The effect of oil expulsion or retention on further thermal degradation of kerogen at the high maturity stage: A pyrolysis study of type II kerogen from Pingliang shale,China

High maturity oil and gas are usually generated after primary oil expulsion from source rocks, especially from oil prone type I/II kerogen. However, the detailed impacts of oil expulsion, or retention in source rock on further thermal degradation of kerogen at the high maturity stage remain unknown. In the present study, we collected an Ordovician Pingliang shale sample containing type II kerogen. The kerogens, which had previously generated and expelled oil and those which had not, were prepared and pyrolyzed in a closed system, to observe oil expulsion or oil retention effects on later oil and gas generation from kerogen. The results show that oil expulsion and retention strongly impacts on further oil and gas generation in terms of both the amount and composition in the high maturity stage. Gas production will be reduced by 50% when the expulsion coefficient reaches 58%, and gas from oil-expelled kerogen (less oil retained) is much drier than that from fresh kerogen. The oil expulsion also causes n-alkanes and gas compounds to have heavier carbon isotopic compositions at high maturity stages. The enrichment of ¹³C in n-alkanes and gas hydrocarbons are 1‰ and 4–6‰ respectively, compared to fresh kerogen. Oil expulsion may act as open system opposite to the oil retention that influences the data pattern in crossplots of δ¹³C₂–δ¹³C₃ versus C₂/C₃, δ¹³C₂–δ¹³C₃ versus δ¹³C₁ and δ¹³C₁–δ¹³C₂ versus ln(C₁/C₂), which are widely used for identification of gas from kerogen cracking or oil cracking. These results suggest that the reserve estimation and gas/source correlation in deep burial basins should consider the proportion of oil retention to oil expulsion the source rocks have experienced.     

长江三角洲对流域输沙变化的响应:进展与问题

流域变化对河流三角洲的影响已成为全球性的问题。由于流域水库建设的影响,长江输沙率自1980年以来呈现明显下降趋势,引发了研究人员对长江三角洲地貌和沉积响应问题的关注。在地貌上,海图对比和海岸冲淤观测的证据显示,长江输沙率目前已经低于冲淤平衡的临界值,使三角洲进入了蚀退阶段。分析表明,根据水下三角洲部分范围的沉积速率与河流输沙率的关系进行计算,会过低估计临界输沙率。对于水下三角洲整体而言,应根据沉积物滞留指数来更准确地估算临界输沙率,而且需要区分2个"临界输沙率",一个是保持三角洲体积的临界值,另一个是保持三角洲陆上部分面积的临界值。在沉积响应上,来自长江水下三角洲沉积中心的柱状样显示出沉积速率自下而上减小的趋势,反映了流域输沙率变化的影响。今后,如将柱状样采集区域扩大到沉积中心之外的整个水下三角洲范围,则所获得的数据不仅有助于沉积速率响应特征的全面了解,而且还可应用于沉积物滞留指数特征和控制因素的分析以及河口区碳循环过程变化的研究。此外,在长江三角洲沉积记录的分析方面,为了更好地提取气候、环境演化信息,应充分考虑沉积记录形成后所经历的自身变化(如成岩作用变化、分解和衰变等)和相对于岸线迁移的空间位置变化。     

Delineation of hydrologically similar units in a watershed based on fuzzy classification of soil hydraulic properties

Evaluation of flow and transport processes in a watershed‐scale requires that the watershed be divided into homogenous spatial units referred to as hydrologically similar units (HSUs). Although a few discretization schemes are already in use, a universally acceptable method of obtaining HSUs is yet to emerge. In this study, we developed a fuzzy inference system (FIS) to classify the saturated hydraulic conductivity (K_s) and two water‐retention parameters α and n into fuzzy logic‐based soil hydrologic classes (FSHCs). Analysis of these classes showed that soil properties within an FSHC have less variability and those between two FSHCs have large variability. This result suggested that soils belonging to a specific FSHC may be more similar than those across different FSHCs and may be grouped together to represent an HSU. Soils within a specific hydrologic class were aggregated to delineate HSUs within the watershed. For the Dengei Pahad micro‐watershed (DPW), this approach showed five distinct regions representing a discretized zone having similar soil hydraulic properties. Application of this approach on a larger international database of soil hydraulic properties revealed that the developed hydrologic classes are quite comparable across different databases. The delineated HSUs based on these FSHCs were also better than the soil series map of the watershed in maintaining the soil heterogeneity of the watershed. Moreover, this new discretization scheme using the SWAT modelling environment showed better performance than the soil series‐based discretization approach. Copyright © 2010 John Wiley & Sons, Ltd.     

The effects of controlled drainage on subsurface outflow from level agricultural fields

Daily outflow frequencies and recession curves were used to identify differences in storage–outflow relationships between two different drainage systems, conventional and controlled drainage. A three‐year (1996–1999) field drainage experiment was carried out on a loamy sand soil in southern Sweden. Plots with an area of 0·2 hectares were drained by conventional subsurface drainage (CD) or by controlled drainage (CWT1 and CWT2). The controlled drainage system allowed the groundwater level in the soil to be varied during the year. It was kept at least 70 cm below the soil surface during the growing season but allowed to rise to a maximum of 20 cm below the soil surface during the rest of the year. Measurements were performed to record precipitation, drain outflow and groundwater levels. Daily values of outflow were divided into 10 categories, based on the size of outflow. Recession curves of hourly measurement of outflow were selected. They behaved like single reservoirs and a linear storage–outflow model was applied. Least squares estimates of the parameters initial outflow, initial storage volume and retention constant were calculated. Controlled drainage had a significant effect on total drain outflow and outflow pattern during the three years of measurement. The total drain outflow was 70% to 90% smaller in CWT than in CD. The analysis revealed that the initial outflows were higher, the retention constant and the temporary storage lower in CWT. The hydrological impacts of the reduction in temporary storage were higher peak flow, shorter lag time and shorter recession time and these effects increased with an increased groundwater level. Copyright © 2003 John Wiley & Sons, Ltd.     

城市暴雨过程对下凹式绿地设计参数的影响研究

为了探索城市暴雨过程对下凹式绿地设计参数的影响,使下凹式绿地的设计更为科学,根据城市暴雨产汇流过程,推导了下凹式绿地设计参数之间的关系,并以北京市大兴区一居民住宅区作为研究实例,对不同城市暴雨重现期、不同拦蓄率下的下凹式绿地设计面积、下凹深度进行了计算,结果表明,城市暴雨重现期对下凹式绿地设计面积影响最大,同时,城市暴雨重现期越长,下凹深度和拦蓄率对下凹面积的影响越大。研究结论可为城市下凹式绿地的设计应用提供参考。     

Water chemistry and effect of evapotranspiration on chemical sedimentation on the Mkuze River floodplain, South Africa

The Mkuze Wetland System, forming part of the iSimangaliso World Heritage Site, is South Africa’s largest freshwater wetland area and is known to act as a sink for naturally occurring solutes within the landscape. The chemistry of groundwater and porewater samples, collected from two transects on the Mkuze River floodplain, was investigated to identify processes involved in the control of solute concentrations. Results show that solutes in the groundwater become increasingly concentrated under the influence of evapotranspiration, resulting in the saturation, precipitation, and accumulation of less soluble compounds. Trends in porewater chemistry and calculated saturation indices support previously documented mineralogical and sediment geochemical investigations, with CaCO₃ and silica precipitation, and Fe-rich smectite neoformation identified as the major controls on solute concentration. The association of these mineral phases with zones of high salinity suggests that mineral precipitation is an active process on the floodplain which results in the progressive development of salinity, particularly in areas dominated by deep-rooted trees. Similarities between geochemical processes documented in the Okavango Delta (Botswana) and those identified in this study suggest that evapotranspiration-induced chemical sedimentation is an important process in southern African wetlands, which has the potential to influence vegetation distribution, hydrological flows, and local topography.     

Effects of Replacing Fishmeal with Animal By-products Meal Supplementation in Diets on the Growth and Nutrient Utilization of Mangrove Red Snapper

A feeding trial was conducted for 75 d to evaluate the nutritive value of a mixture of animal by-products(MAB) as a possible protein source in diets for juvenile mangrove red snapper,Lutjanus argentimaculatus(mean initial body weight,30 g). Fish were fed one of five isonitrogenous diets(40% crude protein) replacing 0,25%(MAB25),50%(MAB50),75%(MAB75) and 100%(MAB100) of fish meal protein with similar percentages of MAB. The MAB consisted of 25% cow liver meal,20% leather meal,20% meat and bone meal,15% blood meal,10% APC(poultry feather meal),8% poultry manure dried,1.5% choline and 0.5% chromic oxide. After 75 d of feeding,fish fed with diets MAB50,MAB75 and MAB100 exhibited significantly lower growth per-formance than that of fish fed with control and MAB25 diets. The optimum level of MAB was estimated to be 23%. Replacement of fish meal by MAB23% showed the following performance:maximum weight gain,510%;SGR,2.39% and FCE,2.83%. The MAB substitution up to 75% of fish meal protein in diets did not show differences in apparent protein digestibility(83.6% for MAB25,79.2% for MAB50,78.7% for MAB75) compared with control(83.4%),whereas in MAB100 group digestibility(65.3%) was sig-nificantly lower than in other groups. The apparent phosphorus absorption of test diet groups was significantly higher(37.1% for MAB25,28.5% for MAB50,55.6% for MAB75 and 54.5% for MAB100) than that of control(11.2%). The levels of protein and ash in the whole body,carcass and viscera increased as MAB substitution in diets increased,whereas lipids and moisture remained con-sistent among all treatment groups. These results showed that approximately 23% of fish meal protein could be replaced by a mixture of animal by-products for juvenile snapper growing from 30 g to 167 g in 75 d without compromising growth performance and feed efficiency.     

Consistent parameter constraints for soil hydraulic functions

Parameters of functions to describe soil hydraulic properties are derived from measurements by means of parameter estimation. Of crucial importance here is the choice of correct constraints in the parameter space. Often, the parameters are mere shape parameters without physical meaning, giving flexibility to the model. A fundamental requirement is that the hydraulic functions are monotonic: the retention function and the conductivity function can only decrease as the capillary suction increases. A stricter physical requirement for the conductivity function is that its decrease with respect to saturation is at least linear. This linear decrease would occur if all pores of a capillary bundle had an equal radius. In the first part of this contribution, we derive constraints for the so-called tortuosity parameter of the Mualem conductivity model, which allow highest possible flexibility on one hand and guarantee physical consistency on the other hand. In combination with the retention functions of Brooks and Corey, van Genuchten, or Durner, such a constraint can be expressed as a function of the pore-size distribution parameters. In the second part, we show that a common modification of retention models, which is applied to reach zero water content at finite suction, can lead to the physically unrealistic case of increasing water content with increasing suction. We propose a solution for this problem by slightly modifying these models and introducing a correct parameter constraint.