Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

无人机航空伽马能谱数据处理中大气氡的修正

介绍了无人机航空伽马能谱数据处理中大气氡修正的一种方法——能谱比法的原理与方法、数据处理过程及其在无人机航空伽马能谱数据处理中的应用。使用该方法对喀什地区的无人机航空伽马能谱进行修正,修正后的航放U较好地反映了该区的地质情况,可以应用到生产实践中去。     

微震监测系统标定信号的应用

徐州矿务集团有限公司三河尖煤矿建立了覆盖全矿井的KZ-1型微震监测系统,通过地面监测主机向井下各测站发时间同步校时信号,用GPS秒号起始去同步各个测站下位机时钟,保证了各测站之间相对时间精确度.KZ-1型微震监测系统的拾震器设置了双换能器,且各有一个独立的磁回路,通过地面监测主机向拾震器标定换能器发标定指令信号,信号检测换能器再将输出信号上传至监测主机,实现了即时定量标定.标定信号的应用使KZ-1型微震监测系统具备整个系统检测功能,包括灵敏度、频响特征以及各测站的时间同步误差.     

基于GRACE卫星测量得到的中国及其周边地区陆地水量变化

GRACE卫星成功开辟了空间大地测量对地观测的新途径。利用GRACE卫星得到的时变地球重力资料,分析估计了中国及其周边地区陆地水量的变化趋势,较为清晰地揭示了该地区季节性变化特征。进一步采用13点滑动平均的方法扣除了季节性变化,提取了4个特征区域(喜马拉雅南部,新疆与西藏及其周边的亚洲高山区域,中国华北、东北地区和中国南部地区)的陆地水量变化特征信息,这4个区域陆地水量的变化趋势分别为-12.7±0.7、-60.4±2.7、-12.5±0.5和6.6±0.9 km³/a。其中：喜马拉雅南部和亚洲高山区域陆地水量呈现明显的衰减趋势,与Matsuo和Heki模拟冰川质量损失源得到的结果较为一致;但近10年来亚洲高山区域西北部冰川加速融化趋势并不明显。中国华北、东北地区和南部地区水量变化比较复杂,具不稳定的变化趋势。     

Seasonal Forecasting for Climate Hazards: Prospects and Responses

One of the most promising developments for early warning of climate hazards is seasonal climate forecasting. Already forecasts are operational in many parts of the tropics and sub-tropics, particularly for droughts and floods associated with ENSO events. Prospects for further development of seasonal forecasting for a range of climatichazards are reviewed, illustrated with case studies in Africa, Australia, the U.S.A. and Europe. A critical evaluation of the utility of seasonal forecasts centres on vulnerability, communicationchannels, and effective responses. In contrast to short-term prediction, seasonal forecasts raise new issues of preparedness and the use of information.     

湿度效应及其对降水中δ18O季节分布的影响

提出了湿度效应的概念,即降水中稳定同位素比率与大气的温度露点差ΔT_d存在显著的正相关关系.对两个气候特征完全不同的取样站乌鲁木齐和昆明降水中δ¹⁸O与温度露点差之间的关系进行了分析,尽管两站的δ¹⁸O与ΔT_d的季节变化存在差异,但它们的湿度效应是显著的.利用稳定同位素动力分馏模型并根据500hPa月平均温度的季节分布对昆明站云中凝结物中δ¹⁸O进行了模拟,模拟的月平均δ¹⁸O与月平均温度的变化具有非常好的一致性,说明昆明站云中凝结物中的氧稳定同位素具有温度效应.这个结果与地面降水中氧稳定同位素的降水量效应截然不同.昆明站降水中δ¹⁸O一定程度上指示大气的干湿状况,同时也间接地指示降水量的多寡或季风的强弱.湿度效应的存在,影响降落雨滴中稳定同位素蒸发富集的强度以及雨滴与大气之间稳定同位素物质迁移的方向.它不仅改变降水中稳定同位素比率的大小,也改变其季节分布的特点.     

季节性冻结滞水促滑效应——滑坡发育的一种新因素

在综合分析西北季节性冻土地区滑坡发生时间规律和危险斜坡变形动态规律的基础上，提出季节性冻融作用产生的冻结滞水效应可使斜坡区地下水富集，土体软化范围扩大瞌 水压力增大，是本区滑坡发育的一种重要外动力因素，并对其作用机理和发生条件进行了论述。     

湖北清江和尚洞洞穴温度对气候变化的响应

对湖北清江流域和尚洞内、洞外气温进行同步高频监测,发现洞穴温度响应洞外气温的变化,但由于受到洞穴的“缓冲作用” ,由外及里的温度变化幅度变小,时间滞后,且响应的快慢具有明显的季节性。2003- 2008年度监测的数据统计表明,在150m 洞深处,洞内日温度的变化幅度仅0. 2℃ ,明显低于洞外气温变化幅度( 6. 9℃ ) ;同样,洞内夏、冬季节温差变化( 6. 9℃ )也小于洞外( 31. 8℃ )。比较洞内外温度的时间序列,发现日尺度上,洞内气温滞后洞外0～ 2小时,而在季节尺度上则滞后10～ 40天,其中降温阶段滞后小,升温阶段滞后大。此外,一年四季中,洞内温度对外界气温变化的响应呈现慢( 2- 4月)→快( 5- 7月)→较快( 8- 10月)→较慢( 11- 1月)的特点,可能与不同季节下洞穴“缓冲作用”的强弱变化有关。      

Belemnites from the lower middle Cenomanian of Hoppenstedt, northern Germany: significance and integrated correlation

The belemnite species Praeactinocamax primus (Arkhangelsky, 1912) and Belemnocamax boweri Crick, 1910 are described from the Cenomanian of the abandoned limestone quarry section of Hoppenstedt (Sachsen-Anhalt, northern Germany). They co-occur in the upper part of a prominent tripartite bioclastic limestone bed associated with the ammonite Acanthoceras rhotomagense, indicating the primus Event of the lower middle Cenomanian A. rhotomagense ammonite Zone. An integrated stratigraphical calibration including carbon stable isotope correlation to southern England suggests that the belemnite event horizon at Hoppenstedt occupies exactly the same chronostratigraphical position as elsewhere, highlighting the strictly isochronous character of the primus Event across northwestern Europe. Furthermore, stratigraphical gaps in the Hoppenstedt succession are evaluated.     

一种土壤氡浓度测量的校正方法及其应用

通过对土壤氡浓度测量校正模型的应用和分析,初步建立了根据残留气体的土壤氡浓度校正方法,并在实际应用中论证了方法的可参考性及实用性。