提出季节性冻融作用产生的冻结滞水效应可使斜坡区地下水富集，土体软化范围扩大瞌 水压力增大，是本区滑坡发育的一种重要外动力因素，并对其作用机理和发生条件进行了论述。     

层状地基中空沟对交通荷载的竖向隔振分析

空沟是一种常用的连续隔振屏障,可以有效地降低人工振动。以位移为变量的二维格子法在波动问题计算中具有良好的适应性、高效性,兼备有限元与差分法的一些优点,应用该法针对层状地基中作用于路堤上的交通荷载引起振动的空沟竖向隔振问题进行了参数研究,分别考虑了上软下硬地基和上硬下软地基两种情况。研究结果表明：空沟宽度对隔振效果的影响较小;空沟深度与空沟的位置是影响隔振效果的关键因素,它们相互关联,其取值应综合考虑;在上述两类层状地基中,若空沟深度与上层土的厚度接近或相等均对竖向隔振不利;路堤高度越大对竖向隔振效果越不利。     

白垩纪快速气候变化研究新进展——温室世界中的冰川证据

白垩纪被认为是两极无冰的典型温室气候时期,但近年来对于白垩纪存在短暂冰川甚至是极地冰盖的猜想引起了越来越多的关注。根据前人提出的冰川或气候变冷证据,如冰川遗迹、全球海平面快速下降事件以及δ18O正偏事件等,总结了白垩纪可能存在冰川的时期,包括Berriasian Valanginian之间、Valanginian晚期、Barremiana期、Aptian Albian之交、Albian Cenomanian之交、Cenomanian中期和末期、Turonian中期、Coniacian中期、Santonian早期、Campanian晚期、Campanian Maastrichtian之交和Maastrichtian末期等。对这些证据的有效性进行详细的讨论,同时也对白垩纪冰川的可能成因进行探讨。笔者认为,白垩纪即便存在冰川,也是小规模、短暂地存在,因此,精确的年代学约束是进行白垩纪冰川研究的前提;米兰科维奇旋回控制下的气候波动是白垩纪形成短暂冰川的可能成因。     

岩溶地面塌陷三机理理论及其应用

为了给岩溶地面塌陷预测、监测、防治和应急措施提供理论依据,全面总结了岩溶地面塌陷的发育规律,认为岩溶、土体和诱发因素是岩溶地面塌陷的三要素。岩溶为土体丧失提供通道和储藏空间。土的工程地质性质决定了土体塌陷方式：“黏土块”坍塌、砂颗粒漏失、软弱土流失;土体塌陷方式决定了土体塌陷机理;据土体塌陷方式提出了由“土洞型塌陷”“沙漏型塌陷”和“泥流型塌陷”构成的岩溶地面塌陷三机理理论：黏性土和密实砂性土层中,在外力作用下,土洞顶板拱效应失效而产生的地面塌陷现象称为土洞型塌陷;由于诱发因素的触发导致可溶岩上方松散砂层中砂颗粒漏失而产生的地面塌陷现象称为沙漏型塌陷;可溶岩上方软弱土体在外力作用下向可溶岩中流失而产生的地面塌陷现象称为泥流型塌陷。三机理理论关注土体塌陷方式,既解释了岩溶地面塌陷现象,更回答了土体“如何塌”的问题。诱发因素是塌陷的外部影响因素,不是塌陷机理的构成要素;诱发因素产生作用力;作用力改变土颗粒运动状态,使土颗粒由“静止→运动”,土体由“稳定→塌陷”。依据三机理理论,提出了岩溶地面塌陷综合地质预测方法,建立了基于三个塌陷机理的土体塌陷确定性预测模型,系统总结了岩溶地面塌陷监测、防治和应急措施方法,形成了从理论到实践的、完整的岩溶地面塌陷思想体系。     

Ice-core records of global climate and environment changes

Precipitation accumulating on the Greenland and Antarctic ice sheets records several key parameters (temperature, accumulation, composition of atmospheric gases and aerosols) of primary interest for documenting the past global environment over recent climatic cycles and the chemistry of the preindustrial atmosphere. Several deep ice cores from Antarctica and Greenland have been studied over the last fifteen years. In both hemispheres, temperature records (based on stable isotope measurements in water) show the succession of glacial and interglacial periods. However, detailed features of the climatic stages are not identical in Antarctica and in Greenland. A tight link between global climate and greenhouse gas concentrations was discovered, CO₂ and CH₄ concentrations being lower in glacial conditions by about 80 and 0.3 ppmv, respectively, with respect to their pre-industrial levels of 280 and 0.65 ppmv. Coldest stages are also characterized by higher sea-salt and crustal aerosol concentrations. In Greenland, contrary to Antarctica, ice-age ice is alkaline. Gas-derived aerosol (in particular, sulfate) concentrations are generally higher for glacial periods, but not similar in both the hemispheres. Marine and continental biomass-related species are significant in Antarctica and Greenland ice, respectively. Finally, the growing impact of anthropogenic activities on the atmospheric composition is well recorded in both polar regions for long-lived compounds (in particular greenhouse gases), but mostly in Greenland for short-lived pollutants.